URANYL NITRATE HEXAHYDRATE Struktur

URANYL NITRATE HEXAHYDRATE

Bezeichnung:URANYL NITRATE HEXAHYDRATE

CAS-Nr13520-83-7

Englisch Name:URANYL NITRATE HEXAHYDRATE

CBNumberCB4392622

SummenformelH12N2O14U

Molgewicht502.13

MOL-Datei13520-83-7.mol

URANYL NITRATE HEXAHYDRATE physikalisch-chemischer Eigenschaften

Schmelzpunkt	60,2°C
Siedepunkt	118℃ [HAW93]
Dichte	2,807 g/cm³
Löslichkeit	soluble in ethanol, ethyl ether
Aggregatzustand	yellow orthorhombic crystals
Farbe	yellow orthorhombic crystals, crystalline; hygroscopic
Wasserlöslichkeit	g/100g H2O: 98 (0°C), 122 (20°C), 474 (100°C) [LAN05]; very soluble alcohol, ether [MER06], data are in [SIE94]
Stabilität	Radioactive, but chemically stable. Strong oxidant. Hygroscopic. Incompatible with combustible materials, reducing agents. May react explosively with cellulose and certain organic solvents.
CAS Datenbank	13520-83-7(CAS DataBase Reference)
EPA chemische Informationen	Uranium, bis(nitrato-.kappa.O)dioxo-, hexahydrate, (T-4)- (13520-83-7)

Sicherheit

Kennzeichnung gefährlicher	T+,R,N
R-Sätze:	26/28-33-51/53
S-Sätze:	20/21-45-61
RIDADR	2912
RTECS-Nr.	YR3850000
HazardClass	7
PackingGroup	II
HS Code	28441000
Toxizität	cat,LDLo,oral,238mg/kg (238mg/kg),"Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co., 1956-59Vol. 1, Pg. 310, 1955.

Gefahreninformationscode (GHS)

Bildanzeige (GHS)
Alarmwort

Achtung
Gefahrenhinweise

H272：Kann Brand verstärken; Oxidationsmittel.

H300：Lebensgefahr bei Verschlucken.

H330：Lebensgefahr bei Einatmen.

H373：Kann die Organe schädigen bei längerer oder wiederholter Exposition.

H411：Giftig für Wasserorganismen, mit langfristiger Wirkung.
Sicherheit

P210：Von Hitze, heißen Oberflächen, Funken, offenen Flammen und anderen Zündquellenarten fernhalten. Nicht rauchen.

P220：Von Kleidung und anderen brennbaren Materialien fernhalten.

P260：Dampf/Aerosol/Nebel nicht einatmen.

P264：Nach Gebrauch gründlich waschen.

P264：Nach Gebrauch gründlich waschen.

P270：Bei Gebrauch nicht essen, trinken oder rauchen.

P271：Nur im Freien oder in gut belüfteten Räumen verwenden.

P284：Atemschutz tragen.

P301+P310：BEI VERSCHLUCKEN: Sofort GIFTINFORMATIONSZENTRUM/Arzt/... (geeignete Stelle für medizinische Notfallversorgung vom Hersteller/Lieferanten anzugeben) anrufen.

P304+P340：BEI EINATMEN: Die Person an die frische Luft bringen und für ungehinderte Atmung sorgen.

P310：Sofort GIFTINFORMATIONSZENTRUM/Arzt/ anrufen.

P314：Bei Unwohlsein ärztlichen Rat einholen / ärztliche Hilfe hinzuziehen.

P320：Besondere Behandlung dringend erforderlich

P321：Besondere Behandlung

P330：Mund ausspülen.

P370+P378：Bei Brand: zum Löschen verwenden.

P403+P233：An einem gut belüfteten Ort aufbewahren. Behälter dicht verschlossen halten.

P405：Unter Verschluss aufbewahren.

P501：Inhalt/Behälter ... (Entsorgungsvorschriften vom Hersteller anzugeben) zuführen.

URANYL NITRATE HEXAHYDRATE Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R26/28:Sehr giftig beim Einatmen und Verschlucken.
R33:Gefahr kumulativer Wirkungen.
R51/53:Giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
S-Sätze Betriebsanweisung:
S20/21:Bei der Arbeit nicht essen, trinken,rauchen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
Chemische Eigenschaften
yellow crystals
Verwenden
Uranyl nitrate can be used as an analytical reagent, as a lighting device in the photographic industry, and in the production of fine porcelain.
Allgemeine Beschreibung
Acidic solution in water of uranyl nitrate, a radioactive yellow crystalline solid. Mildly chemically toxic. Contains nitric acid. Noncombustible, but will accelerate the burning of other combustible materials if concentrated or if the water evaporates. Large quantities may explode if exposed to fire. Produces toxic oxides of nitrogen if involved in fire. Radioactive materials emit certain rays which can be detected only by instruments. Unirradiated uranium is only mildly radioactive. Minimal radiation hazard during transportation. No protective shielding is required. Non-fissile (natural or depleted) uranium, containing not more than 1.0% u-235, cannot sustain a nuclear chain reaction.
Air & Water Reaktionen
Dissolves in water forming a weak solution of nitric acid, the reaction is not hazardous.
Reaktivität anzeigen
Mixtures of metal/nonmetal nitrates with alkyl esters may explode, owing to the formation of alkyl nitrates; mixtures a nitrate with phosphorus, tin (II) chloride, or other reducing agents may react explosively [Bretherick 1979. p. 108-109]. Dissolves in water forming a weak solution of nitric acid, the reaction is not hazardous.
Health Hazard
Radiation presents minimal risk to transport workers, emergency response personnel and the public during transportation accidents. Packaging durability increases as potential hazard of radioactive content increases. Undamaged packages are safe. Contents of damaged packages may cause higher external radiation exposure, or both external and internal radiation exposure if contents are released. Low radiation hazard when material is inside container. If material is released from package or bulk container, hazard will vary from low to moderate. Level of hazard will depend on the type and amount of radioactivity, the kind of material it is in, and/or the surfaces it is on. Some material may be released from packages during accidents of moderate severity but risks to people are not great. Released radioactive materials or contaminated objects usually will be visible if packaging fails. Some exclusive use shipments of bulk and packaged materials will not have "RADIOACTIVE" labels. Placards, markings and shipping papers provide identification. Some packages may have a "RADIOACTIVE" label and a second hazard label. The second hazard is usually greater than the radiation hazard; so follow this GUIDE as well as the response GUIDE for the second hazard class label. Some radioactive materials cannot be detected by commonly available instruments. Runoff from control of cargo fire may cause low-level pollution.
Sicherheitsprofil
Poison by ingestion, subcutaneous, intravenous, and intraperitoneal routes. Mutation data reported. A corrosive irritant to skin, eyes, and mucous membranes. A raboactive material. When heated to decomposition it emits toxic fumes of NOx. See also URANIUM.
Synthese
Take uranyl nitrate hexahydrate and prepare a saturated solution with water or 0.1-1mol/L nitric acid solution at room temperature. Put it in a pressure-resistant desiccator and gradually evacuate it. After the crystals are precipitated, a part of the crystals initially precipitated is removed by filtration, and then vacuum is continued to separate out the crystals. This part of the crystals is filtered out and placed in a desiccator filled with 35% to 40% sulfuric acid, dried and stored.
läuterung methode
Crystallise the nitrate from water by cooling to -5o, taking only the middle fraction of the solid which separates. Dry the deliquescent rhombic yellow crystals of the hexahydrate over 35-40% H2SO4 in a vacuum desiccator. The crystals reflect a greenish lustre. They are remarkable because on crushing, rubbing or shaking they show triboluminescence with occasional detonation. They are very soluble in EtOH, and solutions of the nitrate in Et2O can explode in the presence of sunlight.

URANYL NITRATE HEXAHYDRATE Upstream-Materialien And Downstream Produkte

URANYL NITRATE HEXAHYDRATE Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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