1-CHLORO-1-NITROPROPANE Struktur

1-Chlor-1-nitropropan

Bezeichnung:1-Chlor-1-nitropropan

CAS-Nr600-25-9

Englisch Name:1-CHLORO-1-NITROPROPANE

CBNumberCB5319114

SummenformelC3H6ClNO2

Molgewicht123.54

MOL-Datei600-25-9.mol

Synonyma

1-Chlor-1-nitropropan

1-Chlor-1-nitropropan physikalisch-chemischer Eigenschaften

Siedepunkt	142°C (estimate)
Dichte	1.2070
Dampfdruck	6 at 25 °C (NIOSH, 1997)
Brechungsindex	1.4251 (estimate)
Löslichkeit	Soluble in alcohol, ether (Weast, 1986), and many low molecular weight hydrocarbons (pentane, hexane, heptane), and halogenated hydrocarbons such as chloroform, methylene chloride, trichloroethylene.
pka	3.93±0.36(Predicted)
Aggregatzustand	Colorless liquid
Farbe	Clear, colorless liquid with an unpleasant odor
Wasserlöslichkeit	6 mg/L at 20 °C (quoted, Verschueren, 1983)
Henry's Law Constant	0.157 atm?m³/mol at 20 °C (approximate - calculated from water solubility and vapor pressure)
Expositionsgrenzwerte	NIOSH REL: TWA 2 ppm (10 mg/m³), IDLH 100 ppm; OSHA PEL: TWA 20 ppm (100 mg/m³); ACGIH TLV: TWA 2 ppm (adopted).
EPA chemische Informationen	1-Chloro-1-nitropropane (600-25-9)

Sicherheit

Kennzeichnung gefährlicher	Xn
R-Sätze:	20/22
RIDADR	2810
OEB	B
OEL	TWA: 2 ppm (10 mg/m3)
HazardClass	6.1(b)
PackingGroup	III
Giftige Stoffe Daten	600-25-9(Hazardous Substances Data)
Toxizität	Acute oral LD₅₀ for mice 510 mg/kg (quoted, RTECS, 1985).
IDLA	100 ppm

Gefahreninformationscode (GHS)

1-CHLORO-1-NITROPROPANE Chemische Eigenschaften,Einsatz,Produktion Methoden

ERSCHEINUNGSBILD
FARBLOSE FLüSSIGKEIT MIT CHARAKTERISTISCHEM GERUCH.
CHEMISCHE GEFAHREN
Beim Verbrennen Bildung giftiger und ätzender Rauche mit Chlordämpfen, Chlorwasserstoff, Stickstoffoxidenund Phosgen. Reagiert mit Oxidationsmitteln und Säuren. Greift Kunststoff, Gummi und Isolatoren an.
ARBEITSPLATZGRENZWERTE
TLV: 2 ppm (als TWA); (ACGIH 2005).
MAK: IIb (nicht festgelegt, aber Informationen vorhanden) (DFG 2005).
AUFNAHMEWEGE
Aufnahme in den Körper durch Inhalation und durch Verschlucken.
INHALATIONSGEFAHREN
Beim Verdampfen bei 20°C kann schnell eine gesundheitsschädliche Kontamination der Luft eintreten.
WIRKUNGEN BEI KURZZEITEXPOSITION
WIRKUNGEN BEI KURZZEITEXPOSITION:
Die Substanz reizt stark die Augen und die Atemwege. Inhalation hoher Dampfkonzentrationen kann zu Lungenödem führen (s.Anm.).
LECKAGE
Ausgelaufene Flüssigkeit möglichst in abdichtbaren Behältern sammeln. Reste mit Sand oder inertem Absorptionsmittel aufnehmen und an einen sicheren Ort bringen. Chemikalienschutzanzug mit umgebungsluftunabhängigem Atemschutzgerät.
R-Sätze Betriebsanweisung:
R20/22:Gesundheitsschädlich beim Einatmen und Verschlucken.
Beschreibung
Chloronitropropane is a flammable, colorlessliquid with an unpleasant odor that causes tears (lachrimator). Molecular weight =123.5; Specific gravity (H2O:1) =1.2; Boiling point =142.7℃; Vapor pressure =6 mmHg at25℃; Flash point =62℃ (oc). Hazard Identification (basedon NFPA 704 M Rating System): Health (unknown),Flammability 3, Reactivity 2. Slightly soluble in water;solubility =0.6% at 20℃
Chemische Eigenschaften
Chloronitroproane is a flammable, colorless liquid with an unpleasant odor that causes tears (lachrymator).
Verwenden
Fungicide.
Synthesis Reference(s)
The Journal of Organic Chemistry, 42, p. 3764, 1977 DOI: 10.1021/jo00443a034
Allgemeine Beschreibung
Colorless liquid. Unpleasant odor.
Air & Water Reaktionen
Slightly soluble in water [Lawry's].
Reaktivität anzeigen
1-CHLORO-1-NITROPROPANE is sensitive to heat (may be explosive). 1-CHLORO-1-NITROPROPANE is incompatible with oxidizers. 1-CHLORO-1-NITROPROPANE will attack some forms of plastics, rubber and coatings . Combustible: May produce toxic gases, including nitrogen oxides, hydrogen chloride, and carbon monoxide. Will attack some plastics, rubber, and coatings [USCG, 1999].
Health Hazard
LIQUID: Irritating to skin and eyes. Harmful if swallowed.
Brandgefahr
Combustible: May produce toxic gases, including nitrogen oxides, hydrogen chloride, and carbon monoxide. Will attack some plastics, rubber, and coatings.
Sicherheitsprofil
Poison by ingestion, subcutaneous, and possibly other routes. Moderately toxic by inhalation. Causes injury to kidneys, liver, and cardiovascular system. Mutation data reported. Flammable liquid when exposed to heat, flame (sparks), and oxidizers. Moderately explosive when exposed to heat. To fight fire, use alcohol foam, water, CO2, or dry chemical. When heated to decomposition it emits toxic fumes of Cland NOx. See also other chloropropane entries and CHLORIDES.
mögliche Exposition
This compound is used in the synthetic rubber industry; as a component in rubber cements; and as a fungicide.
Erste Hilfe
If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.Medical observation is recommended for 2448 h afterbreathing overexposure, as pulmonary edema may bedelayed. As first aid for pulmonary edema, a doctor orauthorized paramedic may consider administering a corticosteroid spray.
Lager
Color Code—Blue: Health Hazard/Poison: Store ina secure poison location. Prior to working with 1-chloro-1-nitropropane you should be trained on its proper handling andstorage. Before entering confined space where 1-chloro-1-nitropropane may be present, check to make sure that anexplosive concentration does not exist. Store to avoid contactwith strong oxidizers (such as chlorine, bromine, and fluorine), since violent reactions occur. Store in tightly closedcontainers in a cool, well-ventilated area away from heat.Metal containers involving the transfer of this chemicalshould be grounded and bonded. Where possible, automatically pump liquid from drums or other storage containers toprocess containers. Drums must be equipped with self-closingvalves, pressure vacuum bungs, and flame arresters. Use onlynonsparking tools and equipment, especially when openingand closing containers of this chemical. Sources of ignition,such as smoking and open flames, are prohibited where thischemical is used, handled, or stored in a manner that couldcreate a potential fire or explosion hazard.
Versand/Shipping
UN2810 Toxic liquids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
Inkompatibilitäten
May form explosive mixture with air. Strong oxidizers may cause a fire and explosion hazard. May explode when exposed to heat.
Waste disposal
Incineration (816C, 0.5-second minimum for primary combustion; 1204C, 1.0 second for secondary combustion) after mixing with other fuel. The formation of elemental chlorine may be prevented by injection of steam or using methane as a fuel in the process. Alternatively it may be poured over soda ash, neutralized and flushed into the sewer with large volumes of water.

1-Chlor-1-nitropropan Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

600-25-9, 1-CHLORO-1-NITROPROPANE Verwandte Suche:

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