Ethyl 4,4,4-trifluoroacetoacetate
- Product NameEthyl 4,4,4-trifluoroacetoacetate
- CAS372-31-6
- CBNumberCB1133091
- MFC6H7F3O3
- MW184.11
- EINECS206-750-7
- MDL NumberMFCD00000424
- MOL File372-31-6.mol
Chemical Properties
| Melting point: | -39 °C |
| Boiling point: | 129-130 °C(lit.) |
| Density | 1.259 g/mL at 25 °C(lit.) |
| vapor pressure | 8hPa at 20℃ |
| refractive index | n |
| Flash point: | 84 °F |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | 10g/l |
| form | Liquid |
| pka | 7.76±0.10(Predicted) |
| Specific Gravity | 1.259 (20/4℃) |
| color | Clear colorless to slightly yellow |
| PH | 6.2 (10g/l, H2O, 20℃) |
| Water Solubility | 10 g/L (20 ºC) |
| BRN | 608353 |
| InChI | 1S/C6H7F3O3/c1-2-12-5(11)3-4(10)6(7,8)9/h2-3H2,1H3 |
| InChIKey | OCJKUQIPRNZDTK-UHFFFAOYSA-N |
| SMILES | CCOC(=O)CC(=O)C(F)(F)F |
| CAS DataBase Reference | 372-31-6(CAS DataBase Reference) |
| NIST Chemistry Reference | Butanoic acid, 4,4,4-trifluoro-3-oxo-, ethyl ester(372-31-6) |
| EPA Substance Registry System | Ethyl 4,4,4-trifluoroacetoacetate (372-31-6) |
Safety
| Symbol(GHS) |
  GHS02,GHS07 |
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| Signal word | Warning | |||||||||
| Hazard statements | H226-H302-H412 | |||||||||
| Precautionary statements | P210-P273-P301+P312+P330 | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter | |||||||||
| Hazard Codes | Xn,F,C,Xi | |||||||||
| Risk Statements | 10-22-52/53 | |||||||||
| Safety Statements | 61-16 | |||||||||
| RIDADR | UN 3272 3/PG 3 | |||||||||
| WGK Germany | 2 | |||||||||
| Hazard Note | Flammable/Corrosive | |||||||||
| TSCA | TSCA listed | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29183000 | |||||||||
| Storage Class | 3 - Flammable liquids | |||||||||
| Hazard Classifications |
Acute Tox. 4 Oral Aquatic Chronic 3 Flam. Liq. 3 |
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| REACH Registrations | Active | |||||||||
| Limited Quantities | 5.0 L (1.3 gallons) (liquid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L) | |||||||||
| NFPA 704: |
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