Reaction
ChemicalBook > CAS DataBase List > (R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE

(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE

Reaction
(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE Structure
(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE
  • CAS No.246231-79-8
  • Chemical Name:(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE
  • CBNumber:CB5120257
  • Molecular Formula:C34H32F6FeP2
  • Formula Weight:672.41
  • MOL File:246231-79-8.mol
(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE Property
  • alpha -352° ±10° (c 0.5, CHCl3)
  • storage temp. under inert gas (nitrogen or Argon) at 2-8°C
  • form Powder
  • color orange
  • UNSPSC Code 12352101
Safety
  • Risk Statements  :36/37/38
  • Safety Statements  :24/25
  • WGK Germany  :3
  • HS Code  :29319090
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordWarning
  • Hazard statements H315-H319-H335
  • Precautionary statements P261-P305+P351+P338

(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE Chemical Properties,Usage,Production

  • Reaction
    1. Ferrocenylphosphine ligands of the type cpFecp(PR2)(*CH(CH3)PR'2) are a class of asymmetric ligands developed at Solvias in Basel, Switzerland. Ligands of this type are currently used industrially in the stereoselective synthesis of commercial products. A unique feature of these bidentate ligands is the presence of a fixed phosphine moiety and a stereogenic, functionalized side chain, which can be easily modified to accommodate electronic and steric requirements. Based on a versatile synthetic procedure starting with optically active ferrocenes of the type cpFecp(PR2)(*CH(CH3)X) [X = OAc or NR2], a variety of donor atoms can be introduced into the side chain. These ferrocene based phosphine ligands have wide application in the stereoselective hydrogenation of substituted acetamidoacrylates, enol acetates, β-ketoesters and simple alkenes.
    2. Useful as a ligand in Pd-catalyzed C-N bond-forming reactions.
    3. Pd-catalyzed enantioselective alkylative desymmetrization of meso-succinic anhydrides.
    4. Asymmetric hydrogenation of ketones and phosphinylketimines.
    5. Michael addition of Grignard reagents to α,α-unsaturated esters and thioesters.
    6. Boration of α,α-unsaturated esters and nitriles.
    7. Reaction of aryl halides with ammonia.
    8. Cu-catalyzed reduction of activated C=C bonds with PMHS.
    9. Regio- and enantioselective hydroboration of vinyl arenes.
    10. Rh-catalyzed asymmetric ring-opening reactions of oxabicyclic alkenes.
    11. 1,2-Migrations in Pd-catalyzed Negishi couplings with JosiPhos ligands.
    12. Catalyst for the homodimerization of ketoketenes.
    13. Ligand for the Rh catalyzed synthesis of lactones.
    14. Ligand for the Cu-catalyzed synthesis of syn and anti γ-amino alcohols.
    Reactions of 246231-79-8_1
    Reactions of 246231-79-8_2
    Reactions of 246231-79-8_3
  • Chemical Properties Orange powder
  • General Description sold in collaboration with Solvias AG
(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE Preparation Products And Raw materials
Raw materials
Preparation Products
(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE Suppliers
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(R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE Spectrum
246231-79-8, (R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINERelated Search:
  • metallocene
  • Ferrocene Series
  • Chiral Phosphine
  • Josiphos Series
  • 高端化学
  • 合成材料中间体
  • 有机化学
  • 金属有机化合物
  • 有机配体
  • 膦配体
  • 催化剂
  • Chiral Catalysts, Ligands, and Reagents
  • Asymmetric Synthesis
  • Privileged Ligands
  • Solvias Ligands
  • C34H38F6FeP2
  • (2R)-1-[(1R)-1-[双(1,1-二甲基乙基)膦酰基]乙基]-2-[双[4-(三氟甲基)苯基]膦酰基]二茂铁 (ACI)
  • (R)-1-{(SP)-2-[双(4-三氟甲基苯基)膦基]二茂铁基}乙基-二叔丁基膦
  • (R)-(-)-1-[(S)-2-二叔丁基膦)二茂铁]乙基二-(4-三氟甲基苯)膦
  • [-(-)-1-[(S)-2-二叔丁基磷)二茂铁]乙基二-(4-三氟甲基苯)磷]
  • (R)-1-[(SP)-2-双[(4-三氟甲基苯)膦]二茂铁]乙基二叔丁基膦
  • (R)-1-{(R)-2-[双(4-三氟甲基苯基)膦基]二茂铁基}乙基-二叔丁基膦
  • (R)-(-)-1-[(S)-2-二叔丁基膦二茂铁基]乙基双(4-三氟甲基苯基]膦
  • (R)-(-)-1-{(S)-2-[双(4-三氟甲基苯基)膦基]二茂铁基}乙基-二叔丁基膦
  • (2R)-1-[(1R)-1-[双(1,1-二甲基乙基)膦]乙基]-2-[双[4-(三氟甲基)苯基]膦]二茂铁
  • (R)-(-)-1-[(SP)-2-双(4-三氟甲基苯)磷二茂铁]乙基二叔丁基膦
  • (R)-(-)-1-[(S)-2-二叔丁基磷)二茂铁]乙基二-(4-三氟甲基苯)磷
  • (2R)-1-[(1R)-1-[双(1,1-二甲基乙基)膦]乙基]-2-[双[4-(三氟甲基)苯基]膦]二茂铁(符合 CAS 标准)
  • -(-)-1-[(S)-2-二叔丁基磷)二茂铁]乙基二-(4-三氟甲基苯)磷
  • (-)-1-[(S)-2-二叔丁基磷)二茂铁]乙基二-(4-三氟甲基苯)磷
  • (R)-1-{(SP)-2-[双[4-(三氟甲基)苯基]膦]二茂铁基}乙基-二叔丁基膦
  • (R)-1-[(S)-2-二-(4-三氟甲基苯基膦基)二茂铁基]-乙基-二叔丁基膦
  • (R)-1-[(S)-2-二-(4-三氟甲基苯基膦基)二茂铁基]-乙基-二叔丁基膦, SOLVIAS AG 制造
  • (R)-(-)-1-[(S)-2-双(4-三氟甲基苯)磷二茂铁]乙基二叔丁基膦
  • (R)-1-[(S)-2-(二-(4-三氟甲苯基)膦)二茂铁基]乙基二叔丁基膦
  • (R)-(-)-1-[(S)-2-二叔丁基磷)二茂铁]乙基二-(4-三氟甲基苯)膦
  • (2R)-1-[(1R)-1-[二(叔丁基)膦基]乙基]-2-[二[4-(三氟甲基)苯基]膦基]二茂铁
  • 246231-79-8
  • (<i>R</i>)-1-{(<i>S</i><sub>P</sub>)-2-[Bis[4-(trifluoromethyl)phenyl]phosphino]ferrocenyl}ethyldi-<i>tert</i>-butylphosphine
  • CID 71433572
  • (2R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-[bis[4-(trifluoromethyl)phenyl]phosphino]ferrocene (ACI)
  • (R)-(-)-1-{(Sp)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyldi-t-butylphosphine
  • (R)-(-)-1-[(S)-2-Di-t-butylphosphino)ferrocenyl]ethyldi-(4-C...
  • (R)-1-{(R)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-di-t-butylphosphine
  • (R)-(-)-1-{(S)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-di-t-butylphosphine, min. 97%,99%ee
  • Ferrocene, 1-[(1R)-1-[bis(1,1-dimethylethyl)phosphino]ethyl]-2-[bis[4-(trifluoromethyl)phenyl]phosphino]-, (2R)-
  • (S)-1-[(R)-2-[BIS[4-(TRIFLUO
  • Josiphos SL-J011-1 / (R)-(-)-1-[(S)-2-Di-tert-butylphosphino)ferrocenyl]ethyldi-(4-trifluoromethylphenyl)phosphine
  • "Josiphos SL-J011-1/ (R)-1-{(SP)-2-[Bis[4-(trifluoromethyl)phenyl]phosphino]ferrocenyl}ethyldi-tert-butylphosphine"
  • (2R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-[bis[4-(trifluoromethyl)phenyl]phosphino]ferrocene
  • (R)-(-)-1-{(SP)-2-[Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyldi-tert-butylphosphine
  • (R)-1-{(SP)-2-[Bis[4-(trifluoromethyl)phenyl]phosphino]ferrocenyl}ethyldi-tert-butylphosphine >=97%
  • (R)-1-[(S)-2-Di-(4-trifluoroMethylphenylphos-phino)ferrocenyl]-ethyl-di-tert-butylphosphine, Manufactured by Solvias AG
  • (R)-1-[(S)-2-Di-(4-trifluoromethylphenylphos-phino)ferrocenyl]-ethyl-di-tert-butylphosphine
  • (R)-(-)-1-[(S)-2-Di-tert-butylphosphino)ferrocenyl]ethyldi-(4-trifluoromethylphenyl)phosph
  • (R)-(-)-1-{(S)-2-[Bis(4-trifluoromethylphenyl) phosphino]ferrocenyl} ethyl-di-t-butylphosphine, min. 97%
  • (r,r)-1-[1-(di-tert-butylphosphino)ethyl]-2-{bis[4-(trifluoromethyl)phenyl]phosphino}ferrocene (acc to cas)
  • (R)-(-)-1-{(S)-2-(Bis(4-trifluoromethylphenyl)phosphino]ferrocenyl}ethyl-di-t-butylphosphine,min.97%

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