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Aluminum trifluoromethanesulfonate

Aluminum trifluoromethanesulfonate Structure
Aluminum trifluoromethanesulfonate
  • CAS No.74974-61-1
  • Chemical Name:Aluminum trifluoromethanesulfonate
  • CBNumber:CB7387584
  • Molecular Formula:CH4AlF3O3S
  • Formula Weight:180.08
  • MOL File:74974-61-1.mol
Aluminum trifluoromethanesulfonate Property
  • Melting point 300 °C(lit.)
  • storage temp. Inert atmosphere,Room Temperature
  • solubility soluble in ether, acetone, acetonitrile, and diglyme; poorly soluble in nitromethane; sparingly soluble in SO2 and SO2 ClF.
  • form Powder
  • color White
  • Water Solubility Insoluble in water.
  • Sensitive Hygroscopic
  • Hydrolytic Sensitivity 6: forms irreversible hydrate
  • Stability hygroscopic
  • CAS DataBase Reference 74974-61-1(CAS DataBase Reference)
  • UNSPSC Code 12161600
  • NACRES NA.22
Safety
  • Hazard Codes  :C,Xi
  • Risk Statements  :34-36/37/38
  • Safety Statements  :26-36/37/39-45-36
  • RIDADR  :UN 3261 8/PG 3
  • WGK Germany  :3
  • Hazard Note  :Corrosive
  • TSCA  :No
  • HazardClass  :8
  • PackingGroup  :III
  • HS Code  :29049020
  • NFPA 704:
    1
    3 1
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordDanger
  • Hazard statements H314
  • Precautionary statements P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
Aluminum trifluoromethanesulfonate Price More Price(4)
  • Brand: Sigma-Aldrich(India)
  • Product number: 515884
  • Product name : Aluminum trifluoromethanesulfonate
  • Purity: 99.9% trace metals basis
  • Packaging: 10G
  • Price: ₹11383.45
  • Updated: 2022/06/14
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  • Brand: Sigma-Aldrich(India)
  • Product number: 515884
  • Product name : Aluminum trifluoromethanesulfonate
  • Purity: 99.9% trace metals basis
  • Packaging: 50G
  • Price: ₹24971.85
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: ALFA India
  • Product number: ALF-B20785-14
  • Product name : Aluminum trifluoromethanesulfonate, 99%
  • Purity: 
  • Packaging: 25g
  • Price: ₹20226
  • Updated: 2022/05/26
  • Buy: Buy
  • Brand: ALFA India
  • Product number: ALF-B20785-06
  • Product name : Aluminum trifluoromethanesulfonate, 99%
  • Purity: 
  • Packaging: 5g
  • Price: ₹6930
  • Updated: 2022/05/26
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Aluminum trifluoromethanesulfonate Chemical Properties,Usage,Production

  • Chemical Properties White powder
  • Uses Lewis acid used as a catalyst for Friedel–Crafts, ketalization, nucleophilic substitution, hydroalkoxylation, methoxycarbonyla- tion, rearrangement, and epoxide ring-opening reactions.
  • Uses Aluminum trifluoromethanesulfonate is used in pharmaceutical intermediates.
  • Preparation Can be prepared from aluminum trichloride and tribromide by heating with triflic acid in anhydrous conditions. Preparations from triethylaluminum, aluminum carbide, and aluminum isopropoxide have also been described.
  • Reactions Friedel-Crafts Reactions.
    Aluminum trifluoromethanesulfonate has been used for the Friedel-Crafts alkylation reaction of toluene with isopropyl and tert-butyl chlorides (eq 1), and for theacylationofbenzeneandtoluenewithacetylandbenzoylchlo- rides in low to moderate yields. Intramolecular Friedel-Crafts acylation of an aromatic compound with Meldrum’s acid has also been reported using catalytic amounts of Al(OTf) 3 . Acylation of 2-methoxynaphthalene with acetic anhydride has been reported using Al(OTf) 3 and lithium perchlorate as an additive to afford the corresponding 6-acetylated adduct in 83% yield. Effective acylation of arenes with carboxylic acids has also been disclosed using polystyrene-supported Al(OTf)3.
    Aluminum trifluoromethanesulfonate Friedel-Crafts Reactions
  • reaction suitability core: aluminum
    reagent type: catalyst
Aluminum trifluoromethanesulfonate Preparation Products And Raw materials
Raw materials
Preparation Products
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Aluminum trifluoromethanesulfonate Spectrum
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