2-BUTANOL Struktur

(±)-Butan-2-ol

Bezeichnung:(±)-Butan-2-ol

CAS-Nr15892-23-6

Englisch Name:2-BUTANOL

CBNumberCB8441652

SummenformelC4H10O

Molgewicht74.12

MOL-Datei15892-23-6.mol

Synonyma

(±)-Butan-2-ol

(±)-Butan-2-ol physikalisch-chemischer Eigenschaften

Schmelzpunkt	−115 °C(lit.)
Siedepunkt	98 °C(lit.)
Dichte	0.808 g/mL at 25 °C(lit.)
Dampfdichte	2.6 (vs air)
Dampfdruck	12.5 mm Hg ( 20 °C)
Brechungsindex	n20/D 1.397(lit.)
Flammpunkt	80 °F
CAS Datenbank	15892-23-6(CAS DataBase Reference)

Sicherheit

Kennzeichnung gefährlicher	Xi
R-Sätze:	10-36/37-67
S-Sätze:	13-24/25-26-46-7/9
RIDADR	UN 1120 3/PG 3
OEB	A
OEL	TWA: 100.0 ppm; 305.0 mg/m3, STEL: 150.0 ppm; 455.0 mg/m3
WGK Germany	1
RTECS-Nr.	EO1750000
HS Code	29051420
Toxizität	dog,LDLo,oral,2400mg/kg (2400mg/kg),National Technical Information Service. Vol. OTS0572377,

Gefahreninformationscode (GHS)

2-BUTANOL Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R10:Entzündlich.
R36/37:Reizt die Augen und die Atmungsorgane.
R67:Dämpfe können Schläfrigkeit und Benommenheit verursachen.
S-Sätze Betriebsanweisung:
S13:Von Nahrungsmitteln, Getränken und Futtermitteln fernhalten.
S24/25:Berührung mit den Augen und der Haut vermeiden.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S46:Bei Verschlucken sofort ärztlichen Rat einholen und Verpackung oder Etikett vorzeigen.
S7/9:Behälter dicht geschlossen an einem gut gelüfteten Ort aufbewahren.
Definition
ChEBI: Butan-2-ol is a secondary alcohol that is butane substituted by a hydroxy group at position 2. It derives from a hydride of a butane.
mögliche Exposition
Butyl alcohols are used as solvents for paints, lacquers, varnishes, natural and synthetic resins, gums, vegetable oils, dyes, camphor, and alkaloids. They are also used as an intermediate in the manufacture of pharmaceuticals and chemicals; in the manufacture of artificial leather, safety glass; rubber and plastic cements, shellac, raincoats, photographic films, perfumes; and in plastic fabrication.
Versand/Shipping
UN1120 Butanols, Hazard Class: 3; Labels: 3— Flammable liquid. UN1212 Isobutanol or Isobutyl alcohol, Hazard Class: 3; Labels: 3—Flammable liquid
läuterung methode
Purification methods are the same as for n-Butanol. These include drying with K2CO3 or CaSO4, followed by filtration and fractional distillation, refluxing with CaO, distillation, then refluxing with magnesium and redistillation, and refluxing with, then distilling from CaH2. Calcium carbide has also been used as a drying agent. The anhydrous alcohol is obtained by refluxing with sec-butyl phthalate or succinate. (For method see Ethanol.) Small amounts of alcohol can be purified via conversion to the alkyl hydrogen phthalate and recrystallisation [Hargreaves J Chem Soc 3679 1956]. For purification of optical isomers, see Timmermans and Martin [J Chem Phys 25 411 1928]. [Beilstein 2 III 1566.]
Inkompatibilitäten
Butyl alcohols may form explosive mixture with air. In all cases they are Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Attacks some plastics, rubber and coatings. n-Butanol is incompatible with strong acids; halogens, caustics, alkali metals; aliphatic amines; isocyanates. sec-Butanol forms an explosive peroxide in air. Ignites with chromium trioxide. Incompatible with strong oxidizers; strong acids; aliphatic amines; isocyanates, organic peroxides. tert-Butanol is incompatible with strong acids (including mineral acid), including mineral acids; strong oxidizers or caustics, aliphatic amines; isocyanates, alkali metals (i.e., lithium, sodium, potassium, rubidium, cesium, francium). isoButanol is incompatible with strong acids; strong oxidizers; caustics, aliphatic amines; isocyanates, alkali metals and alkali earth. May react with aluminum at high temperatur
Waste disposal
Incineration, or bury absorbed waste in an approved land fill.

2-BUTANOL Upstream-Materialien And Downstream Produkte

(±)-Butan-2-ol Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

15892-23-6, 2-BUTANOL Verwandte Suche:

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