ChemicalBook > CAS DataBase List > (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE

(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE

Reaction

CAS No.64536-78-3
Chemical Name:(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
CBNumber:CB3108657
Molecular Formula:C31H47F6IrNP2
Formula Weight:801.88
MOL File:64536-78-3.mol

(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Property

Melting point 175 °C (dec.)(lit.)
Density 1.67 g/cm3
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform (Slightly)
form Crystalline Powder
color Orange
Water Solubility Slightly soluble in acetone, dichloromethane, ethanol and diethyl ether. Insoluble in water.
Sensitive Moisture Sensitive
Merck 13,2594
FDA UNII 816RS2NBPN
UNSPSC Code 12161600
NACRES NA.22

Safety

Hazard Codes :Xi,Xn
Risk Statements :36/37/38
Safety Statements :26-36
WGK Germany :3
F :10-21
TSCA :No
HS Code :29310099

NFPA 704:

	0
2		1

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal wordWarning
Hazard statements H315-H319-H335
Precautionary statements P261-P264-P271-P280-P302+P352-P305+P351+P338

(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Price More Price(5)

Brand: Sigma-Aldrich(India)
Product number: 337498
Product name : (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridium(I) hexafluorophosphate
Purity: 85%
Packaging: 50MG
Price: ₹1530
Updated: 2022/06/14
Buy: Buy

Brand: Sigma-Aldrich(India)
Product number: 337498
Product name : (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridium(I) hexafluorophosphate
Purity: 85%
Packaging: 250MG
Price: ₹5940
Updated: 2022/06/14
Buy: Buy

Brand: Sigma-Aldrich(India)
Product number: 29590
Product name : (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridium(I) hexafluorophosphate
Purity: ≥99.0% (C)
Packaging: 250MG
Price: ₹18636.9
Updated: 2022/06/14
Buy: Buy

Brand: ALFA India
Product number: ALF-042057-MD
Product name : 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99%
Purity:
Packaging: 250mg
Price: ₹7610
Updated: 2022/05/26
Buy: Buy

Brand: TCI Chemicals (India)
Product number: C2824
Product name : (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate
Purity:
Packaging: 100MG
Price: ₹8000
Updated: 2022/05/26
Buy: Buy

(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Chemical Properties,Usage,Production

Reaction
1. Iridium catalyst used for the highly enantioselective hydrogenation of α,β-unsaturated esters.
2. Iridium catalyst used for the stereoselective catalytic hydrogenation and conjugate reduction of 4methylitaconate derivatives bearing a chiral auxiliary.
3. Iridium catalyst used in the synthesis of thiophene-based TAK-779 analogues via C-H arylation.
4. Iridium catalyst used in the practical synthetic approach to chiral (α-chloroalkyl)boronic esters via an iridiumcatalyzed, chemoselective hydrogenation of chloro-substituted alkenyl boronates.
5. Iridium catalyst used in the regioselective C-H activation and hydrogen-isotope exchange of non-aromatic unsaturated functionality.
Chemical Properties orange crystals. Air stable for days, but long term storage under N2 and in the dark recommended.
Uses 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate is used as a catalyst for hydrogenation of mono-, di-, tri-, and tetra-substituted substrates and the isomerization and hydroboration of alkenes. It is also used in isotope exchange reactions, especially the direct exchange of a hydrogen atom with its isotopes deuterium and tritium. Carbonyl groups are also known to direct the hydrogenation by the Crabtree catalyst is highly regioselective.
reaction suitability core: iridium
reagent type: catalyst

(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Preparation Products And Raw materials

Raw materials

Preparation Products

(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Suppliers

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(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Spectrum

(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE(64536-78-3)¹HNMR (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE(64536-78-3)³¹PNMR

64536-78-3, (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATERelated Search:

Ruthenium(III) chloride hydrate GRUBBS CATALYST 2ND GENERATION (1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE DICHLORO-[1,3-BIS(DIISOPROPYLPHENYL)IMIDAZOLYLIDENE]-(3-CHLOROPYRIDYL)PALLADIUM(II) Dimethyl sulfoxide DI-I-PROPYLPHOSPHINE Tricyclohexyl phosphine TRIHEXYLPHOSPHINE TRIISOPROPYLPHOSPHINE DICYCLOHEXYLPHOSPHINE 1,5-Cyclooctadiene CYCLOHEXYLPHOSPHINE (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE

Ir
有机原料
化学试剂
高端化学
铱系列
格氏试剂
吡啶
金属催化剂
Iridium
Catalysis and Inorganic Chemistry
C31H50F6IrNP2
C31H50IrNPPF6
C6H113PC8H12C5H5NIrPF6
C31H50IrNPF6P
(1,5-环辛二烯)(吡啶)(三环己基膦)六氟磷酸铱(I)
,5-环辛二烯(吡啶)(三环己基磷化氢)铱六氟磷酸盐
(1,5-环辛二烯)(吡啶)(三环己基膦)铱(I)六氟磷酸盐
CRABTREE 催化剂
1,5-环辛二烯(吡啶)(三环己基磷)铱(I)六氟磷酸盐
1,5-环辛二烯(吡啶)(三环己基磷化氢)铱六氟磷酸盐,99%
1,5-环辛二烯(吡啶)(三环己基膦)铱六氟磷酸盐
1,5-环辛二烯(吡啶)(三环己基磷化氢)铱六氟磷酸盐
(1,5-环辛二烯)(嘧啶)(三环己基膦)铱(I)六氟磷酸盐
六氟磷酸(三环己基膦)(1,5-环辛二烯)(吡啶)合铱(I)
铱(I)六氟磷酸(1,5-环辛二烯)-(吡啶)-(三环己基膦)复合物
六氟磷酸(三环己基膦)(1,5-环辛二烯)(吡啶)合铱
1,5-环辛二烯(吡啶)(三环己基磷化氢)铱(I)六氟磷酸盐
六氟磷酸(三环已基膦)(1,5-环辛二烯)(吡啶)合铱
64536-78-3
(Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate,98% CRABTREE'S CATALYST
Felkin-Crabtree catalyst
Tricylocohexylphosphine(1,5-cyclooctadiene)(pyridine) iridium(I) hexafluorophosphate ["Crabtree Catalyst"
(1,2,5,6-η)-1,5-cyclooctadiene](pyridine)(tricyclohexylphosphine)-Iridium(1+) hexafluorophosphate(1-) (1:1)
Iridium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene](pyridine)(tricyclohexylphosphine)-, hexafluorophosphate(1-) (1:1)
CRABTREE'S CATALYST
CRABTREE CATALYST
[Ir(cod)(PCy3)(py)]PF6
Crabtrees catalyst, (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-Ir(I) PF6, Iridium(I) hexafluorophosphate (1,5-Cyclooctadiene)-(pyridine)-(tricyclohexylphosphine) complex
tricyclohexylphosphinecyclooctadienepyridineiridium PF6
1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99%,
(Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridiu...
(1, 5-Cyclooctadiene) (pyridine) (tricylocohexylphosphine) iridium(I) hexafluorophosphate
1,5-Cyclooctadiene(Pyridine)(Tricyclohexylphosphine)Iridium(I) Hexafluorophospha
phosphine)iridium(I) hexafL
ooctadiene(pyridine)(tricycL
[Ir(PCy3)(COD)(Py)]+PF6-
(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) PF6, 85%
Crabtrees Catalyst~(Tricyclohexyphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate
(Tricyclohexyphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate
(1,5-cyclooctadiene)(pyrid.)(tric.hexyl-phosphine)irid(I)pf6
(TRICYCLOHEXYLPHOSPHINE)(1,5-CYCLOOCTADIENE)(PYRIDINE)IRIDIUM (I) HEXAFLUOROPHOSPHATE
(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
CRABTREE PRECURSOR COMPLEX
IRIDIUM(I) HEXAFLUOROPHOSPHATE (1,5-CYCLOOCTADIENE)-(PYRIDINE)-(TRICYCLOHEXYLPHOSPHINE) COMPLEX
(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridiuM(I) hexafluorophosphate 85%
(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridiuM(I) hexafluorophosphate >=99.0% (C)
1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridiuM(I)
(Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridiuM(I)hexafluorophosphate,CRABTREE'S CATALYST

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