ARAMITE

Bezeichnung:ARAMITE

CAS-Nr140-57-8

Englisch Name:ARAMITE

CBNumberCB3304743

SummenformelC15H23ClO4S

Molgewicht334.86

MOL-Datei140-57-8.mol

ARAMITE physikalisch-chemischer Eigenschaften

Schmelzpunkt	-31.7°
Siedepunkt	bp0.1 175°; bp7.0 200-210°
Dichte	1.195
Brechungsindex	nD20 1.5100 to 1.5118; nD27 1.5075
storage temp.	2-8°C
Löslichkeit	Chloroform (Slightly), Methanol (Slightly)
Aggregatzustand	Oil
Farbe	Colourless to Pale Brown
Stabilität	Hygroscopic
IARC	2B (Vol. 5, Sup 7) 1987
EPA chemische Informationen	Aramite (140-57-8)

Sicherheit

Kennzeichnung gefährlicher	F,Xn
R-Sätze:	11-36/37/38-48/20-62-40
S-Sätze:	53-16-36/37/39-45-36/37-24/25-23
RIDADR	UN 1208 3/PG 2
WGK Germany	2
HS Code	29252900
Giftige Stoffe Daten	140-57-8(Hazardous Substances Data)
Toxizität	LD50 orally in rats: 3.90±0.28 g/kg (Oser, Oser)

Gefahreninformationscode (GHS)

ARAMITE Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R11:Leichtentzündlich.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R48/20:Gesundheitsschädlich: Gefahr ernster Gesundheitsschäden bei längerer Exposition durch Einatmen.
R62:Kann möglicherweise die Fortpflanzungsfähigkeit beeinträchtigen.
R40:Verdacht auf krebserzeugende Wirkung.
S-Sätze Betriebsanweisung:
S53:Exposition vermeiden - vor Gebrauch besondere Anweisungen einholen.
S16:Von Zündquellen fernhalten - Nicht rauchen.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
S23:Gas/Rauch/Dampf/Aerosol nicht einatmen(geeignete Bezeichnung(en) vom Hersteller anzugeben).
Beschreibung
Aramite is a synthetic chlorinated hydrocarbon with molecular weight of 334.87 and density of 1.143 at 20°C. It is a clear, light-colored oil with melting point of 37.3 C and boiling point of 175 °C at 0.1 mm Hg. The technical grade aramite is a dark amber liquid. Aramite is soluble at 0.000 1% (practically insoluble) in water but is miscible in many organic solvents. It was sold as mixture in organic solvents at different strengths for further dilution and use. Aramite was used as a pesticide (acaricide) to control mites in plants and animals. Aramite was initially introduced to market around 1950. It was mostly used between 1950 and 1954 in greenhouses in the United States. Its manufacture and use were voluntarily discontinued due to its carcinogenic potential according to a US Environmental Protection Agency (EPA) notice dated 12 April 1977. However, there are reports of bans of aramite use in a few European countries, in 1987 (Lithuania), 1996 (Poland), and 1999 (Estonia). There is no information on the production, import, registration, marketing, stockpiling, and use of aramite in Russia. Occupational exposure through dermal contact and inhalation was possible during its use.
Chemische Eigenschaften
Aramite is a heavy, dark-amber liquid.
Verwenden
Miticide.
Verwenden
Aramite was formerly used in control of mites (miticide) in citrus fruits, vegetables, and animals. Active mite stage was most sensitive to aramite toxicity. The death in mites was due to paralysis and disorganized movements of appendages, leading to detachment from the plant. Insects and mites other than Tetracychidae are not as sensitive to aramite. Mites exposed in the field to up to 21 applications were not found to develop resistance in mites, unlike other organochlorines where insects develop resistance rapidly. Aramite is rendered inactive when mixed with lime and other alkaline materials. Aramite was used in combination of other pesticides to control a wide range of mite species.
Definition
ChEBI: Aramite is an alkylbenzene.
Allgemeine Beschreibung
Aramite is a carcinogenic acaricide, widely used against six spotted mite, European red mite and others affecting crops.
Sicherheitsprofil
Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Experimental poison by intraperitoneal route. Moderately toxic to humans by ingestion. Moderately toxic experimentally by ingestion. Experimental reproductive effects. A pesticide. When heated to decomposition it emits toxic fumes of Cland SOx. See also ESTERS and SULFUROUS ACID.
mögliche Exposition
Aramite is an organochlorine miticide and antimicrobial agent. Aramite is regulated by EPA under the Federal Insecticide, Fungicide, and Rodenticide Act and the Resource Conservation and Recovery Act. The significant regulatory action was a voluntary cancellation of the active ingredient registration by the sole producer in 1975.
Versand/Shipping
UN2902 Pesticides, liquid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
Toxicity evaluation
Aramite can be released directly into the environment through its use as an acaricide (miticide); however, this use has been discontinued. If released to soil, aramite is expected to have no mobility. Volatilization from moist soil surfaces is not expected to be an important fate process based on an estimated Henry’s Law constant of 1.9×10^-7 atm m3 mol^-1. Biodegradation data for aramite are not available, and if released into water, aramite is expected to adsorb to suspended solids and sediments based upon the estimated Koc of 2.0×10⁺⁴. Volatilization from water surfaces is not expected to be an important fate process based on this compound’s estimated Henry’s Law constant. Aramite’s potential for bioconcentration in aquatic organisms is very high. Functional groups of aramite are susceptible to hydrolysis; however, insufficient data are available to predict the relative importance or occurrence of chemical or biological degradation processes in water or soil. Aramite is hydrolyzed by alkalies and may contribute to degradation in soil or water. If released into air, aramite is expected to be physically removed by wet and dry deposition processes.
Inkompatibilitäten
Incompatible with alkaline material, such as lime or Bordeaux mixture (slaked lime and copper sulfate solution).
Waste disposal
Acid or alkaline hydrolysis followed by flushing to sewer.

ARAMITE Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

140-57-8, ARAMITE Verwandte Suche:

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