Reaction
A versatile ligand for asymmetric catalysis.
(a) Conjugate addition of hydrazoic acid to unsaturated imides.
(b) Formation of cyanohydrins from aldehydes.
(c) Desymmetrization of meso-epoxides with azide.
(d) Hetero Diels-Alder reaction.
(e) Nozaki-Hiyama reaction.
(f) Reagent used for the Passerini, three-component reaction.
Chemical Properties
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE is yellow powder
Uses
(
S,
S)-(+)-
N,
N′-Bis(3,5-di-
tert-butylsalicylidene)-1,2-cyclohexanediamine is a chiral salen-type ligand used for preparing Jacobsen′s catalyst suitable for enantioselective epoxidation of olefins lacking functional groups.
Uses
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE is a versatile ligand used in the preparation of Jacobsen's catalyst.
