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GLYCINE ANHYDRIDE

GLYCINE ANHYDRIDE Structure
GLYCINE ANHYDRIDE
  • CAS No.106-57-0
  • Chemical Name:GLYCINE ANHYDRIDE
  • CBNumber:CB3356030
  • Molecular Formula:C4H6N2O2
  • Formula Weight:114.1
  • MOL File:106-57-0.mol
GLYCINE ANHYDRIDE Property
  • Melting point >300 °C (lit.)
  • Boiling point 213.59°C (rough estimate)
  • Density 1.3565 (rough estimate)
  • refractive index 1.4487 (estimate)
  • storage temp. Store below +30°C.
  • solubility 142g/l
  • pka 12.88±0.20(Predicted)
  • form Crystalline Powder
  • color White to slightly yellow
  • Water Solubility Soluble in water (142mg/L).
  • Merck 14,7466
  • BRN 112112
  • InChIKey BXRNXXXXHLBUKK-UHFFFAOYSA-N
  • CAS DataBase Reference 106-57-0(CAS DataBase Reference)
  • EWG's Food Scores 1
  • FDA UNII 240L69DTV7
  • EPA Substance Registry System 2,5-Piperazinedione (106-57-0)
  • UNSPSC Code 12352209
  • NACRES NA.26
Safety
  • Safety Statements  :24/25
  • WGK Germany  :3
  • RTECS  :TL6325250
  • TSCA  :Yes
  • HS Code  :29335990
  • NFPA 704:
    1
    0 0
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordWarning
  • Hazard statements H315-H319-H335
  • Precautionary statements P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
GLYCINE ANHYDRIDE Price More Price(8)
  • Brand: Sigma-Aldrich(India)
  • Product number: G7251
  • Product name : Glycine anhydride
  • Purity: cyclic dipeptide
  • Packaging: 25G
  • Price: ₹4570
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: G7251
  • Product name : Glycine anhydride
  • Purity: cyclic dipeptide
  • Packaging: 100G
  • Price: ₹15923.58
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: G7251
  • Product name : Glycine anhydride
  • Purity: cyclic dipeptide
  • Packaging: 1KG
  • Price: ₹56138.45
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 8.14160
  • Product name : 2,5-Piperazinedione
  • Purity: for synthesis
  • Packaging: 25G
  • Price: ₹11040
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: TCI Chemicals (India)
  • Product number: G0100
  • Product name : Glycine Anhydride
  • Purity: 
  • Packaging: 25G
  • Price: ₹4000
  • Updated: 2022/05/26
  • Buy: Buy

GLYCINE ANHYDRIDE Chemical Properties,Usage,Production

  • Chemical Properties white to slightly yellow crystalline powder
  • Uses 2,5-Piperazinedione, can be used as an intermediate in the preparation of various pharmaceutical and biologically active compounds. It can be used in the synthesis of dipeptide isosteres by cross-metathesis.
  • Definition ChEBI: A cyclic peptide that is piperazine in which the hydrogens at positions 2 and 5 are replaced by oxo groups.
  • Synthesis Reference(s) Journal of the American Chemical Society, 87, p. 4646, 1965 DOI: 10.1021/ja00948a047
  • Purification Methods Recrystallise glycine anhydride from H2O (plates) and it can be sublimed (slowly) at 260o or at 140-170o/0.5mm. The dihydrochloride has m 129-130o and is prepared by dissolving it in conc HCl and adding EtOH to crystallisation point; dry it in a vacuum. The bis-1-naphthylurethane has m 232o(dec), and the diperchlorate has m 117o (hygroscopic). [MS: Johnstone J Chem Soc, Perkin Trans 1 1297 1975, NMR: Blaha & Samek Collect Czech Chem Commun 32 3780 1967, Sauborn J Phys Chem 36 179 1932, Corey J Am Chem Soc 60 1599 1938, Beilstein 24 IV 1070.]
GLYCINE ANHYDRIDE Preparation Products And Raw materials
Raw materials
Preparation Products
Global(270)Suppliers
  • Supplier:
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GLYCINE ANHYDRIDE Spectrum
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