Natriummetavanadat

Bezeichnung:Natriummetavanadat

CAS-Nr13718-26-8

Englisch Name:Sodium metavanadate

CBNumberCB9853081

SummenformelNaO3V

Molgewicht121.93

MOL-Datei13718-26-8.mol

Synonyma

Natriummetavanadat

Natriummetavanadat physikalisch-chemischer Eigenschaften

Schmelzpunkt	600 °C
Dichte	3.241 g/cm3
storage temp.	Sealed in dry,Room Temperature
Aggregatzustand	Powder
Farbe	White to faintly yellow-beige or pale green
Geruch (Odor)	Odorless
Wasserlöslichkeit	Soluble in water.
Merck	14,8700
Expositionsgrenzwerte	NIOSH: Ceiling 0.05 mg/m3
Stabilität	Stable.
InChI	InChI=1S/Na.3O.V/q+1;;;-1;
InChIKey	CMZUMMUJMWNLFH-UHFFFAOYSA-N
SMILES	[V]([O-])(=O)=O.[Na+]
CAS Datenbank	13718-26-8(CAS DataBase Reference)
EPA chemische Informationen	Sodium vanadate (13718-26-8)

Sicherheit

Kennzeichnung gefährlicher	T
R-Sätze:	25-36/37/38
S-Sätze:	26-36/37/39-45
RIDADR	UN 3285 6.1/PG 3
WGK Germany	3
RTECS-Nr.	YW1050000
TSCA	Yes
HazardClass	6.1
PackingGroup	II
HS Code	28419000

Gefahreninformationscode (GHS)

Sodium metavanadate Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R25:Giftig beim Verschlucken.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
Chemische Eigenschaften
Sodium vanadate, sodium orthovanadate, Na3VO4, white solid, soluble, formed by fusion of vanadium pentoxide and sodium carbonate. Used (1) in inks, (2) in photography, (3) in dyeing of furs, (4) in inoculation of plant life.
Verwenden
Sodium metavanadate is used as an analytical reagent and mordant. It is also found to be useful in the photography industry and the pharmaceutical industry. In addition to this, it is used in the making of vanadium alloy and vanadium catalyst.
Verwenden
Vanadium is a metallic element that occurs in six oxidation states and numerous inorganic compounds. Some of the more important compounds are vanadium pentoxide (V2O5), sodium metavanadate (NaVO3), sodium orthovanadate (Na3VO4), vanadyl sulfate (VOSO4), and ammonium vanadate (NH4VO3). Vanadium is used primarily as an alloying agent in steels and non-ferrous metals (ATSDR, 1990). Vanadium compounds are also used as catalysts and in chemical, ceramic or specialty applications.
Verwenden
Sodium metavanadate (SMV) is a vanadium salt that can be used as a corrosion inhibitor with good inhibition efficiency (98%) at 200 ppm. It can be used in the protection of carbon steel.
Definition
ChEBI: Sodium metavanadate is an inorganic sodium salt having metavanadate as the counterion. It contains a metavanadate.
synthetische
sodium metavanadate synthesis: Dissolve vanadium pentoxide in sodium hydroxide solution, crystallized by concentration, that is, the finished product of sodium metavanadate.
V2O5+2NaOH→2NaVO3+H2O
Allgemeine Beschreibung
Colorless to yellow crystals or cream colored solid. Melting point 630°C.
Air & Water Reaktionen
Soluble in water.
Reaktivität anzeigen
Sodium metavanadate is a moderately strong oxidizing agent [Cotton and Wilkinson].
Hazard
Toxic by ingestion.
Health Hazard
Vanadium pentoxide and sodium metavanadate have a toxicity rating of 5, equivalent to a probable lethal oral dose in humans of 5-50 mg/kg (Gosselin et al., 1984). The elemental metallic form is considered to be non-toxic.
Stokinger et al. (1953) reported that a 10% solution of sodium metavanadate is a primary irritant to human skin. Saturated solutions of ammonium metavanadate (0.5%) and vanadium pentoxide (0.8% solution) did not irritate the skin. Sjoberg (1951) reported that several workers occupationally exposed to vanadium developed what appeared to be a contact dermatitis and that in one case, skin patch tests produced eczematous lesions indicative of an allergic reaction.
COMMENTS: The NOAEL is derived from a study in which rats were given 0, 5, 10 and 50 ppm sodium metavanadate, in drinking water for 3 months. Impaired kidney function was seen at 50 ppm, and 10 ppm was considered a NOAEL. The Uncertainty Factor of 100 is the product of a 10-fold uncertainty in extrapolating from laboratory animals to humans and a 10-fold uncertainty to protect sensitive individuals.
Brandgefahr
Flash point data of Sodium metavanadate are not available. Sodium metavanadate is probably nonflammable.
Flammability and Explosibility
Non flammable
Sicherheitsprofil
Poison by ingestion, intraperitoneal, subcutaneous, and intravenous routes. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of Na2O and VOx. See also VANADIUM COMPOUNDS.

Sodium metavanadate Upstream-Materialien And Downstream Produkte

Natriummetavanadat Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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