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TITANOCENE BIS(TRIFLUOROMETHANESULFONATE)

TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) Structure
TITANOCENE BIS(TRIFLUOROMETHANESULFONATE)
  • CAS No.76262-87-8
  • Chemical Name:TITANOCENE BIS(TRIFLUOROMETHANESULFONATE)
  • CBNumber:CB1163434
  • Molecular Formula:C12F6O6S2Ti
  • Formula Weight:466.1
  • MOL File:76262-87-8.mol
TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) Property
  • solubility sol CH2Cl2, MeNO2; insol benzene, hexane.
  • form powder to crystal
  • color Orange to Amber to Dark red
  • CAS DataBase Reference 76262-87-8
  • UNSPSC Code 12352300
  • NACRES NA.22
Safety
  • Hazard Codes  :Xi
  • Risk Statements  :36/37/38
  • Safety Statements  :26-36
  • WGK Germany  :3
  • F  :10-23
  • HS Code  :2931.90.6000
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordWarning
  • Hazard statements H315-H319-H335
  • Precautionary statements P261-P305+P351+P338
TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) Price More Price(3)
  • Brand: Sigma-Aldrich(India)
  • Product number: 416681
  • Product name : Bis(cyclopentadienyl)titanium(IV) bis(trifluoromethanesulfonate)
  • Purity: 98%
  • Packaging: 1G
  • Price: ₹12350
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: TCI Chemicals (India)
  • Product number: T1658
  • Product name : Titanocene Bis(trifluoromethanesulfonate)
  • Purity: 
  • Packaging: 100MG
  • Price: ₹3800
  • Updated: 2022/05/26
  • Buy: Buy
  • Brand: TCI Chemicals (India)
  • Product number: T1658
  • Product name : Titanocene Bis(trifluoromethanesulfonate)
  • Purity: 
  • Packaging: 1G
  • Price: ₹17800
  • Updated: 2022/05/26
  • Buy: Buy

TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) Chemical Properties,Usage,Production

  • Uses Catalyst for:
    • Transesterification
    • Stereoselective carbonyl-ene cyclization reactions
    • Sakurai reactions
    • Mukaiyama cross-aldol reactions

    Reactant for synthesis of heterobimetallic bridging dinitrogen complexes
  • Preparation TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) is prepared by treatment of a 0.06 M THF solution of Dichlorobis(cyclopentadienyl)titanium with 5.5 equiv of a 0.19 M THF solution of Silver(I) Trifluoromethanesulfonate. After stirring for 15 min the reaction mixture is filtered, the red filtrate is layered with hexane, and the resulting red crystals are collected. Recrystallization from CH2Cl2/pentane or THF/hexane affords Cp2Ti(OSO2CF3)2 (25-30%) as red needles. 
  • Application TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) is used as a catalyst for Diels-Alder reaction, Mukaiyama crossed-aldol reaction, and Sakurai reaction.
  • reaction suitability core: titanium
    reagent type: catalyst
  • storage TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) [Cp2Ti(OSO2CF3)2] and Cp2Zr(OSO2CF3)2 can be handled for short periods of time in air, but are best handled and stored in a glove box. Both can be prepared in situ. The pentamethylcyclopentadienyl analog Cp*2Ti(OH2)22+ is air and water stable. Titanium(IV) is reputed to be of low toxicity.
TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) Preparation Products And Raw materials
Raw materials
Preparation Products
TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) Suppliers
Global(47)Suppliers
  • Supplier：
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  • Email：sales8178@energy-chemical.com
  • Country：China
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TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) Spectrum
76262-87-8, TITANOCENE BIS(TRIFLUOROMETHANESULFONATE)Related Search:
  • Transition Metal Compounds
  • Titanocene, etc.
  • Ti (Titanium) Compounds
  • Metallocenes
  • Classes of Metal Compounds
  • 金属催化剂
  • 有机贵金属催化剂
  • 钛
  • Ti (Titanium) Compounds
  • Transition Metal Compounds
  • Classes of Metal Compounds
  • Metallocenes
  • Titanocene, etc.
  • Catalysis and Inorganic Chemistry
  • Titanium
  • C12H10F6O6S2Ti
  • 二茂钛二(三氟甲磺酸)
  • TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) 双(三氟甲磺酸)二茂钛
  • 双(三氟甲磺酸)二茂钛
  • 双(环戊二烯基)二(三氟甲基磺酸基)钛
  • 双(三氟甲烷磺酸)二茂钛
  • 二环戊二烯钛双(三氟甲磺酸)盐
  • 76262-87-8
  • Titanocene bis(trifluoromethanesulfonate), Di(cyclopentadienyl)titanium(IV) bis(trifluoromethanesulfonate)
  • Titanocene ditriflate
  • Bis(trifluoromethanesulfonate)dicyclopentadienyltitanium(IV)
  • Bis(cyclopentadienyl)di(triflato)titanium
  • Bis(cyclopentadienyl)bis(trifluoromethanesulfonato)titanium
  • di(cyclopentadienyl)titanium(iv) bis(trifluoromethanesulfonate)
  • TITANOCENE BIS(TRIFLUOROMETHANESULPHONATE)
  • BIS(CYCLOPENTADIENYL)TITANIUM BIS(TRIFLUOROMETHANESULFONATE)
  • BIS(CYCLOPENTADIENYL)TITANIUM(IV) BIS(TRIFLUOROMETHANESULFONATE)
  • TITANOCENE BIS(TRIFLUOROMETHANESULFONATE)

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