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L(-)-10-Camphorsulfonyl chloride

L(-)-10-Camphorsulfonyl chloride Structure
L(-)-10-Camphorsulfonyl chloride
  • CAS No.39262-22-1
  • Chemical Name:L(-)-10-Camphorsulfonyl chloride
  • CBNumber:CB0356635
  • Molecular Formula:C10H15ClO3S
  • Formula Weight:250.74
  • MOL File:39262-22-1.mol
L(-)-10-Camphorsulfonyl chloride Property
  • Melting point 66-68 °C(lit.)
  • alpha -33 º (c=3, chloroform)
  • Boiling point 349.4±15.0 °C(Predicted)
  • Density 1.331±0.06 g/cm3(Predicted)
  • storage temp. Keep in dark place,Inert atmosphere,Room temperature
  • solubility Acetone, Dichloromethane, Ethyl Acetate, Methanol
  • form Solid
  • color White
  • optical activity [α]18/D 33°, c = 3 in chloroform
  • Water Solubility Decomposes
  • Sensitive Moisture Sensitive
  • BRN 3205975
  • InChIKey BGABKEVTHIJBIW-UHFFFAOYSA-N
  • CAS DataBase Reference 39262-22-1(CAS DataBase Reference)
  • UNSPSC Code 12352115
  • NACRES NA.22
Safety
  • Hazard Codes  :C
  • Risk Statements  :34
  • Safety Statements  :26-36/37/39-45
  • RIDADR  :UN 3261 8/PG 2
  • WGK Germany  :3
  • F  :10-21
  • HazardClass  :8
  • PackingGroup  :II
  • HS Code  :29147090
  • NFPA 704:
    1
    3 0
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordDanger
  • Hazard statements H314
  • Precautionary statements P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
L(-)-10-Camphorsulfonyl chloride Price More Price(3)
  • Brand: Sigma-Aldrich(India)
  • Product number: 301949
  • Product name : (1R)-(−)-10-Camphorsulfonyl chloride
  • Purity: 97%
  • Packaging: 5G
  • Price: ₹5726.43
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: TCI Chemicals (India)
  • Product number: C1308
  • Product name : (-)-10-Camphorsulfonyl Chloride
  • Purity: 
  • Packaging: 5G
  • Price: ₹3700
  • Updated: 2022/05/26
  • Buy: Buy
  • Brand: TCI Chemicals (India)
  • Product number: C1308
  • Product name : (-)-10-Camphorsulfonyl Chloride
  • Purity: 
  • Packaging: 25G
  • Price: ₹8400
  • Updated: 2022/05/26
  • Buy: Buy

L(-)-10-Camphorsulfonyl chloride Chemical Properties,Usage,Production

  • Chemical Properties white to light yellow crystal powde
  • Uses L(-)-10-Camphorsulfonyl chloride is a useful synthetic intermediate,it is used for asymmetric hydroxylation.
  • Uses A chiral derivative of Camphor.
  • Purification Methods If free from OH bands in the IR, then recrystallise it from Et2O or pet ether; otherwise treat it with SOCl2 at 50o for 30minutes, evaporate, dry the residue over KOH in a vacuum and recrystallise it. The (±)-acid chloride has m 85o [Bartlett & Knox Org Synth 45 14 1965]. Itis characterised as the amide (prisms from EtOH) m 132o, [ ] 17 (+) and (-) 1.5o (EtOH). On repeated recrystallisation from EtOH the anilide has m 120.5-121o, [] 25 +76o (c 1, CHCl3). [Read & Storey J Chem Soc 2761 1930, Sutherland & Shriner J Am Chem Soc 58 62 1936, Halterman et al. J Am Chem Soc 109 8105 1987, Bartlet & Knox Org Synth 45 55 1945, Beilstein 11 IV 650.]
L(-)-10-Camphorsulfonyl chloride Preparation Products And Raw materials
Raw materials
Preparation Products
L(-)-10-Camphorsulfonyl chloride Suppliers
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L(-)-10-Camphorsulfonyl chloride Spectrum
39262-22-1, L(-)-10-Camphorsulfonyl chlorideRelated Search:
  • Terpenes
  • Synthetic Organic Chemistry
  • Optical Resolution
  • for Resolution of Bases
  • for Resolution of Alcohols & Thiols
  • Biochemistry
  • Bicyclic Monoterpenes
  • Chiral Reagents
  • chiral
  • Sulfonyl Chlorides
  • Pharmaceuticals
  • Intermediates & Fine Chemicals
  • Peptide
  • 其它原料及中间体
  • 高端化学
  • 合成材料中间体
  • 手性砌块
  • 稳定同位素
  • 医药中间体
  • 卤代物
  • 不对称合成
  • 中间体
  • SULFONYL CHLORIDE
  • Optical Resolution
  • for Resolution of Alcohols & Thiols
  • for Resolution of Bases
  • Terpenes
  • Bicyclic Monoterpenes
  • C10H15O3Cl
  • (-)-10-樟脑磺酰氯*5
  • 左旋樟脑磺酰氯(樟脑磺酸杂质2)
  • ((1R,4S)-7,7-二甲基-2-氧代双环[2.2.1]庚烷-1-基)甲烷磺酰氯
  • (-)-10-CAMPHORSULFONYL CHLORIDE (-)-10-樟脑磺酰氯
  • (1R)-(-)-樟脑-10-磺酰氯
  • 左旋樟脑-10-磺酰氯(+4℃)
  • ()-樟脑-10-磺酰氯
  • (1R)-(-)-樟脑-10-磺酰氯,97%
  • (-)-10-樟脑磺酰氯
  • L-(-)-10-樟脑磺酰氯
  • (1R)-(-)-10-樟脑磺酰氯
  • 左旋樟脑磺酰
  • L-(-)-樟脑-10-磺酰氯
  • (-)-樟脑-10-磺酰氯
  • (1R)-(-)-樟脑-10-磺酰氯(冷库)
  • (1<I>R</I>)-(-)-10-樟脑磺酰氯
  • (-)-10-樟脑磺酰氯,97%
  • 左旋樟脑-10-磺酰氯
  • 左旋樟脑磺酰氯
  • (-)-10-樟脑磺酸氯
  • 39262-22-1
  • (-)-Camphor-10-sulfonyl chloride
  • ((1R,4S)-7,7-DiMethyl-2-oxobicyclo[2.2.1]heptan-1-yl)Methanesulfonyl chloride
  • [3-(chlorosulfonylmethyl)-2,2,3-trimethylcyclopentyl]methanesulfonyl chloride
  • (-)-10-Camphorsulfonyl Chloride
  • L-(-)-1-Camphorsulfonyl chloride
  • (+)-camphor-10-sulfonyl chloride
  • L(-)-10-Camphorsulfonyl chloride USP/EP/BP
  • (1R)-(-)-10-CamphorsuL

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