(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE

Reaction

1. Chiral ligands for copper-catalyzed asymmetric allylic alkylation with dialkylzincs.
2. Chiral ligands for copper-catalyzed asymmetric conjugate addition of diethylzinc to enones.
3. Chiral ligands for palladium-catalyzed asymmetric hydrosilylation of styrenes
4. Chiral ligands for copper-catalyzed asymmetric ring-opening of oxabicyclic alkenes with Grignard reagents.
5. Chiral ligands for nickel-catalyzed asymmetric hydrovinylation of α-alkyl vinylarenes.
6. Chiral ligands for iridium-catalyzed asymmetric hydrogenation of cyclic enamines.
7. Chiral ligands for iridium-catalyzed asymmetric hydrogenation of cyclic imines.
8. Chiral ligands for gold-catalyzed asymmetric [2 + 2] cycloaddition reaction.
9. Chiral ligands for rhodium-catalyzed asymmetric hydroacylation of salicylaldehydes to homoallylic sulfides.
10. Chiral ligands for palladium-catalyzed asymmetric carboamination reactions. 

Uses

• Spiroindolenines by Pd-catalyzed intramolecular dearomative arylation of haloaryl-3-substituted indoles.
• Enantioselective conjugate addition compound by Cu-catalyzed 1,4-addition of diethylzinc (Et₂Zn) to cyclic enones.
• Octaketide natural products via rhodium-phosphoramidite catalyzed alkene hydroacylation.