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Dicyclohexylborane
Dicyclohexylborane
- CAS No.1568-65-6
- Chemical Name:Dicyclohexylborane
- CBNumber:CB21074659
- Molecular Formula:C12H23B
- Formula Weight:178.12
- MOL File:1568-65-6.mol
Dicyclohexylborane Property
- Melting point 103-105 °C
- Boiling point 263.7±23.0 °C(Predicted)
- solubility Soluble in THF, diethyl ether, dichloromethane, and pentane.
Safety
- Hazard Codes :F,C
- Risk Statements :17-34
- Safety Statements :16-23-26-36/37/39-45
-
Symbol(GHS)
- Signal wordDanger
- Hazard statements H314-H250
- Precautionary statements P260-P264-P280-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P321-P305+P351+P338-P405-P501-P210-P222-P280-P302+P334-P370+P378-P422
Dicyclohexylborane Chemical Properties,Usage,Production
- Uses Dicyclohexylborane is a reducing reagent such as in the synthesis of chlorosulfolipid products such as deschloromytilipin A.
- Synthesis Reference(s) Journal of the American Chemical Society, 95, p. 6876, 1973 DOI: 10.1021/ja00801a081
- Reactivity Profile Dicyclohexylborane is a reagent for the reduction of ketones and α,β-unsaturated ketones; it is used for the hydroboration of alkynes, alkenes, and allenes.
- Synthesis Dicyclohexylborane is a stable white solid available via the hydroboration of cyclohexene with either Borane-Tetrahydrofuran or Borane-Dimethyl Sulfide. Recently, dicyclohexylborane has been prepared via the hydroboration of cyclohexene with borane-1,4-thioxane.
- Precautions Dicyclohexylborane must be used immediately upon generation or stored as a solid under dry nitrogen. Use in a fume hood.
Dicyclohexylborane Preparation Products And Raw materials
Raw materials
Preparation Products
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- 硼烷还原剂
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- 1568-65-6
- icyclohexylboron
- Borane, dicyclohexyl-
- Dicyclohexylborane