Nitrocyclohexan

Bezeichnung:Nitrocyclohexan

CAS-Nr1122-60-7

Englisch Name:NITROCYCLOHEXANE

CBNumberCB5116443

SummenformelC6H11NO2

Molgewicht129.16

MOL-Datei1122-60-7.mol

Synonyma

Nitrocyclohexan

Nitrocyclohexan physikalisch-chemischer Eigenschaften

Schmelzpunkt	−34 °C(lit.)
Siedepunkt	205.5-206 °C768 mm Hg(lit.)
Dichte	1.061 g/mL at 25 °C(lit.)
Dampfdichte	4.46 (vs air)
Dampfdruck	768 mm Hg ( 205 °C)
Brechungsindex	n20/D 1.462(lit.)
Flammpunkt	166 °F
Löslichkeit	soluble in Alcohol
Aggregatzustand	clear liquid
pka	8.44±0.20(Predicted)
Farbe	Light orange to Yellow to Green
EPA chemische Informationen	Nitrocyclohexane (1122-60-7)

Sicherheit

Kennzeichnung gefährlicher	T
R-Sätze:	23/24/25-36/37/38
S-Sätze:	26-36/37/39-45
RIDADR	UN 3382 6.1/PG 1
WGK Germany	3
RTECS-Nr.	GV6600000
HazardClass	6.1(b)
PackingGroup	III
HS Code	29049090
Giftige Stoffe Daten	1122-60-7(Hazardous Substances Data)

Gefahreninformationscode (GHS)

NITROCYCLOHEXANE Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R23/24/25:Giftig beim Einatmen, Verschlucken und Berührung mit der Haut.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
Chemische Eigenschaften
Colorless to dark yellow liquid
Chemische Eigenschaften
Nitrocyclohexane is a highly flammable, colorless liquid.
Definition
ChEBI: A C-nitro compound that is cyclohexane in which a single hydrogen is replaced by a nitro group.
Synthesis Reference(s)
Journal of the American Chemical Society, 75, p. 4047, 1953 DOI: 10.1021/ja01112a049
Tetrahedron, 46, p. 7443, 1990 DOI: 10.1016/S0040-4020(01)89059-1
Tetrahedron Letters, 21, p. 1117, 1980 DOI: 10.1016/S0040-4039(01)83928-9
Allgemeine Beschreibung
Colorless liquid.
Air & Water Reaktionen
Highly Flammable
Reaktivität anzeigen
Nitroalkanes, such as NITROCYCLOHEXANE, range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. Nitroalkanes are milder oxidizing agents, but still react violently with reducing agents at higher temperature and pressures. Nitroalkanes react with inorganic bases to form explosive salts. The presence of metal oxides increases the thermal sensitivity of nitroalkanes. Nitroalkanes with more than one nitro group are generally explosive. Nitroalkanes are insoluble in water. Flammable/combustible material. May be ignited by heat, sparks or flames.
mögliche Exposition
Used in organic synthesis.
Versand/Shipping
UN3382 Toxic by inhalation liquid, n.o.s. with an LC50 lower than or equal to 1000 ml/m3 and saturated vapor concentration ≥10 LC50, Hazard Class: 6.1; Labels: 6.1 Technical Name Required, Inhalation Hazard Zone B.
Inkompatibilitäten
A nitro compound; a fire and explosive hazard. May form explosive mixture with air. Nitrocyclohexane, a nitroalkane, is a strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. Nitroalkanes are milder oxidizing agents, but still react violently with reducing agents at higher temperature and pressures. Nitroalkanes react with inorganic bases to form explosive salts. The presence of metal oxides increases the thermal sensitivity of nitroalkanes. Nitroalkanes with more than one nitro group are generally explosive. Incompatible with alkalis, and metal oxides. This chemical is highly reactive and may be heat-and shock-sensitive.
Waste disposal
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

NITROCYCLOHEXANE Upstream-Materialien And Downstream Produkte

Nitrocyclohexan Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

1122-60-7, NITROCYCLOHEXANE Verwandte Suche:

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