Reaction
ChemicalBook > CAS DataBase List > (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE

Reaction
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE Structure
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE
  • CAS No.500997-70-6
  • Chemical Name:(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE
  • CBNumber:CB7471614
  • Molecular Formula:C33H32NO2P
  • Formula Weight:505.59
  • MOL File:500997-70-6.mol
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE Property
  • Melting point 99-101°C
  • alpha -63.5° (c 1.0, CH2Cl2)
  • Boiling point 617.8±65.0 °C(Predicted)
  • storage temp. -20°C
  • pka 0.40±0.20(Predicted)
  • form solid
  • color white
  • optical activity [α]22/D 65.0°, c = 1 in chloroform
  • Sensitive moisture sensitive
  • UNSPSC Code 12352005
  • NACRES NA.22
Safety
  • Hazard Codes  :Xi
  • Risk Statements  :36/37/38
  • Safety Statements  :26-36/37
  • WGK Germany  :3
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordWarning
  • Hazard statements H315-H319-H335
  • Precautionary statements P261-P305+P351+P338
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE Price More Price(2)
  • Brand: Sigma-Aldrich(India)
  • Product number: 700762
  • Product name : (S)-SIPHOS-PE
  • Purity: 97%
  • Packaging: 50MG
  • Price: ₹8356.9
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 700762
  • Product name : (S)-SIPHOS-PE
  • Purity: 97%
  • Packaging: 250MG
  • Price: ₹30158.45
  • Updated: 2022/06/14
  • Buy: Buy

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE Chemical Properties,Usage,Production

  • Reaction
    1. Chiral ligands for copper-catalyzed asymmetric allylic alkylation with dialkylzincs.
    2. Chiral ligands for copper-catalyzed asymmetric conjugate addition of diethylzinc to enones.
    3. Chiral ligands for palladium-catalyzed asymmetric hydrosilylation of styrenes
    4. Chiral ligands for copper-catalyzed asymmetric ring-opening of oxabicyclic alkenes with Grignard reagents.
    5. Chiral ligands for nickel-catalyzed asymmetric hydrovinylation of α-alkyl vinylarenes.
    6. Chiral ligands for iridium-catalyzed asymmetric hydrogenation of cyclic enamines.
    7. Chiral ligands for iridium-catalyzed asymmetric hydrogenation of cyclic imines.
    8. Chiral ligands for gold-catalyzed asymmetric [2 + 2] cycloaddition reaction.
    9. Chiral ligands for rhodium-catalyzed asymmetric hydroacylation of salicylaldehydes to homoallylic sulfides.
    10. Chiral ligands for palladium-catalyzed asymmetric carboamination reactions. 
    Reactions of 500997-70-6_1
    Reactions of 500997-70-6_2
    Reactions of 500997-70-6_3
    Reactions of 500997-70-6_4
  • Uses (S)-SIPHOS-PE is a chiral spiro phosphoramidate ligand that can be used to synthesize:
    • Spiroindolenines by Pd-catalyzed intramolecular dearomative arylation of haloaryl-3-substituted indoles.
    • Enantioselective conjugate addition compound by Cu-catalyzed 1,4-addition of diethylzinc (Et2Zn) to cyclic enones.
    • Octaketide natural products via rhodium-phosphoramidite catalyzed alkene hydroacylation.

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE Preparation Products And Raw materials
Raw materials
Preparation Products
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE Suppliers
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(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE Spectrum
500997-70-6, (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINERelated Search:
  • CPN
  • Chiral Spiro Ligand
  • Chiral Phosphine
  • 高端化学
  • 磷酸催化剂-手性磷酸催化剂
  • 有机配体
  • 膦配体
  • C33H32NO2P
  • (11AS)-(-)-10,11,12,13-四氢茚并[7,1-DE:1',7'-FG][1,3,2]二氧磷-5-双[(R)-1-苯乙基]胺
  • (11AS)-10,11,12,13-四氢二茚并[7,1-DE:1',7'-FG][1,3,2]二氧杂磷杂环庚-5-双[(R)-1-苯乙基]胺
  • (11AS)-(-)-10,11,12,13-四氢二茚并[7,1-DE:1',7'-FG][1,3,2]二氧杂磷杂环辛二烯-5-双[(R)-1-苯基乙基]胺(S)-SIPHOS-PE
  • (11AS)-(-)-10,11,12,13-四氢二茚并[7,1-DE:1',7'-FG][1,3,2]二氧杂磷杂环辛二烯-5-双[(R)-1-苯基乙基]胺
  • (11AS)-10,11,12,13-四氢-N,N-双[(1R)-1-苯乙基]-二茚并[7,1-DE:1',7'-FG][1,3,2]二氧磷-5-胺
  • N-二[(R)-1-苯乙基]-[(S)-1,1'-螺二氢茚-7,7'-二基]亚磷酰胺
  • (11AS)-(-)-10,11,12,13-四氢茚并[7,1-DE:1',7'-FG][1,3,2]二氧磷-5-双[-1-苯乙基]胺
  • N-二[(R)-1-苯乙基]-[(S)-1,1'-螺二氢茚-7,7'-二基]-氨基磷酸酯
  • (11AS)-(-)-10,11,12,13-四氢茚并[7,1-DE:1′, 7′-FG][1,3,2]二氧磷-5-双[(R)-1-苯乙基]胺
  • N-二[(R)-1-苯乙基]-[(S)-1,1'-螺二氢茚-7,7'-二基]亚磷酰胺 10G
  • 500997-70-6
  • (S)-N,N-bis((R)-1-phenylethyl)-4,5,6,7-tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-12-amine
  • (<i>S</i>)-SIPHOS-PE
  • (11aS)-10,11,12,13-Tetrahydro-N,N-bis[(1R)-1-phenylethyl]-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine
  • (11aS)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine
  • (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1'',7''-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine
  • (S)-SIPHOS-PE,(S,R,R)-SIPHO,(11aS)-10,11,12,13-Tetrahydro-N,N-bis[(1R)-1-phenylethyl]-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine
  • N,N-bis((R)-1-phenylethyl)-4,5,6,7-tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-12-amine
  • Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine,10,11,12,13-tetrahydro-N,N-bis[(1R)-1-phenylethyl]-, (11aS)-
  • (Sa,R,R)-SIPHOS-PE（WS200893）
  • (11aS)-10,11,12,13-Tetrahydro-N,N-bis[(1R)-1-phenylethyl]-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine,99%e.e.
  • (S)-SIPHOS-PE 97%
  • (SA,R,R)-SIPHOS-PE
  • (11aS)- 10,11,12,13-tetrahydro-N,N-bis[(1R)-1-phenylethyl]-Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-aMine
  • (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine
  • N-Di[(R)-1-phenylethyl]-[(S)-1,1'-spirobiindane-7,7'-diyl]-phosphoramidite ,98%
  • (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1μ, 7μ-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine, N-Di[(R)-1-phenylethyl]-[(S)-1,1μ-spirobiindane-7,7μ-diyl]-phosphoramidite
  • (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine,min.98%(S)-SIPHOS-PE
  • (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE
  • (11AS)-(-)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1-PHENYLETHYL]AMINE
  • N-DI[(R)-1-PHENYLETHYL]-[(S)-1,1'-SPIROBIINDANE-7,7'-DIYL]-PHOSPHORAMIDITE
  • N-DI[(R)-1-PHENYLETHYL]-[(R)-1,1'-SPIROBIINDANE-7,7'-DIYL]-PHOSPHORAMIDITE
  • (S)-SIPHOS-PE
  • (R)-SIPHOS-PE

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