ChemicalBook > CAS DataBase List > (S)-(+)-KETOPINIC ACID
(S)-(+)-KETOPINIC ACID
(S)-(+)-KETOPINIC ACID
- CAS No.40724-67-2
- Chemical Name:(S)-(+)-KETOPINIC ACID
- CBNumber:CB0748218
- Molecular Formula:C10H14O3
- Formula Weight:182.22
- MOL File:40724-67-2.mol
(S)-(+)-KETOPINIC ACID Property
- Melting point 237-239 °C(lit.)
- Boiling point 313.3±25.0 °C(Predicted)
- alpha 58 º (C=1 IN CHLOROFORM)
- Density 1.238±0.06 g/cm3(Predicted)
- refractive index 25.5 ° (C=0.65, MeOH)
- storage temp. Sealed in dry,Room Temperature
- pka 3.67±0.40(Predicted)
- form powder to crystal
- color White to Almost white
- optical activity [α]23/D +58°, c = 1 in chloroform
- BRN 4180005
- CAS DataBase Reference 40724-67-2(CAS DataBase Reference)
- UNSPSC Code 12352115
- NACRES NA.22
Safety
-
Symbol(GHS)
- Signal wordWarning
- Hazard statements H315-H319-H335
- Precautionary statements P261-P264-P271-P280-P302+P352-P305+P351+P338
(S)-(+)-KETOPINIC ACID Price
More Price(3)
- Brand: Sigma-Aldrich(India)
- Product number: 420964
- Product name : (1S)-(+)-Ketopinic acid
- Purity: 99%
- Packaging: 1G
- Price: ₹6770
- Updated: 2022/06/14
- Buy: Buy
- Brand: TCI Chemicals (India)
- Product number: K0028
- Product name : (S)-(+)-Ketopinic Acid
- Purity: min. 98.0 %
- Packaging: 1G
- Price: ₹6900
- Updated: 2022/05/26
- Buy: Buy
- Brand: TCI Chemicals (India)
- Product number: K0028
- Product name : (S)-(+)-Ketopinic Acid
- Purity: min. 98.0 %
- Packaging: 5G
- Price: ₹18200
- Updated: 2022/05/26
- Buy: Buy
(S)-(+)-KETOPINIC ACID Chemical Properties,Usage,Production
- Uses 7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic Acid is a useful reactant for the preparation of alkenyl nitrile electrophiles for the possible use of covalent protein labeling.
- Uses 7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic Acid is a useful reactant for the preparation of alkenyl nitrile electrophiles for the possible use of covalent protein labeling.
-
Uses
(1S)-(+)-Ketopinic acid may be used to prepare:
- Chiral phosphine-oxazoline ligands, which can used in asymmetric palladium-catalyzed Heck reaction of aryl or alkenyl triflates with cyclic alkenes.
- A chiral imino-phosphine ligand, which can be used in palladium-catalyzed asymmetric Diels–Alder reactions to prepare six-membered carbocycles.
- A chiral iminopyridine ligand, which can be used in copper-catalyzed Henry (nitro aldol) reaction between nitromethane and o-anisol to form the corresponding β-hydroxynitroalkane.
- General Description (1S)-(+)-Ketopinic acid is a chiral ketone.
(S)-(+)-KETOPINIC ACID Preparation Products And Raw materials
Raw materials
Preparation Products
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40724-67-2, (S)-(+)-KETOPINIC ACIDRelated Search:
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- 40724-67-2
- (1<i>S</i>)-(+)-Ketopinic acid
- (+)-Ketopinic acid
- (1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid
- (S)-(+)-onepinic acid
- (1S,4R)-7,7-dimethyl-2-oxo-bicyclo[2.2.1]heptane-1-methanoic acid
- (S)-(+)-KetopinicAcid>
- 7,7-dimethyl-3-oxo-4-bicyclo[2.2.1]heptanecarboxylic acid
- (1S)-7
- (1S)-(+)-Ketopinic acid 99%
- (1S)-(+)-Ketopinic acid,(1S)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid
- Bicyclo[2.2.1]heptane-1-carboxylic acid, 7,7-dimethyl-2-oxo-, (1S,4R)-
- (4α)-2-Oxo-7,7-dimethylbicyclo[2.2.1]heptane-1β-carboxylic acid
- (1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]-1-carboxylic acid
- (1S,4R)-2-Oxobornane-10-oic acid
- rac-(1S*,4R*)-2-Oxobornane-10-oic acid
- (S)-(+)-KETOPINIC ACID
- (S)-7,7-DIMETHYL-2-OXO-BICYCLO[2.2.1]HEPTANE-1-CARBOXYLIC ACID
- (1s)-7,7-dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid
- (1S)-(+)-KETOPINIC ACID 97+%
- (1S)-(+)-KETOPINIC ACID