(chlorodifluoroMethyl)triMethylsilane

Gefahreninformationscode (GHS)

• Bildanzeige (GHS)

  

• Alarmwort

  Achtung

• Gefahrenhinweise

  H225：Flüssigkeit und Dampf leicht entzündbar.

• Sicherheit

  P210：Von Hitze, heißen Oberflächen, Funken, offenen Flammen und anderen Zündquellenarten fernhalten. Nicht rauchen.

(chlorodifluoroMethyl)triMethylsilane Chemische Eigenschaften,Einsatz,Produktion Methoden

• Verwenden

  (Chlorodifluoromethyl)trimethylsilane, is one of the partially fluorinated compounds, which are often used for diverse applications in materials science, agrochemistry, and the pharmaceutical industry.

• Verwenden

  (chlorodifluoroMethyl)triMethylsilane，also known as Hu reagent，it can be used to generate difluorocarbene at higher temperatures catalyzed by chloride ion.

• Reaktionen

  (1) Difluoromethylenation of alkenes.
  
  Refs. 1) Angew. Chem. Int. Ed. 2011, 50, 7153 –7157; 2) Chem. Commun. 2011, 47, 2411–2413.
  (2) Difluoromethylenation of alkynes.
  
  Refs. 1) Angew. Chem. Int. Ed. 2011, 50, 7153 –7157; 2) Chem. Commun. 2011, 47, 2411–2413.
  (3) Difluoromethylenation of TMSCN.
  
  Ref. J. Org. Chem. 2012, 77, 5850?5855.
  (4) Difluoromethylenation of benzyl and alkylzinc halides.
  
  Ref. Org. Lett. 2013, 15, 917 – 919.
  (5) Fluorination aminocarbonylation of aldehydes
  
  Ref. Angew. Chem. Int. Ed. 2022, e202115467

• Einzelnachweise

  [1]Angewandte Chemie International Edition.DOI :10.1002/anie.202283811
  [2]The Journal of Organic Chemistry.DOI :10.1021/acs.orglett.2c02899

(chlorodifluoroMethyl)triMethylsilane Upstream-Materialien And Downstream Produkte

(chlorodifluoroMethyl)triMethylsilane Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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