Molybdaendioxid

Bezeichnung:Molybdaendioxid

CAS-Nr18868-43-4

Englisch Name:Molybdenum(IV) oxide

CBNumberCB3140754

SummenformelMoO2

Molgewicht127.94

MOL-Datei18868-43-4.mol

Synonyma

Molybdaendioxid

Molybdaendioxid physikalisch-chemischer Eigenschaften

Schmelzpunkt

decomposes [JAN85]

Dichte

6.47 g/mL at 25 °C (lit.)

Löslichkeit

insoluble in H2O, acid solutions, alkaline solutions

Aggregatzustand

Powder

Wichte

6.47

Farbe

Red-brown

Wasserlöslichkeit

slightly soluble H2SO4; insoluble HCl, HF, and alkalies [HAW93]

Crystal Structure

MoO2 type

crystal system

Monoclinic

Space group

P21/c

Lattice constant

a/nm	b/nm	c/nm	α/o	β/o	γ/o	V/nm3
0.55388	0.48562	0.56285	90	119.683	90	0.1315

Expositionsgrenzwerte

ACGIH: TWA 10 mg/m3; TWA 3 mg/m3
NIOSH: IDLH 5000 mg/m3

InChIKey

QXYJCZRRLLQGCR-UHFFFAOYSA-N

CAS Datenbank

18868-43-4(CAS DataBase Reference)

EPA chemische Informationen

Molybdenum oxide (MoO2) (18868-43-4)

Sicherheit

Kennzeichnung gefährlicher	Xn
R-Sätze:	20/21/22-36/37/38
S-Sätze:	26-36
WGK Germany	1
RTECS-Nr.	QA4688000
TSCA	Yes
HS Code	28257000
Toxizität	mouse,LD50,subcutaneous,318mg/kg (318mg/kg),Zhurnal Vsesoyuznogo Khimicheskogo Obshchestva im. D.I. Mendeleeva. Journal of the D.I. Mendeleeva All-Union Chemical Society. Vol. 19, Pg. 186, 1974.

Gefahreninformationscode (GHS)

Molybdenum(IV) oxide Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R20/21/22:Gesundheitsschädlich beim Einatmen,Verschlucken und Berührung mit der Haut.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
Chemische Eigenschaften
Lead-gray, nonvolatile powder. Dapproximately 6.4. Insoluble in hydrochloric acidand hydrogen fluoride and alkalies, sparingly solu-ble in sulfuric acid.
Physikalische Eigenschaften
Molybdenum(IV) oxide can be prepared by several methods including controlled oxidation of Mo and controlled reduction of MoO3 with hydrogen. The pure oxide suitable for structure determination has been prepared by electrolysis of a polymolybdate (K2O5.MoO3) solution. Molybdenum(IV) oxide is insoluble in water: it is inert in solutions of nonoxidizing acids or bases, but is dissolved by oxidizing solutions. It dissociates to Mo and MoO3 at high temperatures (~ 1100°).
Crystalline MoO2 is violet or brown. Its deformed rutile structure consists of infinite chains of MoO6 octahedra sharing opposite edges along the chain direction with Mo-Mo distances alternately long (3.10 A) and short (2.50 A). It is diamagnetic and semiconducting ; metal-metal bonds are present. Some of its thermodynamic properties are as follows: G°f29% ~ 172.415 kcal/mole H°f29% -140.5 kcal/mole S°298 11.954 gibbs/mole.
Verwenden
Molybdenum(IV) oxide is used to catalyze the dehydrogenation of alcohols. It is also used as an intermediates and processing aids. It finds application in the manufacture of molybdenum nano-wires.
Verwenden
Molybdenum(IV) oxide (MoO2) is a transition metal oxide with good electrical conductivity due to the presence of delocalized electrons in its valence band. It is traditionally prepared by reducing MoO3 in dry hydrogen in the temperature range of 450-550°C.
MoO2 can be used in a variety of energy based applications such as an anode material in rechargeable lithium batteries and fuel flexible solid oxide fuel cells.It can also be used as a catalyst in hydrogen reforming processes.
synthetische
Molybdenum(IV) oxide is obtained by passing steam over red hot molybdenum:
Mo + 2H2O → MoO2 + 2H2
Alternatively, the oxide may be prepared by heating a molybdate salt, such as ammonium molybdate, with a reducing agent such as zinc. The dioxide also may be obtained along with other oxides of molybdenum when molybdenum metal is heated in air.
A brown-black suspension of MoO2 in hydrate form may be obtained by reducing a solution of ammonium molybdate with hydrogen in the presence of colloidal palladium.
Allgemeine Beschreibung
Molybdenum(IV) oxide (MoO₂) is a transition metal oxide with good electrical conductivity due to the presence of delocalized electrons in its valence band. It is traditionally prepared by reducing MoO₃ in dry hydrogen in the temperature range of 450-550°C.
Hazard
Toxic material.
Sicherheitsprofil
Poison by subcutaneous route. Incandescent reaction with air. When heated to decomposition it emits toxic fumes of Mo.

Molybdaendioxid Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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