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Perfluorotributylamine

CAS No.311-89-7
Chemical Name:Perfluorotributylamine
CBNumber:CB2449979
Molecular Formula:C12F27N
Formula Weight:671.09
MOL File:311-89-7.mol

Perfluorotributylamine Property

Melting point -52 °C
Boiling point 178 °C(lit.)
Density 1.883 g/mL at 25 °C(lit.)
vapor density 23.3 (vs air)
vapor pressure 1.3 mm Hg ( 25 °C)
refractive index n20/D 1.3
Flash point None
storage temp. Keep in dark place,Inert atmosphere,2-8°C
solubility Chloroform (Sparingly), Methanol (Slightly)
form liquid
pka -26.84±0.50(Predicted)
color Clear colorless
Specific Gravity 1.880
Water Solubility insoluble
FreezingPoint -60℃
BRN 1813883
Dielectric constant 1.8999999999999999
InChIKey VUMYZTYYVRXVJA-UHFFFAOYSA-N
CAS DataBase Reference 311-89-7(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 3702Y1HQ6O
NIST Chemistry Reference Perfluorotributylamine(311-89-7)
EPA Substance Registry System 1-Butanamine, 1,1,2,2,3,3,4,4,4-nonafluoro-N,N-bis(1,1,2,2,3,3,4,4,4-nonafluorobutyl)- (311-89-7)
UNSPSC Code 77101502
NACRES NA.25

Safety

Hazard Codes :Xi,T
Risk Statements :36/37/38
Safety Statements :26-36
WGK Germany :2
RTECS :YA1000000
TSCA :T
HS Code :29211990
Hazardous Substances Data :311-89-7(Hazardous Substances Data)

NFPA 704:

	1
1		0

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal wordWarning
Hazard statements H315-H319-H335
Precautionary statements P280a-P304+P340-P405-P501a-P261-P305+P351+P338

Perfluorotributylamine Price More Price(7)

Brand: Sigma-Aldrich(India)
Product number: H5262
Product name : Heptacosafluorotributylamine
Purity: liquid
Packaging: 5ML
Price: ₹6051.18
Updated: 2022/06/14
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Brand: Sigma-Aldrich(India)
Product number: H5262
Product name : Heptacosafluorotributylamine
Purity: liquid
Packaging: 25ML
Price: ₹18803.03
Updated: 2022/06/14
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Brand: Sigma-Aldrich(India)
Product number: 77299
Product name : Heptacosafluorotributylamine
Purity: analytical standard, suitable for mass spectrometry (MS)
Packaging: 5ML
Price: ₹5986.23
Updated: 2022/06/14
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Brand: Sigma-Aldrich(India)
Product number: 77299
Product name : Heptacosafluorotributylamine
Purity: analytical standard, suitable for mass spectrometry (MS)
Packaging: 25ML
Price: ₹25189.78
Updated: 2022/06/14
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Brand: Sigma-Aldrich(India)
Product number: 442747-U
Product name : Perfluorotributylamine (PFTBA)
Purity: analytical standard
Packaging: 1000MG
Price: ₹6159.43
Updated: 2022/06/14
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Perfluorotributylamine Chemical Properties,Usage,Production

Description Perfluorotributylamine (PFTBA, also termed FC-43) is a common mass calibrant used in GC-MS systems. It is a dense, moderately high-boiling liquid. It is the main component of Fluosol-43, an artificial blood substitute that has been approved by the US Food and Drug Administration for use in cardiac angioplasty.
PFTBA is also used as an ingredient in some refrigerants. It is persistent in the atmosphere and a powerful greenhouse gas. In 2013, S. A. Mabury at the University of Toronto used IR spectroscopy data to calculate that PFTBA is the strongest global-warming potential of any compound detected in the atmosphere-7100 times greater than that of CO2.
Chemical Properties clear colourless liquid
Uses Perfluorotributylamine is used in electronic applications viz. liquid burn-in, testing and vapor phase soldering processes. It acts as an indicator fluid to check the leakage and heat transfer fluid for thermal shock testing. It is an active component in fluosol, which is a substitute for artificial blood and fluorinert coolant liquids. Further, it is used as a solvent for computer disc drive lubrication. In addition to this, it is used as a calibration chemical in gas chromatography.
Perfluorotributylamine (PFTBA) is commonly used for the calibration of the mass axes of mass spectrometers, basically in those systems, which use electron ionization (EI). PFTBA may be used as a calibration standard for the gas chromatography-mass spectrometric determination of tramadol in human plasma samples and phthalate esters in water samples.
Definition ChEBI: Perfluorotributylamine is an organofluorine compound that is tributylamine in which all the hydrogens have been replaced by fluorine atoms. It has a role as a member of greenhouse gas, a solvent and a blood substitute. It derives from a tributylamine.
Preparation Perfluorotributylamine (PFTBA) is prepared by electrofluorination of tributylamine using hydrogen fluoride as solvent and source of fluorine: N(C₄H₉)₃ + 27 HF → N(C₄F₉)₃+ 27 H₂
Application Perfluorotributylamine (PFTBA) is commonly used in systems that use electron ionisation (EI) for the calibration of mass spectrometer mass spectrometer mass spectrometer axes, and PFTBA can be used as a calibration standard for the determination of tramadol in human plasma samples by gas chromatography-mass spectrometry (GC-MS), and for the determination of phthalate esters in water samples.
Safety Perfluorotributylamine is belongs to fluorofluids, fluorofluids are generally of very low toxicity, so much that they have been evaluated as synthetic blood.
Precautions Store in a cool place. Incompatible with powdered metals and alkali metals.