ChemicalBook > CAS DataBase List > BIS(3 5 3' 5'-DIMETHOXYDIBENZYLIDENEACE&
BIS(3 5 3' 5'-DIMETHOXYDIBENZYLIDENEACE&
BIS(3 5 3' 5'-DIMETHOXYDIBENZYLIDENEACE&
- CAS No.811862-77-8
- Chemical Name:BIS(3 5 3' 5'-DIMETHOXYDIBENZYLIDENEACE&
- CBNumber:CB5501496
- Molecular Formula:2C21H22O5.Pd
- Formula Weight:815.22
- MOL File:811862-77-8.mol
BIS(3 5 3' 5'-DIMETHOXYDIBENZYLIDENEACE& Property
- Melting point 170-178 °C(lit.)
- storage temp. under inert gas (nitrogen or Argon) at 2-8°C
- form Powder
- color Red-brown
- Water Solubility Insoluble in water.
- InChI InChI=1S/2C21H22O5.Pd/c2*1-23-18-9-15(10-19(13-18)24-2)5-7-17(22)8-6-16-11-20(25-3)14-21(12-16)26-4;/h2*5-14H,1-4H3;/b2*7-5+,8-6+;
- InChIKey RTGAJOPJZJDWAX-XVGSOSPHSA-N
- SMILES [CH](C1=CC(OC)=CC(OC)=C1)[CH]C(=O)[CH][CH]C1=CC(OC)=CC(OC)=C1.[CH](C1=CC(OC)=CC(OC)=C1)[CH]C(=O)[CH][CH]C1=CC(OC)=CC(OC)=C1.[Pd] |^1:0,11,14,15,26,37,40,41|
- UNSPSC Code 12352300
Safety
-
Symbol(GHS)
- Signal wordWarning
- Hazard statements H315-H319-H335
- Precautionary statements P261-P305+P351+P338-P280a-P304+P340-P405-P501a
BIS(3 5 3' 5'-DIMETHOXYDIBENZYLIDENEACE& Chemical Properties,Usage,Production
- Uses Bis(3,5,3',5'-dimethoxydibenzylideneacetone)palladium(0) used as catalyst in pharmaceutical research.
- Uses suzuki reaction
- General Description Bis(3,5,3′,5′-dimethoxydibenzylideneacetone)palladium(0) is a non-phosphine based Pd(0) catalyst that can catalyze the Suzuki–Miyaura reaction of aryl chlorides with arylboronic acids with higher percentage conversion when compared to tris(dibenzylideneacetone)dipalladium(0) [Pd2(dba)3].
-
reaction suitability
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
BIS(3 5 3' 5'-DIMETHOXYDIBENZYLIDENEACE& Preparation Products And Raw materials
Raw materials
Preparation Products
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811862-77-8, BIS(3 5 3' 5'-DIMETHOXYDIBENZYLIDENEACE&Related Search:
- (XYL)2P(O)H (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) XPhos Pd G3 BrettPhos Pd G3 XPhos Pd G2 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride SPhos Pd G2 ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98 DICHLORO(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)PALLADIUM(II) RuPhos Pd G2 Tris(dibenzylideneacetone)dipalladium Tris(dibenzylideneacetone)dipalladium Bis(triphenylphosphinepalladium) acetate Bis(dibenzylideneacetone)palladium TRANS-DICHLOROBIS(TRIETHYLPHOSPHINE)PALLADIUM(II) Bis(tricyclohexylphosphine)palladium(II) Dichloride Tris(dibenzylideneacetone)dipalladium-chloroform adduct Tris(dibenzylideneacetone)dipalladium
- 高端化学
- 钯
- 催化和无机化学
- 有机贵金属催化剂
- 医药中间体
- 通用试剂
- 膦配体
- 有机贵重金属
- 2C21H22O5Pd
- C42H44O10Pd
- 双(3,5,3',5'-二甲氧基二亚苄基丙酮)钯(0)
- 双(3,3',5,5'-二甲氧基二亚苄基丙酮)钯
- 双(3,5,3',5'-二甲氧基二亚苄基丙酮)
- 双(3,5,3',5'-二甲氧基二亚苄基丙酮)钯
- 双(3,5,3′,5′-二甲氧基二亚苄基丙酮)钯(0)
- 双(3,5,3',5'-二甲氧基二亚苄基丙酮)钯(0), P
- 双(3,5,3',5'-二甲氧基二亚苄基丙酮)钯 1G
- 811862-77-8
- Bis(3,5,3’,5’-dimethoxydibenzylideneacetone)palladium(0)
- Bis(3,5,3',5'-dimethoxydibenzyL
- PalladiuM,bis[(1E,4E)-(1,2,4,5-h)-1,5-bis(3,5-diMethoxyphenyl)
- Bis(3,3′,5,5′-dimethoxydibenzylideneacetone)palladium
- Bis(3,5,3’,5’-dimethoxydibenzylideneacetone)palladium(0) (Pd(dmdba)2)
- palladium(0)
- Bis(3,5,3',5'-dimethoxydibenzylideneacetone)
- Bis[(1E,4E)-1,5-bis(3,5-diMethoxyphenyl)…
- PalladiuM,bis[(1E,4E)-(1,2,4,5-h)-1,5-bis(3,5-diMethoxyphenyl)-1,4-pentadien-3-one]-
- Bis(3,5,3',5'-diMethoxydibenzylideneacetone)palladiuM(0), Pd 13%
- Bis(3,5,3',5′-diMethoxydibenz
- diMethoxydibenzylideneacetone)palladiuM(0)
- Bis(3,5,3',5'-dimethoxydibenzylideneacetone)palladium
- BIS(3 5 3' 5'-DIMETHOXYDIBENZYLIDENEACE&