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O-ALLYL-2,2,2-TRICHLOROACETIMIDATE

O-ALLYL-2,2,2-TRICHLOROACETIMIDATE Structure
O-ALLYL-2,2,2-TRICHLOROACETIMIDATE
  • CAS No.51479-73-3
  • Chemical Name:O-ALLYL-2,2,2-TRICHLOROACETIMIDATE
  • CBNumber:CB8100737
  • Molecular Formula:C5H6Cl3NO
  • Formula Weight:202.47
  • MOL File:51479-73-3.mol
O-ALLYL-2,2,2-TRICHLOROACETIMIDATE Property
  • Boiling point 54-70 °C/7.5-11.25 mmHg
  • Density 1.333 g/mL at 25 °C
  • refractive index n20/D 1.489
  • Flash point 74 °C
  • storage temp. 2-8°C
  • solubility sol hexane, ether, dichloromethane.
  • pka 2?+-.0.70(Predicted)
  • form clear liquid
  • color Colorless to Almost colorless
  • BRN 1907084
  • UNSPSC Code 12352101
Safety
  • Hazard Codes  :Xn
  • Risk Statements  :22-37/38-41
  • Safety Statements  :26-39
  • WGK Germany  :3
  • HS Code  :29252900
  • NFPA 704:
    2
    2 0
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordDanger
  • Hazard statements H302-H315-H318-H335-H227
  • Precautionary statements P210-P264-P302+P352+P332+P313+P362+P364-P305+P351+P338+P310-P403+P235-P501-P261-P280-P305+P351+P338
O-ALLYL-2,2,2-TRICHLOROACETIMIDATE Price More Price(1)
  • Brand: TCI Chemicals (India)
  • Product number: A2186
  • Product name : Allyl 2,2,2-Trichloroacetimidate
  • Purity: min. 98.0 %
  • Packaging: 5G
  • Price: ₹11100
  • Updated: 2022/05/26
  • Buy: Buy

O-ALLYL-2,2,2-TRICHLOROACETIMIDATE Chemical Properties,Usage,Production

  • Uses Reagent used for the protection of an alcohol as its allyl ether in the presence of base sensitive functionality.
  • Application O-allyl-2,2,2-trichloroacetimidate can be used to release allyl groups under mild conditions; used to prepare nitrogen-containing intermediates.
  • Preparation Sodium Hydride (0.5 g, 21 mmol) is slurried in anhydrous ether (20 mL) under a nitrogen blanket. Allyl alcohol (210 mmol) is introduced in ether (30 mL) dropwise with stirring to the slurry. After 20 min, the homogeneous solution is cooled to 0 °C and Trichloroacetonitrile (20 mL, 200 mmol) is added over 15 min. The mixture is allowed to warm to 20 °C over 60 min and then concentrated to a syrup. Pentane (20 mL) containing methanol (0.8 mL, 21 mmol) is added followed by vigorous shaking, filtration, and concentration of the filtrate and pentane washings (2 × 20 mL). The product imidate is obtained as a clear liquid (90-97%). No further purification is required. Alternatively, the imidate can be prepared by using sodium methoxide as a catalyst instead of sodium hydride. Other procedures for the preparation of allyl trichloroacetimidate have been reported.
O-ALLYL-2,2,2-TRICHLOROACETIMIDATE Preparation Products And Raw materials
Raw materials
Preparation Products
O-ALLYL-2,2,2-TRICHLOROACETIMIDATE Suppliers
Global(92)Suppliers
  • Supplier：
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O-ALLYL-2,2,2-TRICHLOROACETIMIDATE Spectrum
51479-73-3, O-ALLYL-2,2,2-TRICHLOROACETIMIDATERelated Search:
  • 高端化学
  • 有机中间体
  • 其他生化试剂
  • 酰胺化合物
  • 酰胺
  • Amidates/Imidates
  • Building Blocks
  • Nitrogen Compounds
  • Organic Building Blocks
  • C5H6Cl3NO
  • O-烯丙基-2,2,2-三氯乙酰亚胺酯
  • 2,2,2-三氯亚氨逐乙酸烯丙酯
  • 2,2,2-三氯乙酰胺烯丙酯
  • 2,2,2-三氯乙酰胺烯丙酯 5G
  • 三氯乙酰亚氨酸丙烯酯
  • 51479-73-3
  • <i>O-</i>Allyl 2,2,2-trichloroacetimidate
  • Allyl Trichloroacetimidate
  • ALLYL 2,2,2-TRICHLOROACETIMIDATE
  • Ethanimidic acid, 2,2,2-trichloro-, 2-propen-1-yl ester
  • Allyl 2,2,2-Trichloroacetimidate &gt
  • O-ALLYL-2,2,2-TRICHLOROACETIMIDATE
  • O-Allyl 2,2,2-trichloroacetimidate 96%
  • 2,2,2-TRICHLOROACETIMIDIC ACID ALLYL ESTER
  • 2,2,2-TRICHLORACETIMIDIC ACID ALLYLESTER

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