ChemicalBook > CAS DataBase List > GLYCINE ANHYDRIDE
GLYCINE ANHYDRIDE
GLYCINE ANHYDRIDE
- CAS No.106-57-0
- Chemical Name:GLYCINE ANHYDRIDE
- CBNumber:CB3356030
- Molecular Formula:C4H6N2O2
- Formula Weight:114.1
- MOL File:106-57-0.mol
GLYCINE ANHYDRIDE Property
- Melting point >300 °C (lit.)
- Boiling point 213.59°C (rough estimate)
- Density 1.3565 (rough estimate)
- refractive index 1.4487 (estimate)
- storage temp. Store below +30°C.
- solubility 142g/l
- pka 12.88±0.20(Predicted)
- form Crystalline Powder
- color White to slightly yellow
- Water Solubility Soluble in water (142mg/L).
- Merck 14,7466
- BRN 112112
- InChIKey BXRNXXXXHLBUKK-UHFFFAOYSA-N
- CAS DataBase Reference 106-57-0(CAS DataBase Reference)
- EWG's Food Scores 1
- FDA UNII 240L69DTV7
- EPA Substance Registry System 2,5-Piperazinedione (106-57-0)
- UNSPSC Code 12352209
- NACRES NA.26
Safety
- Safety Statements :24/25
- WGK Germany :3
- RTECS :TL6325250
- TSCA :Yes
- HS Code :29335990
-
NFPA 704:
1 0 0
-
Symbol(GHS)
- Signal wordWarning
- Hazard statements H315-H319-H335
- Precautionary statements P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
GLYCINE ANHYDRIDE Price
More Price(8)
- Brand: Sigma-Aldrich(India)
- Product number: G7251
- Product name : Glycine anhydride
- Purity: cyclic dipeptide
- Packaging: 25G
- Price: ₹4570
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: G7251
- Product name : Glycine anhydride
- Purity: cyclic dipeptide
- Packaging: 100G
- Price: ₹15923.58
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: G7251
- Product name : Glycine anhydride
- Purity: cyclic dipeptide
- Packaging: 1KG
- Price: ₹56138.45
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: 8.14160
- Product name : 2,5-Piperazinedione
- Purity: for synthesis
- Packaging: 25G
- Price: ₹11040
- Updated: 2022/06/14
- Buy: Buy
- Brand: TCI Chemicals (India)
- Product number: G0100
- Product name : Glycine Anhydride
- Purity:
- Packaging: 25G
- Price: ₹4000
- Updated: 2022/05/26
- Buy: Buy
GLYCINE ANHYDRIDE Chemical Properties,Usage,Production
- Chemical Properties white to slightly yellow crystalline powder
- Uses 2,5-Piperazinedione, can be used as an intermediate in the preparation of various pharmaceutical and biologically active compounds. It can be used in the synthesis of dipeptide isosteres by cross-metathesis.
- Definition ChEBI: A cyclic peptide that is piperazine in which the hydrogens at positions 2 and 5 are replaced by oxo groups.
- Synthesis Reference(s) Journal of the American Chemical Society, 87, p. 4646, 1965 DOI: 10.1021/ja00948a047
- Purification Methods Recrystallise glycine anhydride from H2O (plates) and it can be sublimed (slowly) at 260o or at 140-170o/0.5mm. The dihydrochloride has m 129-130o and is prepared by dissolving it in conc HCl and adding EtOH to crystallisation point; dry it in a vacuum. The bis-1-naphthylurethane has m 232o(dec), and the diperchlorate has m 117o (hygroscopic). [MS: Johnstone J Chem Soc, Perkin Trans 1 1297 1975, NMR: Blaha & Samek Collect Czech Chem Commun 32 3780 1967, Sauborn J Phys Chem 36 179 1932, Corey J Am Chem Soc 60 1599 1938, Beilstein 24 IV 1070.]
GLYCINE ANHYDRIDE Preparation Products And Raw materials
Raw materials
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106-57-0, GLYCINE ANHYDRIDERelated Search:
- (S)-3-Isopropyl-2,5-piperazinedione CYCLO(-GLY-SER) CYCLO(-GLY-HIS) CYCLO(-GLY-TRP) cyclo(Gly-Ile) cyclo(Gly-Met) cyclo(Gly-Lys) cyclo(Gly-Arg) cyclo(Gly-Thr) cyclo(Gly-Asn) DL-2-AMINOPROPIONIC ANHYDRIDE GLYCINE ANHYDRIDE 1,4-DIACETYL-2,5-DIKETOPIPERAZINE 1,4-DIMETHYL-2,5-DIKETOPIPERAZINE,Sarcosine diketopiperazine VERRUCULOGEN AMPICILLIN IMP. C (EP):*) AMPICILLIN DIKETOPIPERAZINE MM(CRM STANDARD) Lisinopril R,S,S-Diketopiperazine GLYCINE ANHYDRIDE,2,5-DIKETOPIPERAZINE
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