ChemicalBook > CAS DataBase List > (2S,3S,8AR)-2-PHENYL-3-HYDROXYMETHYL-8A-METHYL BICYCLIC LACTAM

(2S,3S,8AR)-2-PHENYL-3-HYDROXYMETHYL-8A-METHYL BICYCLIC LACTAM

CAS No.116950-01-7
Chemical Name:(2S,3S,8AR)-2-PHENYL-3-HYDROXYMETHYL-8A-METHYL BICYCLIC LACTAM
CBNumber:CB5273540
Molecular Formula:C15H19NO3
Formula Weight:261.32
MOL File:116950-01-7.mol

(2S,3S,8AR)-2-PHENYL-3-HYDROXYMETHYL-8A-METHYL BICYCLIC LACTAM Property

Melting point 96-100 °C(lit.)
Boiling point 449.5±38.0 °C(Predicted)
Density 1.24±0.1 g/cm3(Predicted)
pka 14.27±0.10(Predicted)

Safety

Hazard Codes :Xi
Risk Statements :36/37/38
Safety Statements :26-36
WGK Germany :3
HazardClass :IRRITANT

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal wordWarning
Hazard statements H315-H319-H335
Precautionary statements P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P

(2S,3S,8AR)-2-PHENYL-3-HYDROXYMETHYL-8A-METHYL BICYCLIC LACTAM Chemical Properties,Usage,Production

Preparation The chiral bicyclic lactams are easily procured via condensation of commercially available (1S,2S)-(+)-2-amino-1-phenyl-1,3-propanediol and the appropriate δ-keto acid (eq 1). Similar bicyclic lactams have been prepared from other amino alcohols and have been extensively utilized in the stereocontrolled formation of quaternary carbon-carbon bonds.

(2S,3S,8AR)-2-PHENYL-3-HYDROXYMETHYL-8A-METHYL BICYCLIC LACTAM Preparation Products And Raw materials

Raw materials

Preparation Products

(2S,3S,8AR)-2-PHENYL-3-HYDROXYMETHYL-8A-METHYL BICYCLIC LACTAM Suppliers

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(2S,3S,8AR)-2-PHENYL-3-HYDROXYMETHYL-8A-METHYL BICYCLIC LACTAM Spectrum

116950-01-7, (2S,3S,8AR)-2-PHENYL-3-HYDROXYMETHYL-8A-METHYL BICYCLIC LACTAMRelated Search:

2-(2-METHYLPIPERIDIN-1-YL)PROPAN-1-OL (1R,2R)-(-)-2-Amino-1-phenyl-1,3-propanediol (-)-Pseudoephedrine N-(1-ISOPROPOXYETHYL)ACETAMIDE (2S,3S,8AR)-2-PHENYL-3-HYDROXYMETHYL-8A-METHYL BICYCLIC LACTAM Oxazolidine, 2,2-dimethyl-5-phenyl- 2-PIPERIDINOL alpha-[1-(Butylmethylamino)ethyl]-benzyl alcohol (1R,2R)-(-)-N-METHYLPSEUDOEPHEDRINE (R*,R*)-alpha-(1-aminoethyl)benzyl alcohol

Pyridines
Heterocyclic Building Blocks
Chiral Building Blocks
Asymmetric Synthesis
Chiral Building Blocks
Pyridines
Heterocyclic Building Blocks
8A-甲基-3-羟甲基-2-苯基-3,6,7,8-四氢-2H-恶唑并[2,3-F]吡啶-5-酮
3-(羟甲基)-8A-甲基-2-苯基六氢-5H-[1,3]恶唑并[3,2-A]吡啶-5-酮
3-(羟甲基)-8A-甲基-2-苯基-3,6,7,8-四氢-2H-恶唑并[2,3-F]吡啶-5-酮
3-(羟甲基)-8A-甲基-2-苯基-3,6,7,8-四氢-2H-[1,3]恶唑并[2,3-F]吡啶-5-酮
[2S-(2Α,3Β,8AΒ)]-(+)-六氢-3-(羟甲基)-8A-甲基-2-苯基-5H-唑并[3,2-A]吡啶-5-酮
[2S-(2Α,3Β,8AΒ)]-(+)-六氢-3-(羟甲基)-8A-甲基-2-苯基-5H-噁唑并[3,2-A]吡啶-5-酮
116950-01-7
5H-Oxazolo[3,2-a]pyridin-5-one, hexahydro-3-(hydroxymethyl)-8a-methyl-2-phenyl-, (2S,3S,8aR)-
8a-methyl-3-methylol-2-phenyl-3,6,7,8-tetrahydro-2H-oxazolo[2,3-f]pyridin-5-one
3-(hydroxymethyl)-8a-methyl-2-phenyl-3,6,7,8-tetrahydro-2H-oxazolo[2,3-f]pyridin-5-one
3-(hydroxymethyl)-8a-methyl-2-phenyl-3,6,7,8-tetrahydro-2H-[1,3]oxazolo[2,3-f]pyridin-5-one
3-(Hydroxymethyl)-8a-methyl-2-phenylhexahydro-5H-[1,3]oxazolo[3,2-a]pyridin-5-one
hexahydro-3-(hydroxymethyl)-8a-methyl-2-phenyl-oxazolo[3,2
[2s-(2α,3β,8aβ)]-(+)-hexahydro-3-(hydroxymethyl)-8a-methyl-2-phenyl-5h-oxazolo[3,2-a]pyridin-5-one
HEXAHYDRO-3-(HYDROXYMETHYL)-8A-METHYL-2- PHENYL-OXAZOLO(3,2-A)PYRIDIN-5-ON, 98%
hexahydro-3-(hydroxymethyl)-8A-methyl-2-phenyl-ox
(2S,3S,8AR)-2-PHENYL-3-HYDROXYMETHYL-8A-METHYL BICYCLIC LACTAM
[2S-(2ALPHA,3BETA,8ABETA)]-(+)-HEXAHYDRO-3-(HYDROXYMETHYL)-8A-METHYL-2-PHENYL-5H-OXAZOLO[3,2-A]PYRIDIN-5-ONE
Oprea1_354110

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