Binapacryl (ISO)

Gefahreninformationscode (GHS)

• Bildanzeige (GHS)

  

• Alarmwort

  Achtung

• Gefahrenhinweise

  H410：Sehr giftig für Wasserorganismen mit langfristiger Wirkung.

• Sicherheit

  P202：Vor Gebrauch alle Sicherheitshinweise lesen und verstehen.

  P264：Nach Gebrauch gründlich waschen.

  P264：Nach Gebrauch gründlich waschen.

  P273：Freisetzung in die Umwelt vermeiden.

  P280：Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.

  P301+P310：BEI VERSCHLUCKEN: Sofort GIFTINFORMATIONSZENTRUM/Arzt/... (geeignete Stelle für medizinische Notfallversorgung vom Hersteller/Lieferanten anzugeben) anrufen.

BINAPACRYL Chemische Eigenschaften,Einsatz,Produktion Methoden

• ERSCHEINUNGSBILD

  FARBLOSES KRISTALLINES PULVER.

• CHEMISCHE GEFAHREN

  Zersetzung beim Erhitzen oder Verbrennen unter Bildung giftiger Rauche mit Stickstoffoxiden. Reagiert langsam mit Wasser unter Bildung von schädlichem Dinoseb.

• ARBEITSPLATZGRENZWERTE

  TLV nicht festgelegt (ACGIH 2005).
  MAK nicht festgelegt (DFG 2005).
  

• AUFNAHMEWEGE

  Aufnahme in den Körper durch Inhalation des Aerosols, über die Haut und durch Verschlucken.

• INHALATIONSGEFAHREN

  Nur ungenügende Angaben vorhanden über die Geschwindigkeit, mit der eine gesundheitsschädliche Konzentration in der Luft beim Verdampfen bei 20°C erreicht wird.

• WIRKUNGEN BEI KURZZEITEXPOSITION

  WIRKUNGEN BEI KURZZEITEXPOSITION:
  Möglich sind Auswirkungen auf den Stoffwechsel mit nachfolgender erhöhter Körpertemperatur und Schwitzen. Die Auswirkungen treten u.U. verzögert ein. ärztliche Beobachtung notwendig.

• LECKAGE

  Verschüttetes Material in abdichtbaren Behältern sammeln. Reste sorgfältig sammeln. An sicheren Ort bringen. NICHT in die Umwelt gelangen lassen. Persönliche Schutzausrüstung: Atemschutzgerät, P3-Filter für giftige Partikel.

• R-Sätze Betriebsanweisung:

  R61:Kann das Kind im Mutterleib schädigen.
  R21/22:Gesundheitsschädlich bei Berührung mit der Haut und beim Verschlucken.
  R50/53:Sehr giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.

• S-Sätze Betriebsanweisung:

  S53:Exposition vermeiden - vor Gebrauch besondere Anweisungen einholen.
  S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
  S60:Dieses Produkt und sein Behälter sind als gefährlicher Abfall zu entsorgen.
  S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.

• Beschreibung

  Binapacryl is a nitrophenol pesticide and thedimethyl acrylic ester of dinoseb. Binapacryl is a colorless,crystalline solid or powder. Crystals may turn pale-yellowto brownish on contact with air. The solid may be dissolved in a flammable liquid carrier. Mild, ammonia odor.Molecular weight=322.31; Density=1.238 g/cm3 at20℃. Melting/Freezing=66℃; Boiling Point=437℃ at760 mmHg; Vapor pressure=4.2 3 10 2 7 mmHg at 20℃;Flash point=172℃; but may be dissolved in a flammableliquid carrier. Practically insoluble in water.

• Verwenden

  Fungicide, miticide.

• Verwenden

  Binapacryl is a miticide and a fungicide used in pesticides. It is readily metabolized to Dinoseb (D480490) an herbicide in the dinitrophenol family.

• Definition

  Generic name for 2-sec-butyl-4,6- dinitrophenyl-3-methyl-2-butenoate. C1 5 H8O 6 N2.

• Hazard

  Toxic by ingestion and inhalation.

• Sicherheitsprofil

  Poison by ingestion. Moderatelytoxic by skin contact. Mutation data reported. Acholinesterase inhibitor. When heated to decomposition itemits fumes of NOx.

• mögliche Exposition

  Mutagen; cholinesterase inhibitor.Used as an acaricide, fungicide, and miticide. Not registeredin the United States.

• Erste Hilfe

  If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions) ifbreathing has stopped, and CPR if heart action has stopped.Transfer promptly to a medical facility. When this chemicalhas been swallowed, get medical attention. Do not inducevomiting when formulations containing petroleum solventsare ingested. Otherwise, give large quantities of waterand induce vomiting. Do not make an unconscious personvomit.
  Note to physician: Treat for methemoglobinemia.Spectrophotometry may be required for precise determination of levels of methemoglobinemia in urine.

• Lager

  Color Code—Red (dissolved material in a flammable liquid carrier): Flammability Hazard: Store in aflammable liquid storage area or approved cabinet awayfrom ignition sources and corrosive and reactive materials.Color Code (dry, solid material)—Blue: Health Hazard/Poison: Store in a secure poison location. Prior to workingwith dinoseb you should be trained on its proper handlingand storage. Store in tightly closed containers in a cool,well-ventilated area. Store at temperatures from 0 to 6℃.

• Versand/Shipping

  Binapacryl, solid: label “SUBSTITUTEDNITROPHENOL PESTICIDES, SOLID, TOXIC.” It fallsinto DOT/UN Hazard Class 6.1(b) and Packing Group III.The DOT-required shipping label of “FLAMMABLELIQUID, POISONOUS/TOXIC MATERIALS.” TheHazard Class is 3 and the Packing Group is I.[19, 20]

• Inkompatibilitäten

  Slight hydrolysis on long contact withwater. Keep away from caustics and concentrated acids thatcan cause decomposition. Slowly decomposed by ultravioletlight. When heated to decomposition it emits fumes ofnitrogen oxides. Contact with metals may evolve flammablehydrogen gas. A nitrophenol may be an oxidizer (ofunknown strength); incompatible with reducing agentsincluding alkali metals, hydrides, nitrides, and sulfides,which might cause a violent reaction or detonation.Nitrophenols may explode when heated. Nitrophenols mayreact as a weak organic acid. Do not mix with Nitric orSulfuric acid as explosive shock- and impact-sensitive saltsmay be formed.

• Short Term Exposure

  Severely irritates eyes, skin, andrespiratory tract, with burning sensation, pain, redness, andswelling. Metabolic stimulant. If inhaled, causes coughing,dilated pupils, headache, profuse perspiration, intensethirst, extreme fatigue, rapid pulse, high fever, clammy,flushed skin, rapid breathing, nausea, vomiting, yellowish tint to skin and lips, anxiety and confusion, convulsions,risk of lung edema. The effects may be delayed. Medicalobservation is recommended. If swallowed, face and lipsturn bluish. Liver injury with associated jaundice, kidneyfailure, and cardiac arrhythmias are commonly noted.Severe exposure can cause death from heart failure.

• Long Term Exposure

  May damage the liver, kidneys, andblood cells. May stain yellow the skin, eyes, and fingernails.Repeated exposure can cause anxiety, fatigue, insomnia, excessive perspiration, unusual thirst, weight loss, andcataracts in the eyes.

• Personal Protective Methods

  Wear protective gloves andclothing to prevent any reasonable probability of skin contact. Safety equipment suppliers/manufacturers can providerecommendations on the most protective glove/clothingmaterial for your operation. All protective clothing (suits,gloves, footwear, headgear) should be clean, available eachday, and put on before work. Contact lenses should not beworn when working with this chemical. If working with liquid wear splash-proof chemical goggles, if working drymaterial wear dust-proof chemical goggles and face shieldunless full face-piece respiratory protection is worn.Employees should wash immediately with soap when skinis wet or contaminated. Provide emergency showers andeyewash.

• Fire Extinguishing

  Binapacryl is a combustible material;it may burn but does not ignite readily. In heat of fire itemits fumes of nitrogen oxides. When heated, vapors mayform explosive mixtures with air. Extinguish fire usingagent suitable for type of surrounding fire. Use water inflooding quantities as fog. Use “alcohol” foam, dry chemical,or carbon dioxide. Cool all affected containers withflooding quantities of water. If fire becomes uncontrollable,evacuate for a radius of 1 mile. Nitrophenol pesticides maybe dangerously explosive. Containers may explode whenheated. From a secure, explosion-proof location, use waterspray to cool exposed containers. If cooling streams areineffective (venting sound increases in volume and pitch,tank discolors, or shows any signs of deforming), withdrawimmediately to a secure position. Runoff will pollute waterways. If material or contaminated runoff enters waterways,notify downstream users of potentially contaminated waters.Notify local health and fire officials and pollution controlagencies. If employees are expected to fight fires, they mustbe trained and equipped in OSHA 1910.156. The onlyrespirators recommended for firefighting are self-containedbreathing apparatuses that have full face-pieces and areoperated in a pressure-demand or other positive-pressuremode.

• Disposal Method Suggested

  Avoid release to the environment. Dissolve or mix the material with a combustiblesolvent and burn in a chemical incinerator equipped with anafterburner and scrubber. All federal, state, and local environmental regulations must be observed. Conduct at1000℃ for 2.0 s minimum with scrubber for nitrogen oxides removal is recommended. In accordance with40CFR165, follow recommendations for the disposal ofpesticides and pesticide containers. Must be disposed properly by following package label directions or by contactingyour local or federal environmental control agency or bycontacting your regional EPA office. Consultwith environmental regulatory agencies for guidance onacceptable disposal practices.

BINAPACRYL Upstream-Materialien And Downstream Produkte

Binapacryl (ISO) Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global(47)Suppliers

485-31-4, BINAPACRYL Verwandte Suche: