Reaction
ChemicalBook > CAS DataBase List > (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE

(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE

Reaction
(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE Structure
(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE
  • CAS No.185346-09-2
  • Chemical Name:(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE
  • CBNumber:CB7448533
  • Molecular Formula:C25H19N3O2
  • Formula Weight:393.44
  • MOL File:185346-09-2.mol
(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE Property
  • Melting point 265°C (dec.)
  • Boiling point 633.0±55.0 °C(Predicted)
  • alpha -364.0° (c 1.04, CH2Cl2)
  • Density 1.50±0.1 g/cm3(Predicted)
  • storage temp. Sealed in dry,Room Temperature
  • form Powder
  • pka 4.35±0.20(Predicted)
  • color white to off-white
  • optical activity [α]20/D -375°, c = 1 in dichloromethane (typical)
  • UNSPSC Code 12352005
  • NACRES NA.22
Safety
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordWarning
  • Hazard statements H302
  • Precautionary statements P280-P305+P351+P338
(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE Price More Price(2)
  • Brand: Sigma-Aldrich(India)
  • Product number: 673978
  • Product name : 2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine
  • Purity: 
  • Packaging: 250MG
  • Price: ₹10800
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 673978
  • Product name : 2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine
  • Purity: 
  • Packaging: 1G
  • Price: ₹28440
  • Updated: 2022/06/14
  • Buy: Buy

(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE Chemical Properties,Usage,Production

  • Reaction
    1. Ligand for Iridium-catalyzed enantio- and diastereoselective reductive aldol reactions
    2. Ligand for Scandium-catalyzed asymmetric Nazarov reactions
    3. Ligand for Scandium-catalyzed enantioselective pyrrole alkylations of α,β-unsaturated 2-acyl imidazoles
    4. Ligand for Scandium-catalyzed enantioselective Friedel-Crafts Alkylations
    5. Ligand for Nickel-catalyzed asymmetric cross-couplings of racemic propargyl groups with arylzinc reagents
    6. Ligand for Scandium-catalyzed enantioselective intramolecular carbonyl-ene reaction, the synthesis of (+)-triptophenolide
    7. Ligand for Scandium-catalyzed asymmetric synthesis of substituted 3-hydroxy-2-oxindoles
    8. Ligand for Indium-catalyzed enantio- and regioselective addition of pyrroles to isatins
    9. Ligand for Scandium-catalyzed asymmetric [3+2] annulation of allylsilanes with isatins in the synthesis of spirooxindoles
    10. Ligand for Scandium-catalyzed enantioselective allylation of isatins using allylsilanes
    11. Ligand for Scandium-catalyzed enantioselective carboannulation with allylsilanes
    Reactions of 185346-09-2_1
    Reactions of 185346-09-2_2
    Reactions of 185346-09-2_3
  • Chemical Properties White powder
  • Uses Reactant involved in synthesis of:
    • Chiral ruthenium(II)-pybox complexes for use as intramolecular C-H amination catalysts
    • Bis(oxazolinyl_pyridine-scandium(III) triflate complex catalyst for enantioselective addition of pyrroles to indoles
    • Chiral N,N,N-tridentate pybos and pyboxazine ligands
(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE Preparation Products And Raw materials
Raw materials
Preparation Products
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(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE Spectrum
185346-09-2, (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINERelated Search:
  • organic amine
  • Chiral Nitrogen
  • BOX series
  • 高端化学
  • 化学试剂
  • 化学连接
  • 有机配体
  • 氮配体
  • (3AS,3'AS,8AR,8'AR)-2,2'-(2,6-吡啶二基)双[3A,8A-二氢-8H-茚并[1,2-D]恶唑
  • 2,6-双((3AS,8AR)-8,8A-二氢-3AH-茚并[1,2-D]恶唑-2-基)吡啶
  • (-)-2,6-双[(3AS,8AR)-3A,8A-二氢-8H-茚并[1,2-D]噁唑啉-2-基]吡啶
  • 人眼黑色素瘤细胞
  • 2,6-双[(3AS,8AR)-(-)-8H-茚并[1,2-D]噁唑啉-2-基]吡啶, 用于合成
  • 2,6-双[(3AS,8AR)-3A,8A-二氢-8H-INDENO[1,2-D]恶唑啉-2-基]吡啶
  • (3AS,3'AS,8AR,8'AR)-2,2'-(2,6-吡啶二基)双[3A,8A-二氢-8H-茚并[1,2-D]恶唑]
  • 2,6-双[(3AS,8AR)-3A,8A-二氢-8H-茚并[1,2-D]恶唑啉-2-基]吡啶
  • 2,6-双[(3AS,8AR)-3A,8A-二氢-8H-茚并[1,2-D]噁唑啉-2-基]吡啶
  • (3AS,3′AS,8AR,8′AR)-2,2′-(2,6-吡啶二基)双[3A,8A-二氢-8H-茚并[1,2-D]唑
  • (-)-2,6-双[2-{3AS-(2(3'AR*,8'AS*),3AΑ,8AΑ)-3A,8A-二氢-8H-茚并[1,2-D]噁唑啉-2-基}]吡啶
  • 2,6-双[(3AS,8AR)-(-)-8H-茚并[1,2-D]噁唑啉-2-基]吡啶
  • 2,6-双[(3AS,8AR)-3A,8A-二氢-8H-茚并[1,2-D]唑啉-2-基]吡啶
  • 185346-09-2
  • (-)-2,6-Bis[2-{3aS-(2(3aR*,8aS*),3Aalpha:,8Aalpha:)-3a,8a-Dihydro-8H-Indeno[1,2-d]Oxazole}]Pyridine
  • 2,6-Bis[(3a<i>S</i>,8a<i>R</i>)-3a,8a-dihydro-8<i>H</i>-indeno[1,2-<i>d</i>]oxazolin-2-yl]pyridine
  • (-)-2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine
  • (-)-2,6-Bis[2-{3aS-(2(3'aR*,8'aS*),3aα,8aα)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine
  • (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-I...
  • (S,R)-In-Pybox
  • 8H-Indeno[1,2-d]oxazole, 2,2'-(2,6-pyridinediyl)bis[3a,8a-dihydro-, (3aS,3'aS,8aR,8'aR)-
  • 2,6-Bis[(3aS,8aR)-(-)-8H-indeno[1,2-d]oxazolin-2-yl)]pyridine, 98%, for synthesis
  • (-)-2,6-Bis[2-[3as-(2(3'ar*,8'as*),3a alpha,8aalpha)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]]pyridine
  • (3aS,3'aS,8aR,8'aR)-2,2'-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole], 95%, (99% ee)
  • [3aS-[2(3'aRS,8'aSR),3aα,8aα]]-2,2'-(2,6-pyridinediyl)bis-[3a,8a-dihydro-8H-indeno[1,2-d]oxazole]
  • SF150006
  • (3aR,8bS)-2-[6-[(3aR,8bS)-4,8b-dihydro-3aH-indeno[1,2-d][1,3]oxazol-2-yl]pyridin-2-yl]-4,8b-dihydro-3aH-indeno[1,2-d][1,3]oxazole
  • (-)-2,6-BIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLIN-2-YL]PYRIDINE,MIN.97%INDENYL-PYBOX
  • (-)-2,6-Bis[2-{3aS-(2(3'aR*,8'aS*),3aα,8aα)-3a,8a-dihydro-8H-indeno [1,2-d]oxazole}]pyridine, min. 97%　
  • (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE
  • (-)-2,6-Bis[2-{3aS-(2(3'aR*,8'aS*),3aalpha:,8aalpha:)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine, min. 97%
  • 2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine
  • (3aS,8aR)-in-pybox, (3aS,3μaS,8aR,8μaR)-2,2μ-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole
  • (-)-2,6-Bis[2-{3aS-(2(3'aR*,8'aS*),3aalpha,8aalpha)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine,min.97%
  • 2,6-BIS((3AS,8AR)-8H-INDENO(1,2-D)OXAZO&
  • (3aS,8aR)-in-pybox
  • 2,6-Bis[(3aS,8aR)-(-)-8H-indeno[1,2-d]oxazolin-2-yl)]pyridine
  • (3aS,3'aS,8aR,8'aR)-2,2'-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole],99%e.e.
  • aS*),3aα,8aα)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine
  • (-)-2,6-Bis[2-{3aS-(2(3'aR*,8'aS*),3aα,8aα)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine,97%
  • (3aS,3'aS,8aR,8'aR)-2,2'-(2,6-pyridinediyl)bis[3a,8a-dihydro-8H-Indeno[1,2-d]oxazole
  • 2,6-Bis((3aS,8aR)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)pyridine
  • (-)-2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine, min. 97% Indenyl-PYBOX

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