(3S,3'S,4S,4'S,11bS,11'bS)-(+)-4,4'-Di-t-butyl-4,4',5,5'-tetrahydro-3,3'-bi-3H-dinaphtho[2,1-c:1',2'-e]phosphepin

Reaction

1. Rhodium complex used in asymmetric hydroformylation reactions.
2. Ligand-palladium complex used in enantioselective carbonyl-ene reactions.
3. Nickel-catalyzed asymmetric transfer hydrogenation of olefins for the synthesis of αand βamino acids.
4. Nickel-catalyzed asymmetric transfer hydrogenation of hydrazones and other ketimines.
5. Nickel/ligand catalyst used in the enantioselective reductive amination of ketones with both arylamines and benzhydrazide,
6. Rh-Binapine and Pd-Binapine complexes form excellent catalysts for asymmetric (transfer) hydrogenation of aryl substituted olefins to form β-amino acids.