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1,1'-FERROCENEDICARBOXYLIC ACID

1,1'-FERROCENEDICARBOXYLIC ACID Structure
1,1'-FERROCENEDICARBOXYLIC ACID
  • CAS No.1293-87-4
  • Chemical Name:1,1'-FERROCENEDICARBOXYLIC ACID
  • CBNumber:CB1411720
  • Molecular Formula:C12H10FeO410*
  • Formula Weight:274.05
  • MOL File:1293-87-4.mol
1,1'-FERROCENEDICARBOXYLIC ACID Property
  • Melting point ≥300 °C(lit.)
  • storage temp. Inert atmosphere,Room Temperature
  • solubility DMSO, Ethyl Acetate (Very Slightly, Heated, Sonicated)
  • form crystal
  • color orange
  • Water Solubility Insoluble
  • Exposure limits ACGIH: TWA 1 mg/m3
    NIOSH: TWA 1 mg/m3
  • Stability Stable. Incompatible with strong oxidizing agents.
  • CAS DataBase Reference 1293-87-4
  • NIST Chemistry Reference 1,1'-Ferrocenedicarboxylic acid(1293-87-4)
  • UNSPSC Code 12352300
  • NACRES NA.22
Safety
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordWarning
  • Hazard statements H315-H319-H335
  • Precautionary statements P261-P305+P351+P338

1,1'-FERROCENEDICARBOXYLIC ACID Chemical Properties,Usage,Production

  • Chemical Properties dark brown powder
  • Uses Reactant for preparation of:
    • Planar chiral ferrocene-based amido-phosphine ligands as catalysts for asymmetric allylic alkylation reactions
    • Potential antitumor agents
    • Isostructural ferrocenyl coordination polymer hollow microspheres with H2 storage properties
    • Prganometallic aromatic polyesters
    • Manganese-lanthanide-ferrocene clusters
  • reaction suitability core: iron
    reagent type: catalyst
  • Purification Methods It crystallises in orange-yellow crystals from AcOH and sublimes above 230o. The monomethyl ester has m 147-149o [Nesmeyanov & Reutov Dokl Acad Nauk USSS 115 518 1957]. The dimethyl ester has m 114-115o [Woodward et al. J Am Chem Soc 74, 3458 1953]. The diacid chloride has m 92-93o when recrystallised from pet ether. [Nesmeyanov & Reutov Dokl Acad Nauk SSSR 120 1267 1958, Kazitsyna et al. Dokl Acad Nauk SSSR 127 333 1959, Beilstein 16 IV 1811.]
1,1'-FERROCENEDICARBOXYLIC ACID Preparation Products And Raw materials
Raw materials
Preparation Products
1,1'-FERROCENEDICARBOXYLIC ACID Suppliers
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1,1'-FERROCENEDICARBOXYLIC ACID Spectrum
1293-87-4, 1,1'-FERROCENEDICARBOXYLIC ACIDRelated Search:
  • Industrial/Fine Chemicals
  • Chemical Synthesis
  • Catalysis and Inorganic Chemistry
  • Miscellaneous
  • Transition Metal Compounds
  • Metallocenes
  • Ferrocenes
  • Fe (Iron) Compounds
  • Classes of Metal Compounds
  • 金属催化剂
  • 高端化学
  • 有机原料
  • 有机化学
  • 其它
  • 单体
  • Classes of Metal Compounds
  • Metallocenes
  • Transition Metal Compounds
  • Fe (Iron) Compounds
  • Ferrocenes
  • Catalysis and Inorganic Chemistry
  • 2C6H5O2Fe
  • C12H10FeO4
  • HOOCC5H42Fe
  • 1293-48-1
  • 1,1'-二茂铁二甲酸*5
  • 1,1'-二茂铁二甲酸
  • 1,1'-二茂铁二甲酸 5G
  • 1,1'-二戊铁二甲酸
  • 1,1-二茂铁二甲酸,98%
  • 1,1'-二羧基二茂铁
  • 二茂铁二甲酸
  • 1,1-二戊铁二羧酸
  • 双(羧基环戊二烯)合铁
  • 1,1ˊ-二茂铁二羧酸
  • 1,1'-二茂铁甲酸
  • 1293-87-4
  • Bis(5-carboxy-1,3-cyclopentadien-1-yl)iron
  • 1,1''-Ferrocenedicarboxylic Acid
  • 1,1'-Dicarboxyferrocene
  • 1,1'-Ferrocenedicarboxylic Acid
  • DK7513
  • 1,1'-FerrocenedicarboxylicAcid&gt
  • 1,1'-FerrocenedicarboxyL
  • 1,1′-Ferrocenedicarboxylic acid 96%
  • 1,1'-Ferrocenedicarboxylic acid ,97%
  • 1,1'-FerrocenediCarbocylic acid
  • 1,1′-Ferrocenedicarboxylic acid, >=98%
  • 1,1′-Biscarboxylferrocene
  • 1,1'- twocarboxyltwoferrocene
  • Bis(carboxycyclopentadienyl) Iron 1,1'-Dicarboxyferrocene
  • 1,1'-Ferrocenedicarboxylic acid, 96+%
  • 1,1''-FERROCENE DICARBOXYLIC ACID, MIN. 96%
  • 1,1'-Ferrocenedicarboxylicacid,min.96%
  • 1,1'-FERROCENDICARBONSAEURE
  • Ferrocene, 1,1'-dicarboxy-
  • Ferrocene dicarboxylic acid
  • BIS(CARBOXYCYCLOPENTADIENYL)IRON

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