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METHOXYALLENE; 95%DISCONTINUED 05/24/01

METHOXYALLENE; 95%DISCONTINUED  05/24/01 Structure
METHOXYALLENE; 95%DISCONTINUED 05/24/01
  • CAS No.13169-00-1
  • Chemical Name:METHOXYALLENE; 95%DISCONTINUED 05/24/01
  • CBNumber:CB5501951
  • Molecular Formula:C4H6O
  • Formula Weight:70.09
  • MOL File:13169-00-1.mol
METHOXYALLENE; 95%DISCONTINUED 05/24/01 Property
  • Boiling point 48.2℃ (760 torr)
  • Density 0.832 g/mL at 25 °C
  • refractive index n20/D 1.429
  • Flash point -29 °C
  • storage temp. 2-8°C
  • solubility sol THF, ether, pentane, hexane, CH2Cl2, CHCl3, DMSO
  • form liquid
  • UNSPSC Code 12352100
  • NACRES NA.22
Safety
  • Hazard Codes  :F
  • Risk Statements  :11
  • RIDADR  :UN 1993 3/PG 2
  • WGK Germany  :3
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordDanger
  • Hazard statements H225
  • Precautionary statements P210
METHOXYALLENE; 95%DISCONTINUED 05/24/01 Price More Price(2)
  • Brand: Sigma-Aldrich(India)
  • Product number: 694126
  • Product name : Methoxyallene
  • Purity: technical grade
  • Packaging: 1G
  • Price: ₹3450
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 694126
  • Product name : Methoxyallene
  • Purity: technical grade
  • Packaging: 5G
  • Price: ₹11430
  • Updated: 2022/06/14
  • Buy: Buy

METHOXYALLENE; 95%DISCONTINUED 05/24/01 Chemical Properties,Usage,Production

  • Uses Reactant involved in:• ;Multicomponent reactions with nitriles and carboxylic acids followed by cyclocondensation for synthesis of enantiopure pyridines1• ;Intermolecular hydroamination2• ;One-pot synthesis of alkoxy and (alkylsulfanyl)-substituted pyrroles and dihydropyridines3• ;Intermolecular [4+2] cycloaddition with dienes4• ;Allenyl cyclization and subsequent transformation into dicarbonyl, cyclopentenones, and butenolide compounds5• ;Insertion reactions of C-C pi-bonds into alkylidenesilacyclopropanes6
  • Uses Reactant involved in:
    • Multicomponent reactions with nitriles and carboxylic acids followed by cyclocondensation for synthesis of enantiopure pyridines
    • Intermolecular hydroamination
    • One-pot synthesis of alkoxy and (alkylsulfanyl)-substituted pyrroles and dihydropyridines
    • Intermolecular [4+2] cycloaddition with dienes
    • Allenyl cyclization and subsequent transformation into dicarbonyl, cyclopentenones, and butenolide compounds
    • Insertion reactions of C-C pi-bonds into alkylidenesilacyclopropanes
  • Preparation Methoxyallene can be prepared on a tens-of-grams scale by the base-catalyzed isomerization of 1-methoxy-2-propyne (methyl propargyl ether). Related 1-alkoxy-1,2-propadiene ethers can be prepared similarly. A convenient version of this preparation has been reported.
    METHOXYALLENE; 95%DISCONTINUED  05/24/01
METHOXYALLENE; 95%DISCONTINUED 05/24/01 Preparation Products And Raw materials
Raw materials
Preparation Products
METHOXYALLENE; 95%DISCONTINUED 05/24/01 Suppliers
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METHOXYALLENE; 95%DISCONTINUED 05/24/01 Spectrum
13169-00-1, METHOXYALLENE; 95%DISCONTINUED 05/24/01Related Search:
  • Organic Building Blocks
  • Chemical Synthesis
  • Building Blocks
  • Allenes
  • 高端化学
  • 1-甲氧基-1,2-丙二烯
  • 甲氧基丙二烯
  • 13169-00-1
  • 1,2-Propadiene, 1-methoxy- (9CI)
  • Methyl(1,2-propadienyl) ether
  • Methyl propadienyl ether
  • Methoxypropadiene
  • Methoxyallene
  • Ether, methyl propadienyl
  • CH2=C=CHOCH3
  • 3-Methoxyallene
  • 1-Methoxypropadiene
  • 1-Methoxyallene
  • 1-methoxy-1,2-propadiene
  • 1,2-Propadiene, 1-methoxy-
  • METHOXYALLENE; 95%DISCONTINUED 05/24/01
  • 95%DISCONTINUED 05/24/01
  • Methoxyallene technical grade
  • NSC 363923
  • 1-Methoxypropa-1,2-diene
  • Allenyl methyl ether
  • Propadienylmethyl ether