Reaction
ChemicalBook > CAS DataBase List > (R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE

(R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE

Reaction
(R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE Structure
(R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE
  • CAS No.528521-87-1
  • Chemical Name:(R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE
  • CBNumber:CB4119957
  • Molecular Formula:C45H42P2
  • Formula Weight:644.76
  • MOL File:528521-87-1.mol
(R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE Property
  • Melting point 150-152°C
  • alpha +212° (c 0.53, CH2Cl2)
  • storage temp. -20°C
  • form solid
  • color white
  • Sensitive air sensitive
Safety
  • HS Code  :29319090
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal word
  • Hazard statements
  • Precautionary statements

(R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE Chemical Properties,Usage,Production

  • Reaction Ligands used for the ruthenium-catalyzed hydrogenation of simple and cyclic ketones with high activity and enantioselectivity.
    Ligands used for palladium-catalyzed asymmetric allylic alkylations.
  • Chemical Properties Solid
(R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE Preparation Products And Raw materials
Raw materials
Preparation Products
(R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE Suppliers
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(R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE Spectrum
528521-87-1, (R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANERelated Search:
  • C45H42P2
  • 1,1'-[(1R)-2,2',3,3'-四氢-1,1'-螺二[1H-茚]-7,7'-二基]双S[1,1-双(4-甲基苯基)膦
  • (R)-7,7'-双(二(对甲基苯基)膦基]-1,1'-螺二氢茚
  • 1,1'-[(1R)-2,2',3,3'-四氢-1,1'-螺二[1H-茚]-7,7'-二基]双S[1,1-双(4-甲基苯基)膦]
  • -7,7'-双[二(4-甲基苯)磷酰]-2,2',3,3'-四羟基-1,1'-螺二氢茚
  • (R)-7,7'-双(二(对甲基苯基)膦基]-1,1'-螺二氢茚 10G
  • (R)-(+)-7,7′-双[二(4-甲苯基)膦基]-2,2′,3,3′-四氢-1,1′-螺二茚
  • [(1R)-2,2',3,3'-四氢-1,1'-螺双[1H-茚]-7,7'-二基]二[二(4-甲基苯基)-膦]
  • 528521-87-1
  • (R)-7,7'-bis[di(4-methylphenyl)phosphanyl]-2,2',3,3'-tetrahydro-1,1'-spirobi[indene
  • (R)-(1,2',3,3'-Tetrahydro-1,2'-spirobi[indene]-4,7'-diyl)bis(di-p-tolylphosphine)
  • (R)-(+)-7,7''-Bis[di(4-methylphenyl)phosphino]-2,2'',3,3''-tetrahydro-1,1''-spirobiindane
  • (R)-Tol-SDP,(R)-7,7′-Bis[di( p-methylphenyl) phosphino]-1,1′-spirobiindane
  • (R)–7,7′-Bis[di(p-methylphenyl)phosphino]-1,1′-spirobiindane((R)-Tol-SDP)
  • Phosphine, 1,1'-[(1R)-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl]bis[1,1-bis(4-methylphenyl)-
  • [(1R)-2,2',3,3'-Tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl]bis[bis(4-methylphenyl)-phosphine]
  • (R)-(+)-7,7′-Bis[di(4-methylphenyl)phosphino]-2,2′,3,3′-tetrahydro-1,1′-spirobiindene
  • 1,1'-[(1R)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDENE]-7,7'-DIYL]BIS[1,1-BIS(4-METHYLPHENYL)PHOSPHINE]
  • (R)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97%
  • -7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97%
  • (R)7,7-BIS[DI(P-METHYLPHENYL)PHOSPHINO]-1,1-SPIROBIINDANE
  • (R)-(+)-7,7''-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2'',3,3''-TETRAHYDRO-1,1''-SPIROBIINDANE (R)-TOL-SDP
  • (R)-(+)-7,7'-Bis[di(4-methylphenyl)phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane,min.97%(R)-Tol-SDP
  • (R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE
  • (S)-TOL-SDP
  • (S)-7,7'-BIS[DI(P-METHYLPHENYL)PHOSPHINO]-1,1'-SPIROBIINDANE
  • (S)-(-)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE
  • (R)-TOL-SDP

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