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Sodium tert-butoxide
Sodium tert-butoxide
- CAS No.865-48-5
- Chemical Name:Sodium tert-butoxide
- CBNumber:CB8169233
- Molecular Formula:C4H9NaO
- Formula Weight:96.1
- MOL File:865-48-5.mol
Sodium tert-butoxide Property
- Melting point 180 °C
- Boiling point 180°C/1mmHg
- Density 1,104 g/cm3
- bulk density 400kg/m3
- vapor pressure 0Pa at 20℃
- refractive index n20/D1.413
- Flash point 12°C
- storage temp. Store below +30°C.
- solubility very slightly in Tetrahydrofuran
- form Powder
- color white to off-white
- Specific Gravity 1.104
- Water Solubility reacts
- Sensitive Air Sensitive & Hygroscopic
- Hydrolytic Sensitivity 7: reacts slowly with moisture/water
- BRN 3654215
- CAS DataBase Reference 865-48-5(CAS DataBase Reference)
- EPA Substance Registry System 2-Propanol, 2-methyl-, sodium salt (865-48-5)
- UNSPSC Code 12352107
- NACRES NA.22
Safety
- Hazard Codes :F,C,Xi
- Risk Statements :11-14-34-37-35-36/37/38-40-19
- Safety Statements :26-36/37/39-43-45-7/8-8-16-36
- RIDADR :UN 3206 4.2/PG 2
- WGK Germany :3
- F :1-3-10
- TSCA :Yes
- HazardClass :4.2
- PackingGroup :II
- HS Code :29051900
-
NFPA 704:
3 3 2 W
-
Symbol(GHS)
- Signal wordDanger
- Hazard statements H228-H251-H314
- Precautionary statements P210-P235-P260-P280-P303+P361+P353-P305+P351+P338
Sodium tert-butoxide Price
More Price(18)
- Brand: Sigma-Aldrich(India)
- Product number: 8.18374
- Product name : Sodium tert-butylate
- Purity: for synthesis
- Packaging: 100G
- Price: ₹3560
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: 8.18374
- Product name : Sodium tert-butylate
- Purity: for synthesis
- Packaging: 1KG
- Price: ₹10440
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: 8.18374
- Product name : Sodium tert-butylate
- Purity: for synthesis
- Packaging: 5KG
- Price: ₹41500
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: 703788
- Product name : Sodium tert-butoxide
- Purity: 99.9%
- Packaging: 5G
- Price: ₹6062
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: 702706
- Product name : Sodium tert-butoxide solution
- Purity: 2?M in THF, ZerO2?
- Packaging: 4X2ML
- Price: ₹885.78
- Updated: 2022/06/14
- Buy: Buy
Sodium tert-butoxide Chemical Properties,Usage,Production
- Chemical Properties white to light tan crystalline powder
- Uses Sodium tert-butoxide is used as a strong base and a non-nucleophilic base. In organic synthesis, it serves as an intermediate in various reactions like condensation, rearrangement and ring-opening. Further, it finds use in agrochemicals, pharmaceuticals, colorants, aroma chemicals, detergents and biodiesel. It acts as a catalyst in polymerization and isomerization reactions.
- Flammability and Explosibility Highly flammable
- Purification Methods Its solubility in tert-BuOH is 0.208M at 30.2o and 0.382M at 60o, and it is quite soluble in tetrahydrofuran (32g/100g). It should not be used if it has a brown colour. [Feuer J Am Chem Soc 78 4364 1956, Hurd Inorg Synth I 87 1939, IR: Seubold J Org Chem 21 156 1956, Beilstein 1 IV 1609.]
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