Trimethylentrinitramin

Bezeichnung:Trimethylentrinitramin

CAS-Nr121-82-4

Englisch Name:HEXAHYDRO-1,3,5-TRINITRO-1,3,5-TRIAZINE

CBNumberCB6714556

SummenformelC3H6N6O6

Molgewicht222.12

MOL-Datei121-82-4.mol

Synonyma

Perhydro-1,3,5-trinitro-1,3,5-triazin

Trimethylentrinitramin

1,3,5-Triaza-1,3,5-trinitrocyclohexan

Trimethylentrinitramin physikalisch-chemischer Eigenschaften

Schmelzpunkt	205-206°
Siedepunkt	363.28°C (rough estimate)
Dichte	d420 1.82
Dampfdruck	0Pa at 20℃
Brechungsindex	1.6700 (estimate)
Flammpunkt	2℃
storage temp.	2-8°C
pka	-15.06±0.20(Predicted)
Aggregatzustand	Colorless crystals
Wasserlöslichkeit	59.75mg/L(25 ºC)
Expositionsgrenzwerte	TLV-TWA skin 1.5 mg/m³ (ACGIH and MSHA).
Stabilität	Unstable. Explosive.
LogP	0.87 at 23℃
EPA chemische Informationen	Cyclonite (121-82-4)

Sicherheit

Kennzeichnung gefährlicher	F,T,Xn,E
R-Sätze:	11-23/24/25-36/37/38-36-20/21/22-3
S-Sätze:	16-27-45-36/37-35-26
RIDADR	0072
OEB	B
OEL	TWA: 1.5 mg/m3, STEL: 3 mg/m3 [skin]
WGK Germany	2
HazardClass	1.1D
HS Code	29339900
Giftige Stoffe Daten	121-82-4(Hazardous Substances Data)
Toxizität	LD50 oral in rat: 100mg/kg

Gefahreninformationscode (GHS)

HEXAHYDRO-1,3,5-TRINITRO-1,3,5-TRIAZINE Chemische Eigenschaften,Einsatz,Produktion Methoden

ERSCHEINUNGSBILD
WEISSES KRISTALLINES PULVER ODER FARBLOSE KRISTALLE
CHEMISCHE GEFAHREN
Bei Stoß, Reibung oder Erschütterung explosionsartige Zersetzung möglich. Kann beim Erhitzen unter Bildung von Stickoxiden explodieren. Reagiert mit starken Oxidationsmitteln und brennbaren Stoffen
ARBEITSPLATZGRENZWERTE
TLV: 0.5 mg/m?als TWA Hautresorption Krebskategorie A4 (nicht klassifizierbar als krebserzeugend für den Menschen); (ACGIH 2006).
MAK nicht festgelegt.
AUFNAHMEWEGE
Aufnahme in den Körper in gefährlichen Mengen durch Inhalation und durch Verschlucken.
INHALATIONSGEFAHREN
Eine gesundheitsschädliche Partikelkonzentration in der Luft kann schnell erreicht werden.
WIRKUNGEN BEI KURZZEITEXPOSITION
WIRKUNGEN BEI KURZZEITEXPOSITION:
Möglich sind Auswirkungen auf das Zentralnervensystem mit Reizbarkeit, Schlaflosigkeit, Krämpfen und Bewusstlosigkeit.
WIRKUNGEN NACH WIEDERHOLTER ODER LANGZEITEXPOSITION
Möglich sind Auswirkungen auf das Zentralnervensystem. Wiederholter oder andauernder Hautkontakt kann Dermatitis hervorrufen.
LECKAGE
Gefahrenbereich verlassen! Fachmann zu Rate ziehen! Zündquellen entfernen. NICHT in die Umwelt gelangen lassen.
R-Sätze Betriebsanweisung:
R11:Leichtentzündlich.
R23/24/25:Giftig beim Einatmen, Verschlucken und Berührung mit der Haut.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S16:Von Zündquellen fernhalten - Nicht rauchen.
S27:Beschmutzte, getränkte Kleidung sofort ausziehen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
Beschreibung
Hexahydro-1,3,5-trinitro-s-triazine is a whitecrystalline compound; Boiling point=.260℃; Freezing/Melting point=203-204℃; Exothermicdecomposition=100℃; Hazard Identification (based onNFPA-704 M Rating System): Health 2, Flammability(explosive), Reactivity (see incompatibilities). Insoluble inwater
Chemische Eigenschaften
Hexahydro-1,3,5-trinitro-S-triazine is a white crystalline compound.
Verwenden
High explosive; rodenticide.RDX is a convulsant.
Verwenden
Cyclonite is a high explosive and principal constituent of plastic bombs. It is preparedby treating hexamethylenetetramine with nitric acid,ammoniumnitrate,andaceticanhydride: It is also used as a rat poison.
Definition
Cyclonite: A highly explosive nitrocompound, (CH₂N.NO₂)₃. It has acyclic structure with a six-memberedring of alternating CH₂ groups andnitrogen atoms, with each nitrogenbeing attached to a NO₂ group. It ismade by nitrating hexamine,C6H12N4, which is obtained from ammoniaand methanal. Cyclonite is avery powerful explosive used mainlyfor military purposes. It is also calledRDX. The abbreviation is for ‘ResearchDepartment composition X’,used at the Chemical Research andDevelopment Department, Woolwich.
Definition
ChEBI: An N-nitro compound that is 1,3,5-triazinane in which all three of the hydrogens attached to the nitrogens have been replaced by nitro groups. It is widely used in both industrial and military explosives.
Allgemeine Beschreibung
Cyclotrimethylene trinitramine is an explosive. The explosion can be initiated by a sudden shock, high temperature or a combination of the two. The primary hazard is from blast effect and not from flying projectiles and fragments. Under prolonged exposure to heat or fire they can explode.
Air & Water Reaktionen
Insoluble in water.
Reaktivität anzeigen
CYCLOTRIMETHYLENE TRINITRAMINE is incompatible with strong oxidizing agents, combustible materials and heat. Detonates on contact with mercury fulminate . Danger of explosion when dry. The self heating and explosive decomposition of the explosive and aqueous alkali (calcium hydroxide) has been studied, [Chem Abs., 1988, 109, 112968].
Health Hazard
Cyclonite is a highly toxic substance. Repeated exposure can cause nausea, vomiting, and convulsions.
LD50 value, oral (rats): 100 mg/kg.
Brandgefahr
MAY EXPLODE AND THROW FRAGMENTS 1600 meters (1 MILE) OR MORE IF FIRE REACHES CARGO.
Sicherheitsprofil
Poison by ingestion, intraperitoneal, and intravenous routes. An experimental teratogen. Other experimental reproductive effects. A corrosive irritant to skin, eyes, and mucous membranes. Cases of epileptifonn convulsions have been reported from exposure. It is one of the most powerful high explosives in use today. Has more shattering power than TNT and is often mixed with TNT as a bursting charge for aerial bombs, mines, and torpedoes. It is easily initiated by mercury fulrmnate, which may be used as a booster. When heated to decomposition it emits toxic fumes of NOx. See also MINES, NITRATES, and EXPLOSIVES, HIGH.
mögliche Exposition
A potential danger to those involved in the manufacture of this material and its handling in munitions and solid-propellant manufacture. It is also used as a rat poison; a powerful military explosive; a base charge for detonators; and in plastic explosives.
Erste Hilfe
If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medcal attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.
Lager
Explosive. Color Code—Red Stripe: FlammabilityHazard: Store separately from all other flammable materals. Prior to working with this chemical you should betrained on its proper handling and storage. Detached storagein a secure area is recommended. Store in tightly closedcontainers in a cool well-ventilated area away from otherexplosives, combustibles, or strong oxidizers (such as chlorine, bromine, and fluorine). Also keep cyclonite away fromshock and heat sources. Use only nonsparking tools andequipment, especially when opening and closing containersof this chemical. Sources of ignition, such as smoking andopen flames, are prohibited where this chemical is used,handled, or stored in a manner that could create a potentialfire or explosion hazard. Wherever this chemical is used,handled, manufactured, or stored, use explosion-proof electrical equipment and fittings.
Versand/Shipping
UN0483 Cyclotrimethylenetrinitramine, desensi- tized or Cyclonite, desensitized or Hexogen, desensitized or RDX, desensitized, Hazard Class: 1D; Labels: 1D- Explosive (with a mass explosion hazard); D-Substances or articles which may mass detonate (with blast and/or frag- ment hazard) when exposed to fire. UN0072 Cyclotrimethylenetrinitramine, wetted or Cyclonite, wetted or Hexogen, wetted or RDX, wetted with not ,15% water by mass, Hazard Class: 1D; Labels: 1D-Explosive (with a mass explosion hazard); D-Substances or articles which may mass detonate (with blast and/or fragment hazard) when exposed to fire.
läuterung methode
RDX crystallises from acetone. [Bachmann & Sheehan J Am Chem Soc 71 1842 1949, Beilstein 26 II 5, 26 III/IV 22.] EXPLOSIVE.
Inkompatibilitäten
Heat, physical damage, shock, and deto- nators. Detonates on contact with mercury fulminate. Keep away from other explosives, combustibles, oxidizers (such as chlorates, nitrates, perchlorates, permanganates, perox- ides; bromine, chlorine, and fluorine); reducing agents; and aqueous alkaline solutions.
Waste disposal
Pour over soda ash, neutralize and flush to sewer with water. Also HMX may be recov- ered from solid propellant waste.

HEXAHYDRO-1,3,5-TRINITRO-1,3,5-TRIAZINE Upstream-Materialien And Downstream Produkte

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