Nickel sulfate hexahydrate

Bezeichnung:Nickel sulfate hexahydrate

CAS-Nr10101-97-0

Englisch Name:Nickel sulfate hexahydrate

CBNumberCB6257493

SummenformelH4NiO5S

Molgewicht174.78

MOL-Datei10101-97-0.mol

Nickel sulfate hexahydrate physikalisch-chemischer Eigenschaften

Schmelzpunkt	1453 °C(lit.)
Siedepunkt	2732 °C(lit.)
Dichte	2,07 g/cm³
Dampfdichte	2.07 (vs air)
storage temp.	Store at +5°C to +30°C.
Löslichkeit	H₂O: soluble
Aggregatzustand	wire
Farbe	Green
Wichte	2.07
PH	4.3-4.7 (100g/l, H2O, 20℃)
Wasserlöslichkeit	625 g/L (20 ºC)
Merck	14,6517
Expositionsgrenzwerte	ACGIH: TWA 0.1 mg/m3 NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
Stabilität	Stable. Efflorescent. Incompatible with strong acids, sulfur, nickel nitrate, wood, other combustibles.
InChIKey	RRIWRJBSCGCBID-UHFFFAOYSA-L
CAS Datenbank	10101-97-0(CAS DataBase Reference)
EPA chemische Informationen	Nickel(II) sulfate hexahydrate (10101-97-0)

Sicherheit

Kennzeichnung gefährlicher	T,Xi,N,Xn,F
R-Sätze:	45-52/53-50/53-42/43-40-22-36/37-23/24/25-11-36/38-68-48/23-38-20/22-61-49-43-51/53-34-48/20
S-Sätze:	53-45-61-60-36/37-22-36/37/39-26-16-23
RIDADR	UN 3178 4.1/PG 2
WGK Germany	3
RTECS-Nr.	WT1157000
TSCA	Yes
HazardClass	6.1
PackingGroup	III
HS Code	28332400
Toxizität	LD50 in male, female rats (mg/kg): 335, 264 orally (Reagan)

Gefahreninformationscode (GHS)

Nickel sulfate hexahydrate Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R45:Kann Krebs erzeugen.
R52/53:Schädlich für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
R50/53:Sehr giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
R42/43:Sensibilisierung durch Einatmen und Hautkontakt möglich.
R40:Verdacht auf krebserzeugende Wirkung.
R22:Gesundheitsschädlich beim Verschlucken.
R36/37:Reizt die Augen und die Atmungsorgane.
R23/24/25:Giftig beim Einatmen, Verschlucken und Berührung mit der Haut.
R11:Leichtentzündlich.
R36/38:Reizt die Augen und die Haut.
S-Sätze Betriebsanweisung:
S53:Exposition vermeiden - vor Gebrauch besondere Anweisungen einholen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
S60:Dieses Produkt und sein Behälter sind als gefährlicher Abfall zu entsorgen.
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S22:Staub nicht einatmen.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S16:Von Zündquellen fernhalten - Nicht rauchen.
Chemische Eigenschaften
Nickel sulphate hexahydrate is available as odourless, blue-green crystals. It is stable at room temperature in closed containers under normal storage and handling conditions and incompatible with strong acids and strong oxidising agents. On decomposition, nickel (II) sulphate hydroxylate releases oxides of sulphur, irritating and toxic fumes and gases, and nickel oxide.
Verwenden
Nickel sulfate hexahydrate is mainly used in Ni plating, as mordant in dyeing and in printing textiles, as a blackening agent for zinc and brass and in the fabrication of organic nickel salts. It is used as an effective catalyst for gas-phase dehydration of glycerol to acrolein. Nickel sulfate hexahydrate crystal is an efficient ultraviolet filter material. Columns used in biochemistry and molecular biology can be regenerated with nickel sulfate. It is used to prepare nickel carbonate, a precursor to pigments and nickel-based catalysts.
Verwenden
Source of nickel in standards.
Verwenden
Nickel sulfate hexahydrate is a source of nickel metal, a common allergen present in various alloys, electroplated metal, earrings, lipstick holders, watches, buttons, zippers, rings, utensils, tools, instruments, batteries, machinery parts, working solutions of metal cutting fluids, nickel plating for alloys, coins, pigments, dentures, orthopedic plates, keys, scissors, razors, spectacle frames, kitchenware etc. May produce erythema multiforme like eruptions.
Definition
ChEBI: A hydrate that is the hexahydrate of nickel sulfate.
Allgemeine Beschreibung
Blue or emerald-green crystalline material. Toxic and carcinogenic. Two known phases. Alpha-form (blue tetragonal) converts to beta-form (green monoclinic) at 127.9°F. Becomes blue and opaque at room temperature. Odorless. Sweet astringent taste. Somewhat efflorescent. Greenish-yellow anhydrous salt is formed at 536°F.
Air & Water Reaktionen
Nickel sulphate is used in the laboratory. Accidental workplace exposures to nickel sulphate hexahydrate by ingestion/inhalation and/or skin absorption cause toxicity and adverse health effects. It causes irritation to the respiratory tract. The symptoms include, but are not limited to, coughing, sore throat, shortness of breath, respiratory distress, lung allergy with asthma-type symptoms, abdominal pain, diarrhoea, nausea, vomiting, giddiness, capillary damage, myocardial weakness, central nervous system depression, and kidney and liver damage. Workers/persons with pre-existing skin disorders, impaired respiratory or pulmonary function, and history of asthma, allergies, or sensitisation to nickel compounds may be at an increased risk upon exposure to nickel sulphate hexahydrate and nickel compounds. Reports of ACGIH list nickel sulphate hexahydrate as Group A4, meaning not classifiable as a human carcinogen; the NIOSH list it as an occupational carcinogen (listed as Nickel); the NTP lists it as a suspect carcinogen (listed as Nickel); the OSHA classifies it as a possible human carcinogen (listed as Nickel); and the IARC classifies nickel sulphate hexahydrate as Group 2B carcinogen (listed as Nickel), meaning possibly carcinogenic to humans. Reports are available suggesting sufficient evidences in humans for the carcinogenicity of nickel compounds and their combinations encountered in the nickel refining industry.
Reaktivität anzeigen
Nickel sulfate hexahydrate is incompatible with strong acids, sulfur, Ni(NO3)2, wood and other combustibles. At elevated temperature undergoes violent reaction with powdered aluminum or magnesium. When heated to decomposition Nickel sulfate hexahydrate emits very toxic fumes of oxides of sulfur [Lewis, 3rd ed., 1993, p. 918].
Brandgefahr
Flash point data for Nickel sulfate hexahydrate are not available. Nickel sulfate hexahydrate is probably combustible.
Sicherheitsprofil
Confirmed human carcinogen. Poison by ingestion, intravenous, and subcutaneous routes. Experimental reproductive effects. Human mutation data reported. When heated to decomposition it emits toxic fumes of SOx. See also NICKEL SULFATE.

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