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2,6-Diisopropylaniline

Description

CAS No.24544-04-5
Chemical Name:2,6-Diisopropylaniline
CBNumber:CB5349476
Molecular Formula:C12H19N
Formula Weight:177.29
MOL File:24544-04-5.mol

2,6-Diisopropylaniline Property

Melting point -45 °C (lit.)
Boiling point 257 °C (lit.)
Density 0.94 g/mL at 25 °C (lit.)
vapor pressure <0.01 mm Hg ( 20 °C)
refractive index n20/D 1.532(lit.)
Flash point 255 °F
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility <0.2g/l
pka 4.25±0.10(Predicted)
form Liquid
color Clear
Water Solubility <0.20 g/L
BRN 2208763
InChIKey WKBALTUBRZPIPZ-UHFFFAOYSA-N
LogP 3.18 at 20℃
CAS DataBase Reference 24544-04-5(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 190BG0089I
NIST Chemistry Reference Benzenamine, 2,6-bis(1-methylethyl)-(24544-04-5)
EPA Substance Registry System 2,6-Diisopropylaniline (24544-04-5)
UNSPSC Code 12352100
NACRES NA.22

Safety

Hazard Codes :Xi
Risk Statements :52/53-36/37/38
Safety Statements :61-37/39-26
WGK Germany :2
RTECS :BX4025000
TSCA :Yes
HS Code :29214980

NFPA 704:

	1
1		0

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal wordWarning
Hazard statements H319-H412
Precautionary statements P273-P305+P351+P338

2,6-Diisopropylaniline Price More Price(11)

Brand: Sigma-Aldrich(India)
Product number: 374733
Product name : 2,6-Diisopropylaniline
Purity: 97%
Packaging: 5G
Price: ₹8616.7
Updated: 2022/06/14
Buy: Buy

Brand: Sigma-Aldrich(India)
Product number: 374733
Product name : 2,6-Diisopropylaniline
Purity: 97%
Packaging: 25G
Price: ₹23382
Updated: 2022/06/14
Buy: Buy

Brand: Sigma-Aldrich(India)
Product number: 157716
Product name : 2,6-Diisopropylaniline
Purity: technical grade, 90%
Packaging: 100ML
Price: ₹1948.5
Updated: 2022/06/14
Buy: Buy

Brand: Sigma-Aldrich(India)
Product number: 157716
Product name : 2,6-Diisopropylaniline
Purity: technical grade, 90%
Packaging: 500ML
Price: ₹7999.68
Updated: 2022/06/14
Buy: Buy

Brand: TCI Chemicals (India)
Product number: D1755
Product name : 2,6-Diisopropylaniline
Purity: min. 90.0 %
Packaging: 25ML
Price: ₹2000
Updated: 2022/05/26
Buy: Buy

2,6-Diisopropylaniline Chemical Properties,Usage,Production

Description
2,6-Diisopropylaniline is an organic compound with the formula H2NC6H3(CHMe2)2 (Me = CH3). It is a colorless liquid although, like many anilines, samples can appear yellow or brown.
Chemical Properties Clear liquid
Uses 2,6-Diisopropylaniline acts as an intermediate used in the production of carbodiimides stabilizers, synthetic resins, antioxidants and active pharmaceutical ingredients. It is also used in the preparation of multitopic Schiff-base ligand precursors and 4,5-bis(2,6-diisopropylanilino)-2,7-di-tert-butyl-9,9-dimethylthioxanthene. It also undergoes condensation reaction with triacetylmethane to get -[1-(2,6-diisopropylphenylamino)ethylidene]pentane-2,4-dione. Further, it is used to prepare N-heterocyclic carbene complexes for alfa-arylation of acyclic ketones, amination of haloarenes and aqueous Suzuki coupling. In addition to this, it is used in the prepartion of organocatalyst based on naphthalene diimides.
Uses 2,6-Diisopropylaniline was used in the preparation of multitopic Schiff-base ligand precursors. It was also used in the preparation of NSN-donor proligand, 4,5-bis(2,6-diisopropylanilino)-2,7-di-tert-butyl-9,9-dimethylthioxanthene.
Uses 2,6-Diisopropylaniline is used as intermediate for the manufacture of carbodiimides stabilizers, RIM-PUR, synthetic resins, pesticides, antioxidants, pharmaceuticals and other products.
2,6-Diisopropylaniline may be used in the preparation of multitopic Schiff-base ligand precursors.It may be used in the preparation of NSN-donor proligand, 4,5-bis(2,6-diisopropylanilino)-2,7-di-tert-butyl-9,9-dimethylthioxanthene. It may be used to prepare N-heterocyclic carbene complexes for α-arylation of acyclic ketones, amination of haloarenes, and aqueous Suzuki coupling.
2,6-Diisopropylaniline may be used in the preparation of organocatalyst based on naphthalene diimides (NDIs).
Reactions 2,6-Diisopropylaniline is an amine. It undergoes condensation with triacetylmethane in toluene in the presence of p-toluenesulfonic acid provides 3-[1-(2,6-diisopropylphenylamino)ethylidene]pentane-2,4-dione. 2,6-Diisopropylaniline is an aromatic amine. It reacts with bis(trimethylsilylmethyl)yttrium complexes supported by bulky amidopyridinate (Ap) and amidinate (Amd) ligands to afford yttrium alkyl anilido species. This reaction involves the elimination of TMS (Trimethylsilane).
General Description 2,6-Diisopropylaniline is an aromatic amine. It reacts with bis(trimethylsilylmethyl)yttrium complexes supported by bulky amidopyridinate (Ap) and amidinate (Amd) ligands to afford yttrium alkyl anilido species. This reaction involves the elimination of TMS (Trimethylsilane).