ChemicalBook > CAS DataBase List > (Carbomethoxymethyl)triphenylphosphonium bromide
(Carbomethoxymethyl)triphenylphosphonium bromide
(Carbomethoxymethyl)triphenylphosphonium bromide
- CAS No.1779-58-4
- Chemical Name:(Carbomethoxymethyl)triphenylphosphonium bromide
- CBNumber:CB0254687
- Molecular Formula:C21H20BrO2P
- Formula Weight:415.26
- MOL File:1779-58-4.mol
(Carbomethoxymethyl)triphenylphosphonium bromide Property
- Melting point 165-170 °C (dec.) (lit.)
- storage temp. Inert atmosphere,Room Temperature
- solubility Soluble in methanol(almost transparency).
- form solid
- color White to Almost white
- Sensitive Hygroscopic
- BRN 3812975
- InChIKey VCWBQLMDSMSVRL-UHFFFAOYSA-M
- CAS DataBase Reference 1779-58-4(CAS DataBase Reference)
- UNSPSC Code 12352108
- NACRES NA.22
Safety
- Hazard Codes :Xi
- Risk Statements :36/37/38
- Safety Statements :26-36-37/39
- WGK Germany :3
- F :9
- HS Code :29319019
-
NFPA 704:
1 2 0
-
Symbol(GHS)
- Signal wordWarning
- Hazard statements H315-H319-H335
- Precautionary statements P261-P264-P271-P280-P302+P352-P305+P351+P338
(Carbomethoxymethyl)triphenylphosphonium bromide Price
More Price(6)
- Brand: Sigma-Aldrich(India)
- Product number: 259063
- Product name : (Methoxycarbonylmethyl)triphenylphosphonium bromide
- Purity: 98%
- Packaging: 50G
- Price: ₹2630.48
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: 259063
- Product name : (Methoxycarbonylmethyl)triphenylphosphonium bromide
- Purity: 98%
- Packaging: 250G
- Price: ₹8281.13
- Updated: 2022/06/14
- Buy: Buy
- Brand: ALFA India
- Product number: ALF-A16301-36
- Product name : (Methoxycarbonylmethyl)triphenylphosphonium bromide, 98+%
- Purity:
- Packaging: 500g
- Price: ₹23051
- Updated: 2022/05/26
- Buy: Buy
- Brand: ALFA India
- Product number: ALF-A16301-22
- Product name : (Methoxycarbonylmethyl)triphenylphosphonium bromide, 98+%
- Purity:
- Packaging: 100g
- Price: ₹7161
- Updated: 2022/05/26
- Buy: Buy
- Brand: ALFA India
- Product number: ALF-A16301-14
- Product name : (Methoxycarbonylmethyl)triphenylphosphonium bromide, 98+%
- Purity:
- Packaging: 25g
- Price: ₹2411
- Updated: 2022/05/26
- Buy: Buy
(Carbomethoxymethyl)triphenylphosphonium bromide Chemical Properties,Usage,Production
- Chemical Properties white powder
- Uses (Methoxycarbonylmethyl)triphenylphosphonium bromide is a reactant for the synthesis of GSK-3 inhibitors using the Wittig reaction, substituted furanones for antifungal and cytostatic activities, photochromic dithienylethene derivatives, gem-diiodoalkanes containing allylic alcohols and highly substituted cyclopentenes and brazilanes via Au-catalyzed deoxygenative Nazarov cyclization. As reactant for asymmetric hydrogenation of α,β-unsaturated ester-phosphonates, studies of thermal decomposition of phosphonium alkyl ester salts.
- reaction suitability reaction type: C-C Bond Formation
- Purification Methods Wash it with pet ether (b 40-50o), recrystallise it from CHCl3/Et2O and dry it at high vacuum at 65o. [Isler et al. Helv Chim Acta 40 1242 1957, Wittig & Haag Chem Ber 88 1654, 1664 1955, Beilstein 16 IV 981.]
(Carbomethoxymethyl)triphenylphosphonium bromide Preparation Products And Raw materials
Raw materials
Preparation Products
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- (Carbomethoxymethyl)triphenylphosphonium bromide(1779-58-4)MS(Carbomethoxymethyl)triphenylphosphonium bromide(1779-58-4)1HNMR(Carbomethoxymethyl)triphenylphosphonium bromide(1779-58-4)IR1(Carbomethoxymethyl)triphenylphosphonium bromide(1779-58-4)IR2(Carbomethoxymethyl)triphenylphosphonium bromide(1779-58-4)Raman
1779-58-4, (Carbomethoxymethyl)triphenylphosphonium bromideRelated Search:
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- bc0001
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- Olefination
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- Wittig Reaction
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- Phosphonium Compounds
- C-C Bond Formation
- C21H20O2PBr
- CH3OCOCH2PBrC6H53
- CH3O2CCH2PC6H53Br
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- 1779-58-4
- (methyloxycarbonylmethyl)triphenylphosphonium bromide
- (2-methoxy-2-oxoethyl)-triphenylphosphanium
- (2-methoxy-2-oxoethyl)-triphenylphosphanium,bromide
- Methoxycarbonylmethyl(triphenyl)phosphoniumBromide>
- (2-methoxycarbonylphenyl)-methyl-diphenylphosphonium bromide
- NSC 136109
- (MethoxycarbonylMethyl)triphenylphosphoniuM broMide, 98+%, 98+%
- MethoxycarbonylMethyl)triphenylphosphoniuM broMi
- Triphenyl(methoxycarbonylmethyl)phosphonium·bromide
- Triphenyl(2-oxo-2-methoxyethyl)phosphonium·bromide
- (2-Oxo-2-methoxyethyl)triphenylphosphonium·bromide
- CMMTPPB