Reaction
ChemicalBook > CAS DataBase List > ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE

Reaction
((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Structure
((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE
  • CAS No.192139-92-7
  • Chemical Name:((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE
  • CBNumber:CB81564668
  • Molecular Formula:C21H21ClN2O2RuS.C10H14
  • Formula Weight:636.219
  • MOL File:192139-92-7.mol
((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Property
  • Melting point 215 °C
  • storage temp. 2-8°C
  • solubility Deuterated Chloroform, DMF
  • form solid
  • color yellow to dark brown
  • optical activity [α]20/D 116°, c = 0.1 in chloroform
  • Sensitive air sensitive
  • InChIKey AZFNGPAYDKGCRB-MNPNNRAMNA-M
  • SMILES C1=C(S(=O)(=O)N([C@H](C2=CC=CC=C2)[C@H](N)C2=CC=CC=C2)[Ru]Cl)C=CC(C)=C1.C1=CC(C)=CC=C1C(C)C |&1:6,13,r|
  • UNSPSC Code 12352116
  • NACRES NA.22
Safety
  • WGK Germany  :3
  • HS Code  :28439000
  • NFPA 704:
    1
    2 0
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordWarning
  • Hazard statements H302-H315-H319-H335
  • Precautionary statements P261-P280-P301+P312-P302+P352-P305+P351+P338
((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Price More Price(4)
  • Brand: Sigma-Aldrich(India)
  • Product number: 703907
  • Product name : RuCl(p-cymene)[(R,R)-Ts-DPEN]
  • Purity: 
  • Packaging: 100MG
  • Price: ₹3651.9
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 703907
  • Product name : RuCl(p-cymene)[(R,R)-Ts-DPEN]
  • Purity: 
  • Packaging: 500MG
  • Price: ₹10334.1
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: TCI Chemicals (India)
  • Product number: R0125
  • Product name : RuCl[(R,R)-Tsdpen](p-cymene)
  • Purity: 
  • Packaging: 200MG
  • Price: ₹3700
  • Updated: 2022/05/26
  • Buy: Buy
  • Brand: TCI Chemicals (India)
  • Product number: R0125
  • Product name : RuCl[(R,R)-Tsdpen](p-cymene)
  • Purity: 
  • Packaging: 1G
  • Price: ₹10800
  • Updated: 2022/05/26
  • Buy: Buy

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Chemical Properties,Usage,Production

  • Reaction This catalyst has shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydoxy, siloxy, carbonyl, ester, amide or thioester. Reactions of 192139-92-7
  • Chemical Properties Orange to brown powder
  • Uses Phosphine cationic ruthenium catalysts used for enantioselective hydrogenation of:
    • Quinolines
    • N-Alkyl ketimines
    • Antitumor and antiproliferative derivatives of natural products isolated from bacteria
    • Hydroxy arylaldehydes via Rap-Stoermer-enantioselective transfer hydrogenation

    Catalyst with improved performance modified via microenvironment engineering of nanocages
  • General Description RuCl(p-cymene)[(R,R)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium.
((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Preparation Products And Raw materials
Raw materials
Preparation Products
((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Suppliers
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((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Spectrum
192139-92-7, ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDERelated Search:
  • organometallic complex
  • Ru
  • 化学试剂
  • 高端化学
  • 转移氢化催化剂
  • 化工中间体
  • 贵金属催化剂
  • 金属催化剂
  • 化学连接
  • 有机贵重金属
  • 催化剂
  • 精细化学品
  • C31H35ClN2O2RuS
  • (R,R)-N-(对甲苯磺酰)-1,2-二苯乙烷二胺(对异丙基苯)氯
  • 氯((1R,2R)-(-)-2-氨基-1,2-二苯基乙基)(对甲基苯磺酰基)氨基)(对伞花烃)钌(II)
  • 氯{[(1R,2R)-(-)-2-氨-1,2-二苯乙基](4-甲苯磺酰)氨}(P-异丙基甲苯)RUTHENIUM(II))钌(II)(192139-92-7)
  • {[(1R,2R)-(-)-2-氨-1,2-二苯乙基](4-甲苯磺酰)氨}(P-异丙基甲苯)钌(II))
  • 氯{[(1R,2R)-(-)-2-氨-1,2-二苯乙基](4-甲苯磺酰)氨}(P-异丙基甲苯)钌(II) )钌
  • ([(1R,2R)-(-)-2-氨-1,2-二苯乙基](4-甲苯磺酰)氨)(P-异丙基甲苯)氯化钌(II)
  • NOYORI 催化剂
  • 氯{[1R,2R-(-)-2-氨-1,2-二苯乙基](5-甲基苯磺酰)氨}(P-异丙基苯基)钌(II)
  • 氯{[(1R,2R)-(-)-2-氨-1,2-二苯乙基](4-甲苯磺酰)氨}(P-异丙基甲苯)钌(II)),RUCL(P-CYMENE)[(R,R)-TS-DPEN]
  • RUCL(对甲基异丙基苯)[(R,R)-TS-DPEN]
  • 氯化(对伞花烃)[(R,R)-N-(对甲苯磺酰基)-1,2-二苯乙烯基二胺]钌(II)
  • (对甲基异丙基苯){[(1R,2R)-2-氨基-1,2-二苯基乙基](对甲基苯磺酰氨基)}氯化钌(II)
  • RUCL(P-异丙基甲苯)[(R,R)-TS-DPEN]
  • (R,R)-N-(对甲苯磺酰)-1,2-二苯乙烷二胺(对异丙基苯)氯化钌(II)
  • [N-[(1R,2R)-2-(氨基-ΚN)-1,2-二苯基乙基]-4-甲基苯磺酰胺合-ΚN]氯[(1,2,3,4,5,6-Η)-1-甲基-4-(1-甲基乙基)苯]-钌
  • (P-异丙基甲苯)[(R,R)-TS-DPEN]
  • 氯{[(1R,2R)-(-)-2-氨-1,2-二苯乙基](4-甲苯磺酰)氨}(P-异丙基甲苯)钌(II)
  • 氯{[(1R,2R)-(-)-2-氨-1,2-二苯乙基](4-甲苯磺酰)氨}(P-异丙基甲苯)RUT
  • (R,R)-TSDPEN 钌
  • (R,R)-N-(对甲苯磺酰)-1,2-二苯乙烷二胺(对异丙基苯)氯化钌
  • 氯{[(1R,2R)-(-)-2-氨-1,2-二苯乙基](4-甲苯磺酰)氨}(P-异丙基甲苯)钌(II) 1G
  • 氯{[(1R,2R)-(-)-2-氨-1,2-二苯乙基](4-甲苯磺酰)氨}(P-异丙基甲苯)RUTHENIUM(II) )钌(II)
  • 氯{[(1R,2R)-(-)-2-氨-1,2-二苯乙基](4-甲苯磺酰)氨}(P-异丙基甲苯)钌(II))钌(II)
  • 氯[[(1R,2R)-(-)-2-氨基-1,2-二苯基乙基](对甲苯磺酰基)氨基)](对伞花烃)钌(II)
  • 192139-92-7
  • RuCl(<i>p</i>-cymene)[(<i>R</i>,<i>R</i>)-Ts-DPEN]
  • CHLORO{[(1R,2R)-(-)-2AMINO-1,2DIPHENY
  • RuCl[(R,R)-Tsdpen](p-cymene)/Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)
  • [(1R,2R)-2-amiNA-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide
  • <font color="#ff0000">192139-92-7</font>
  • [((R,R)-2-Amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](chloro)( p -cymene)ruthenium(II)
  • RuCL
  • RuCl[(R,R)-Tsdpen](p-cymene)
  • TsDPEN
  • Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)
  • RuCl(p-cymene)[(R,R)-Ts-DPEN]
  • RuCl (cymene)[(R,R)-TsDPEN]
  • ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE ISO 9001：2015 REACH
  • Chloro(p-cymene)[(R,R)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II)
  • [(R,R)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide]chloro(p-cymene)ruthenium(II)
  • Ruthenium, [N-[(1R,2R)-2-(amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-
  • [(R,R)-Tsdpen](p-cymene)
  • Ruthenium,[N-[(1R,2R)-2-(amino-kN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-kN]chloro[(1,2,3,4,5,6-h)-1-methyl-4-(1-methylethyl)benzene]-,98%
  • RuCl(p-cymene)[(R,R)-Ts-DPEN] Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)
  • [RuCl(η6-p-cymene)(N-tosyl-1,2-diphenylethylenediamine)]

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