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1-CHLORO-1-METHYLSILACYCLOBUTANE

1-CHLORO-1-METHYLSILACYCLOBUTANE Structure
1-CHLORO-1-METHYLSILACYCLOBUTANE
  • CAS No.2351-34-0
  • Chemical Name:1-CHLORO-1-METHYLSILACYCLOBUTANE
  • CBNumber:CB3430389
  • Molecular Formula:C4H9ClSi
  • Formula Weight:120.65
  • MOL File:2351-34-0.mol
1-CHLORO-1-METHYLSILACYCLOBUTANE Property
  • Boiling point 103 °C(lit.)
  • Density 0.985 g/mL at 25 °C(lit.)
  • refractive index n20/D 1.45(lit.)
  • Flash point 37 °F
  • solubility soluble in most aprotic organic solvents.
  • form liquid
  • Specific Gravity 0.985
  • Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents
  • UNSPSC Code 12352005
  • NACRES NA.22
Safety
  • Hazard Codes  :F,C
  • Risk Statements  :11-14-34
  • Safety Statements  :16-26-36/37/39-45
  • RIDADR  :UN 2985 3/PG 2
  • WGK Germany  :3
  • TSCA  :No
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordDanger
  • Hazard statements H225-H314
  • Precautionary statements P210-P233-P240-P280-P303+P361+P353-P305+P351+P338
1-CHLORO-1-METHYLSILACYCLOBUTANE Price More Price(1)
  • Brand: Sigma-Aldrich(India)
  • Product number: 411582
  • Product name : 1-Chloro-1-methylsilacyclobutane
  • Purity: 98%
  • Packaging: 5G
  • Price: ₹15046.75
  • Updated: 2022/06/14
  • Buy: Buy

1-CHLORO-1-METHYLSILACYCLOBUTANE Chemical Properties,Usage,Production

  • Physical properties bp 103°C; d 0.985 g cm?3.
  • Uses Intermediate in the formation of enoxysilacyclobutanes.
  • Uses Siletanes (silacyclobutanes) represent a unique class of silicon-based reagents that have enjoyed much success in a number of synthetic applications including aldol reactions, allylations, cross-coupling reactions, carbosilane oxidations, and ring expansions. The manifestation of their strain in enhanced Lewis acidity and in the ring opening to silanols accounts for their utility. 1-Chloro-1-methylsiletane can be used for the preparation of the various siletane derivatives for these applications.
    Grignard reagents react efficiently with 1-chloro-1-methylsiletane to provide the corresponding aryl-, alkenyl-, or alkylsiletanes (eqs 1–3).On the contrary, reactions with alkyllithiums are limited to the reaction of 1 with a lithium acetylide (eq 4).The reaction of 1 with an intermediate vinylalane obtained by hydroalumination of 1-heptyne gave (E)-1-heptenylmethylsiletane in >99/1 isomeric purity (eq 5).The reaction of 1 with LiAlD4 afforded 1-deuterio-1-methylsiletane (eq 6).1-CHLORO-1-METHYLSILACYCLOBUTANE
  • Preparation siletane can be prepared in large quantities byWurtz coupling reaction of dichloro-3-chloropropylmethylsilane with Mg.It is commercially available from Gelest and Aldrich chemical company.
1-CHLORO-1-METHYLSILACYCLOBUTANE Preparation Products And Raw materials
Raw materials
Preparation Products
1-CHLORO-1-METHYLSILACYCLOBUTANE Suppliers
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1-CHLORO-1-METHYLSILACYCLOBUTANE Spectrum
2351-34-0, 1-CHLORO-1-METHYLSILACYCLOBUTANERelated Search:
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  • 2351-34-0
  • Silacyclobutane, 1-chloro-1-methyl-
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  • 1-Chloro-1-methylsiletane
  • CYCLOTRIMETHYLENEMETHYLCHLOROSILANE
  • 1-Chloro-1-Methylsilacyclobutane 98%

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