4-o-Tolylazo-o-toluidin Produkt Beschreibung

O-AMINOAZOTOLUENE Struktur
97-56-3
  • CAS-Nr.97-56-3
  • Bezeichnung:4-o-Tolylazo-o-toluidin
  • Englisch Name:O-AMINOAZOTOLUENE
  • Synonyma:4-o-Tolylazo-o-toluidin
    OAAT;o-AT;aat[qr];oaat[qr];o-at[qr];CI 11160;oilyellowc;oilyellowi;oilyellowt;c.i.11160b
  • CBNumber:CB5710733
  • Summenformel:C14H15N3
  • Molgewicht:225.29
  • MOL-Datei:97-56-3.mol
4-o-Tolylazo-o-toluidin physikalisch-chemischer Eigenschaften
Sicherheit

O-AMINOAZOTOLUENE Chemische Eigenschaften,Einsatz,Produktion Methoden

  • R-Sätze Betriebsanweisung: R45:Kann Krebs erzeugen.
    R22:Gesundheitsschädlich beim Verschlucken.
    R43:Sensibilisierung durch Hautkontakt möglich.
  • S-Sätze Betriebsanweisung: S53:Exposition vermeiden - vor Gebrauch besondere Anweisungen einholen.
    S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
  • Aussehen Eigenschaften C14H15N3.
    Rot-oranges Pulver.
  • Gefahren für Mensch und Umwelt Gefährliche Reaktionen mit starken Oxidationsmitteln.
    Giftig beim Verschlucken, Einatmen und bei Berührung mit der Haut. Verursacht Irritationen am Auge, auf der Haut und den oberen Atemwegen. Chronische Wirkungen. Krebserregend. Kann genetisches Material verändern.
  • Schutzmaßnahmen und Verhaltensregeln Im Abzug arbeiten.
    Schutzhandschuhe (nur als kurzzeitiger Spritzschutz).
  • Verhalten im Gefahrfall Verschüttetes Pulver vorsichtig aufnehmen und als Sondermüll entsorgen. Staubbildung vermeiden. Ggf. Staubmaske tragen.
    Wasser, CO2, Pulver.
  • Erste Hilfe Nach Hautkontakt: Mit viel Wasser abwaschen.
    Nach Augenkontakt: Mit viel Wasser bei geöffnetem Lidspalt mindestens 15 Minuten ausspülen.
    Nach Einatmen: Frischluft. Arzt!
    Nach Verschlucken: Viel Wasser trinken lassen. Arzt!
    Nach Kleidungskontakt: Kontaminierte Kleidung sofort ausziehen.
    Ersthelfer: siehe gesonderten Anschlag

  • Sachgerechte Entsorgung Als Sondermüll entsorgen.
  • Chemische Eigenschaften red-brown crystalline powder
  • Chemische Eigenschaften Aminoazotoluene forms golden yellow or reddish-brown crystalline solid.
  • Verwenden Coloring oils, fats and waxes; manufacture of pigments. Chemical intermediate for the production of dyes.
  • Verwenden C.I. 11160
  • synthetische (a) will Sodium nitrite (1 Moore) to join O-Methylaniline (8.5 Moore) and hydrochloric acid (1 Moore), the temperature is maintained at 28 ℃ below, until diazotization finish. Add a small amount of hydrochloric acid (about 0.2 Moore), and heating (40 ℃, 3 hours), in order to separate, with Sodium hydroxide for mercerization, and distillation reservoir. In order to get the refined products, usable alcohol recrystallization; (b) O-Methylaniline?diazotization, and O-Methylaniline?base Methanesulfonic acid coupling, and then with Sodium hydroxide solution common boiling, hydrolysis off Methanesulfonic acid base.
  • Allgemeine Beschreibung Reddish-brown to golden crystals; orangish red powder. Odorless.
  • Air & Water Reaktionen Dust may form an explosive mixture in air. Insoluble in water.
  • Reaktivität anzeigen O-AMINOAZOTOLUENE is an azo compound. Azo, diazo, azido compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases are formed by mixing materials of this class with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides. O-AMINOAZOTOLUENE is sensitive to prolonged exposure to heat. O-AMINOAZOTOLUENE is incompatible with strong oxidizing agents.
  • Hazard Possible carcinogen.
  • Brandgefahr Flash point data for O-AMINOAZOTOLUENE are not available. O-AMINOAZOTOLUENE is probably combustible.
  • Sicherheitsprofil Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by ingestion. Moderately toxic by subcutaneous route. An experimental teratogen. Human mutation data reported. When heated to decomposition it emits toxic fumes of NO,. See also AROMATIC AMINES.
  • mögliche Exposition An azo compound used in dyes, medicines; as a colorant in shoe polishes and other wax-based polishes.
  • Carcinogenicity o-Aminoazotoluene is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.
  • Versand/Shipping UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
  • läuterung methode Recrystallise the dye twice from EtOH, once from *benzene, then dry it in an Abderhalden drying apparatus. [Cilento J Am Chem Soc 74 968 1952, Sawicki J Org Chem 21 605 1956, Beilstein 16 H 334, 16 I 322, 16 II 178, 16 III 386, 16 IV 525.] CARCINOGENIC.
  • Properties and Applications yellow. In the ethanol for yellow sheet crystallization, melting point 100 ℃. Soluble in Acetone, ethanol, Cellosolve and Toluene, insoluble in water. In concentrated sulfuric acid for brown, dilution after red orange solution, and precipitation; In concentrated nitric acid for red brown solution; In concentrated hydrochloric acid partly dissolved for brown; In 10% of the sulfuric acid insoluble; In 10% Sodium hydroxide solution slightly soluble, pale yellow. Dye alcohol solution to join hydrochloric acid red hydrochloride crystal, heating the solution. Used for paraffin color.
    Standard Light Fastness Heat-resistant(℃) Water Sodium Carbonate(5%) Hydrochloric acid(5%)
    Melting point Stable
    ISO General 100 150Sublimation Indissolvable Indissolvable Poor
  • Inkompatibilitäten Dust may form explosive mixture in air. Azo compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases are formed by mixing materials of this class with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides. This chemical is sensitive to prolonged exposure to heat. This chemical is incompatible with strong oxidizing agents.
O-AMINOAZOTOLUENE Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
4-o-Tolylazo-o-toluidin Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
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97-56-3, O-AMINOAZOTOLUENE Verwandte Suche:
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  • oilyellowc
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  • oilyellowi
  • oilyellowi[qr]
  • oilyellowt
  • Organol Yellow 2T
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  • orthoaminoasotoluol
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  • o-Toluol-azo-o-toluidin
  • Somalia Yellow R
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  • sudanyellowrra[qr]
  • Toluazotoluidine
  • toluazotoluidine[qr]
  • Tulabase Fast Garnet GB
  • Tulabase Fast Garnet GBC
  • tulabasefastgarnetgb
  • tulabasefastgarnetgb[qr]
  • tulabasefastgarnetgbc
  • tulabasefastgarnetgbc[qr]
  • Waxakol Yellow NL
  • O-TOLUENE-AZO-O-TOLUIDINE
  • O-AMINOAZOTOLUENE
  • Benzenamine, 2-methyl-4-(2-methylphenyl)azo-
  • P-Aminoazotoluene
  • 2-methyl-4-(o-tolyldiazenyl)benzenamine
  • O-AMINOAZOTOLUENE OEKANAL, 250 MG
  • FAST GARNET GBC BASE 97%
  • ORTHO-AZOAMINOTOLUENE
  • 4-(ORTHO-TOLYLAZO)-ORTHO-TOLUIDINE
  • 2-METHYL-4-((2-METHYLPHENYL)AZO)-BENZENAMIDE
  • ORTHOAMINOAZOTOLUOL
  • 4-o-tolylazo-o-toluidine 4-amino-2',3-dimethylazobenzene fast garnet GBC base AAT o-aminoazotoluene
  • TOLUENEAZOAMINOTOLUENE
  • 4μ-Amino-2,3μ-dimethylazobenzene, o-Aminoazotoluene, Solvent Yellow 3
  • 4μ-Amino-2,3μ-dimethylazobenzene, Solvent Yellow 3
  • 2',3-Dimethyl-4-aminoazobenzene
  • 2’,3-dimethyl-4-aminoazobenzene
  • 2’,3-dimethyl-4-aminoazobenzene[qr]
  • 2-methyl-4-((2-methylphenyl)azo)-benzenamin
  • 2-methyl-4-((2-methylphenyl)azo)benzenamine
  • 2-Methyl-4((2-methylphenyl)azo)benzenamine
  • 2-methyl-4-((o-tolyl)azo)aniline[qr]
  • 2-methyl-4-[(2-methylphenyl)azo]-benzenamin
  • 2-methyl-4-[(2-methylphenyl)azo]-Benzenamine
  • 2-Methyl-4-[(E)-(2-methylphenyl)diazenyl]aniline
  • 2-Methyl-4-[(o-tolyl)azo]aniline