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Mannose Triflate

Mannose Triflate Structure
Mannose Triflate
  • CAS No.92051-23-5
  • Chemical Name:Mannose Triflate
  • CBNumber:CB7774955
  • Molecular Formula:C15H19F3O12S
  • Formula Weight:480.36
  • MOL File:92051-23-5.mol
Mannose Triflate Property
  • Melting point 118-122 °C
  • alpha [α]D20 -14~-17゜(c=1,CHCl3)
  • Boiling point 481.6±45.0 °C(Predicted)
  • Density 1.50±0.1 g/cm3(Predicted)
  • refractive index -16 ° (C=1, CHCl3)
  • storage temp. -20°C
  • solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
  • form Solid
  • color White to Off-White
  • optical activity [α]22/D -16°, c = 1 in chloroform
  • BRN 4341413
  • InChI InChI=1/C15H19F3O12S/c1-6(19)25-5-10-11(26-7(2)20)12(27-8(3)21)13(14(29-10)28-9(4)22)30-31(23,24)15(16,17)18/h10-14H,5H2,1-4H3/t10-,11-,12+,13+,14-/s3
  • InChIKey OIBDVHSTOUGZTJ-UBBZJQTNNA-N
  • SMILES [C@H]1(OC(=O)C)[C@H](OC(=O)C)[C@H](O[C@@H](OC(=O)C)[C@H]1OS(=O)(=O)C(F)(F)F)COC(=O)C |&1:0,5,10,12,17,r|
  • FDA UNII 0KI8FFQ6TT
  • UNSPSC Code 41116107
  • NACRES NA.24
Safety
  • Hazard Codes  :Xi
  • Safety Statements  :24/25
  • WGK Germany  :3
  • F  :10-21
  • HS Code  :29329990
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordWarning
  • Hazard statements H335-H315-H319
  • Precautionary statements P261-P280-P271
Mannose Triflate Price More Price(8)
  • Brand: Sigma-Aldrich(India)
  • Product number: M1568
  • Product name : Mannose triflate
  • Purity: For PET imaging, ≥98% (TLC)
  • Packaging: 20MG
  • Price: ₹2359.85
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: M1568
  • Product name : Mannose triflate
  • Purity: For PET imaging, ≥98% (TLC)
  • Packaging: 25MG
  • Price: ₹3031
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: M1568
  • Product name : Mannose triflate
  • Purity: For PET imaging, ≥98% (TLC)
  • Packaging: 100MG
  • Price: ₹7328.53
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: M1568
  • Product name : Mannose triflate
  • Purity: For PET imaging, ≥98% (TLC)
  • Packaging: 10X25MG
  • Price: ₹15219.95
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 655112
  • Product name : β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate
  • Purity: 98%
  • Packaging: 100MG
  • Price: ₹4340.83
  • Updated: 2022/06/14
  • Buy: Buy

Mannose Triflate Chemical Properties,Usage,Production

  • Description Mannose triflate is a glucose analog. Mannose triflate is a well-known precursor for 18F-FDG synthesis for PET applications. 18F-FDG is an imaging technique for cancer.
  • Physical properties White to off-white powder or crystal
  • Uses 1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-beta-D-mannopyranose is a radiolabelled pharmaceutical preparation for diagnostic aims used in positron emission tomography.
  • Preparation The tetraacetyl mannose (1.8 g, 5 mmol) was dissolved in anhydrous CH2Cl2(14 mL) containing dry pyridine (0.9 mL, 11 mmol). This solution was cooled to -15°C, and trifluoromethanesulfonic anhydride (triflic anhydride) (0.9 mL, 5.2 mmol) was added dropwise over 25 min under a nitrogen atmosphere with vigorous stirring. The mixture was then allowed to reach room temperature overnight. The reaction mixture was successively washed with ice-cold saturated aqueous NaHCO3(50 mL) and water (50 mL). The organic layer was dried over anhydrous Na2SO4, filtered, and concentrated on a rotary evaporator.2-Tf-O-AcManwas isolated by column chromatography on silica with hexane :EtOAc=1: 1 as the eluant as white solid Mannose triflate(1.4 g, 56percent).
Mannose Triflate Preparation Products And Raw materials
Raw materials
Preparation Products
Global(244)Suppliers
  • Supplier:
    Henan Fengda Chemical Co., Ltd
  • Tel:+86-371-86557731<br/>+86-13613820652
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    Henan Tianfu Chemical Co.,Ltd.
  • Tel:+86-0371-55170693<br/>+86-19937530512
  • Email:info@tianfuchem.com
  • Country:China
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  • Supplier:
    career henan chemical co
  • Tel:+86-0371-86658258<br/>+8613203830695
  • Email:sales@coreychem.com
  • Country:China
  • ProdList:29859
  • Advantage:58
Mannose Triflate Spectrum
92051-23-5, Mannose TriflateRelated Search:
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  • C15H19F3O12S
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  • 92051-23-5
  • β-<sc>D</sc>-Mannopyranose 1,3,4,6-tetra-<i>O</i>-acetate 2-<i>O</i>-trifluoromethanesulfonate
  • Tetra-<i>O</i>-acetyl-mannose triflate
  • β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate ( TATM)