1H,1H,2H,2H-Heptadecafluorodecyl acrylate Struktur

3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluordecylacrylat

Bezeichnung:3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluordecylacrylat

CAS-Nr27905-45-9

Englisch Name:1H,1H,2H,2H-Heptadecafluorodecyl acrylate

CBNumberCB2673282

SummenformelC13H7F17O2

Molgewicht518.17

MOL-Datei27905-45-9.mol

Synonyma

3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluordecylacrylat

3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluordecylacrylat physikalisch-chemischer Eigenschaften

Schmelzpunkt	-3°C
Siedepunkt	90 °C4 mm Hg(lit.)
Dichte	1.637 g/mL at 25 °C(lit.)
Brechungsindex	n20/D 1.337(lit.)
Flammpunkt	>230 °F
storage temp.	2-8°C
Löslichkeit	Chloroform, Methanol (Slightly), Water (Sparingly)
Aggregatzustand	Liquid
Farbe	Clear colorless
Wichte	1.596
BRN	5173337
Stabilität	Light Sensitive
InChIKey	QUKRIOLKOHUUBM-UHFFFAOYSA-N
CAS Datenbank	27905-45-9(CAS DataBase Reference)
EPA chemische Informationen	1,1,2,2-Tetrahydroperfluorodecyl acrylate (27905-45-9)

Sicherheit

Kennzeichnung gefährlicher	Xi
R-Sätze:	36/37/38
S-Sätze:	37/39-26-24/25
WGK Germany	3
F	10-23
TSCA	T
HazardClass	IRRITANT
HS Code	29161290

Gefahreninformationscode (GHS)

1H,1H,2H,2H-Heptadecafluorodecyl acrylate Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
Chemische Eigenschaften
clear colorless liquid
Verwenden
(Perfluorooctyl)ethyl Acrylate is a reagent used in the synthesis of parahydrophobic polymer coatings, as well as polymer brushes for controlling surface lubrication.
Definition
1H,1H,2H,2H-Heptadecafluorodecyl acrylate is a semi-volatile fluorinated organic compound and is in polluted air in Asia and the western United States during the spring. The structure of this substance contains multiple fluorine atoms and a terminal olefin unit. It has high chemical reactivity and is sensitive to intense light. Perfluorooctylethyl acrylate contains an unsaturated double-bond unit and can be used to prepare perfluoroacrylate polymers.
Application
1H,1H,2H,2H-Heptadecafluorodecyl acrylate can be applied as follows:
(1) Coatings Industry: Due to their low surface tension and excellent heat resistance, 1H,1H,2H,2H-Heptadecafluorodecyl acrylate are commonly used in the preparation of high-performance surface coatings, such as water-repellent, oil-repellent, corrosion-repellent, anti-adhesive and temperature-resistant coatings^[1-2].
(2) Lubricants: It can be used as a lubricant, especially where oil and water resistance is required.
(3) Surface Modifiers: In surface modification of textiles, plastics and other materials, it can provide special surface properties such as anti-staining and anti-adhesion^[3].
(4) Electronic encapsulation material: Due to its chemical inertness and heat resistance, it can also be used as encapsulation material for electronic products, such as liquid crystal displays and fibre optic manufacturing.
Research
Latex based upon fluorinated acrylates such as perfluorooctylethyl methacrylate (FMA) and perfluorooctylethyl acrylate (FA; 1H,1H,2H,2H-Heptadecafluorodecyl acrylate) and fluorine-free acrylates such as n-butyl methacrylate (BMA) was prepared using emulsion polymerization in the presence of octadecyltrimethylammonium bromide (C18TAB) and 2,2′-azobis(2-amidinopropane) dihydrochloride (V50) as water-soluble azo initiator[4].
Einzelnachweise
[1] VIRENDRA KUMAR. Fluorocarbon Coatings Via Plasma Enhanced Chemical Vapor Deposition of 1H,1H,2H,2H‐perfluorodecyl Acrylate ‐ 2, Morphology, Wettability and Antifouling Characterization[J]. Plasma Processes and Polymers, 2010. DOI:10.1002/PPAP.201000038.
[2] N. YOSHINO. Syntheses and Reactions of Metal Organics. XVII. Synthesis of Silane Coupling Agent Having Fluorocarbon Chain and Surface Modification of Glass Plate[J]. Bulletin of the Chemical Society of Japan, 1993. DOI:10.1246/BCSJ.66.472.
[3] JIYOUNG LEE . Robust and superomniphobic core-shell SiO2@poly(1H,1H,2H,2H-heptadecafluorodecyl methacrylate-co-methyl methacrylate) coating materials synthesized by thiol lactam initiated radical polymerization[J]. Progress in Organic Coatings, 2020. DOI:10.1016/j.porgcoat.2020.105851.
[4] Reinhard F. Linemann. “Latex Blends of Fluorinated and Fluorine-Free Acrylates: Emulsion Polymerization and Tapping Mode Atomic Force Microscopy of Film Formation.” Macromolecules 32 6 (1999): 1715–1721.

3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluordecylacrylat Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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