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Phenyl trifluoromethanesulfonate

Phenyl trifluoromethanesulfonate Structure
Phenyl trifluoromethanesulfonate
  • CAS No.17763-67-6
  • Chemical Name:Phenyl trifluoromethanesulfonate
  • CBNumber:CB5369083
  • Molecular Formula:C7H5F3O3S
  • Formula Weight:226.17
  • MOL File:17763-67-6.mol
Phenyl trifluoromethanesulfonate Property
  • Boiling point 99-100 °C/60 mmHg (lit.)
  • Density 1.396 g/mL at 25 °C (lit.)
  • refractive index n20/D 1.435(lit.)
  • Flash point 160 °F
  • storage temp. Inert atmosphere,Room Temperature
  • form clear liquid
  • color Colorless to Almost colorless
  • InChI InChI=1S/C7H5F3O3S/c8-7(9,10)14(11,12)13-6-4-2-1-3-5-6/h1-5H
  • InChIKey GRJHONXDTNBDTC-UHFFFAOYSA-N
  • SMILES C(F)(F)(F)S(OC1=CC=CC=C1)(=O)=O
  • UNSPSC Code 12352100
  • NACRES NA.22
Safety
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordDanger
  • Hazard statements H301+H311-H314
  • Precautionary statements P270-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P361+P364
Phenyl trifluoromethanesulfonate Price More Price(3)
  • Brand: Sigma-Aldrich(India)
  • Product number: 423939
  • Product name : Phenyl trifluoromethanesulfonate
  • Purity: 98%
  • Packaging: 5ML
  • Price: ₹10540
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: TCI Chemicals (India)
  • Product number: P1829
  • Product name : Phenyl Trifluoromethanesulfonate
  • Purity: min. 98.0 %
  • Packaging: 1G
  • Price: ₹2600
  • Updated: 2022/05/26
  • Buy: Buy
  • Brand: TCI Chemicals (India)
  • Product number: P1829
  • Product name : Phenyl Trifluoromethanesulfonate
  • Purity: min. 98.0 %
  • Packaging: 5G
  • Price: ₹8300
  • Updated: 2022/05/26
  • Buy: Buy

Phenyl trifluoromethanesulfonate Chemical Properties,Usage,Production

  • Chemical Properties Colorless Liquid.
  • Uses Phenyl trifluoromethanesulfonate (phenyl triflate) may be used in the following studies:
    As an arylating agent for the asymmetric α-arylation of ketones catalyzed by Pd(dba)2 and difluorphos.
    As a reactant in the one pot synthesis of carbazoles by palladium-catalyzed N-arylation of anilines with phenyl triflate followed by oxidative coupling.
    Synthesis of N-(2,6-diarylbenzoyl)anilines by diarylation of benzanilides with phenyl triflate in the presence of palladium-based catalyst.
    As an arylating agent in the synthesis of (R)-2-phenyl-2,3-dihydrofuran by the arylation of 2,3-dihydrofuran.
  • Preparation Synthesis of Phenyl trifluoromethanesulfonate: The reaction of phenol (1.00 g, 10.6 mmol) with triflic anhydride as outlined in the general procedure provided phenyl trifluoromethanesulfonate as colorless oil (0.73 g, 30%).
    1H NMR (400 MHz, CDCl3) δ 7.50 – 7.42 (m, 2H), 7.41 – 7.36 (m, 1H), 7.32 – 7.24 (m, 2H).
  • General Description Phenyl trifluoromethanesulfonate (phenyl triflate) is an aryl fluorosulphonate. It has been synthesized by the reaction of phenol with fluorosulphonic anhydride.
Phenyl trifluoromethanesulfonate Preparation Products And Raw materials
Raw materials
Preparation Products
Phenyl trifluoromethanesulfonate Suppliers
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Phenyl trifluoromethanesulfonate Spectrum
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