ChemicalBook CAS DataBase List 4405-13-4

4405-13-4

Name	GLYOXAL HYDRATE TRIMER
CAS	4405-13-4
EINECS(EC#)	224-551-3
Molecular Formula	C6H10O8
MDL Number	MFCD00010556
Molecular Weight	210.14
MOL File	4405-13-4.mol

Synonyms

Brn 3542160 GLYOXAL TRIMER Einecs 224-551-3 Glyoxal Dihydrate GLYOXAL HYDRATE TRIMER Triethanedialdihydrate Ethanedial,trimer,dihydrate Glyoxal trimer dihydrate,Ethanedial GLYOXAL HYDRATE (TRIMER) FOR SYNTHESIS 3-b)-p-dioxin-2,3,6,7-tetrol,hexahydro-p-dioxino( perhydrodioxino(2,3-b)(1,4)dioxin-2,3,6,7-tetraol 3-b]-p-dioxin-2,3,6,7-tetrol,hexahydro-p-Dioxino[2 Hexahydro-p-dioxino[2,3-b]-p-dioxin-2,3,6,7-tetrol p-Dioxino[2,3-b]-p-dioxin-2,3,6,7-tetrol,hexahydro- 4)dioxino(2,3-b)-1,4-dioxin-2,3,6,7-tetrol,hexahydro-( Hexahydro[1,4]dioxino[2,3-b]-1,4-dioxin-2,3,6,7-tetrol 4)Dioxino[2,3-b]-1,4-dioxin-2,3,6,7-tetrol,hexahydro-(1 Hexahydro-[1,4]dioxino[2,3-b]-1,4-dioxin-2,3,6,7-tetrol (1,4)Dioxino[2,3-b]-1,4-dioxin-2,3,6,7-tetrol,hexahydro- Hexahydro-[1,4]dioxino[2,3-b][1,4]dioxine-2,3,6,7-tetrol hexahydro-2,3,6,7-tetrahydroxy-1,4,5,8-tetroxanaphthalene hexahydro-[1,4]dioxino[2,3-b][1,4]dioxine-2,3,6,7-tetraol HEXAHYDRO-2,3,6,7-TETRAHYDROXY-P-DIOXINO [2,3-B]-P-DIOXINE

Chemical Properties

Melting point	179 - 182°C
Boiling point	453℃
density	1.900
Fp	228℃
storage temp.	Refrigerator, Under inert atmosphere
solubility	DMSO (Slightly, Heated), Methanol (Slightly, Heated)
form	Solid
pka	10.54±0.70(Predicted)
color	White to Off-White
EPA Substance Registry System	[1,4]Dioxino[2,3-b]-1,4-dioxin-2,3,6,7-tetrol, hexahydro- (4405-13-4)

Safety Data

Hazard Codes	Xi
Risk Statements	36/37/38 less more
Safety Statements	26-36 less more
WGK Germany	3
RTECS	JH5380000

Hazard Information

Uses

Reactant involved in the synthesis of:

Aza-analogs of 1,4-naphthoquinones as effectors of plasmodial thioredoxin and glutathione reductase
Substituted side-bridged cyclam derivatives
Furandicarboxylic acid di-methyl ester derivatives

General Description

White powder.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

GLYOXAL HYDRATE TRIMER(4405-13-4) is an aldehyde. is an aldehyde. Aldehydes are frequently involved in self-condensation or polymerization reactions. These reactions are exothermic; they are often catalyzed by acid. Aldehydes are readily oxidized to give carboxylic acids. Flammable and/or toxic gases are generated by the combination of aldehydes with azo, diazo compounds, dithiocarbamates, nitrides, and strong reducing agents. Aldehydes can react with air to give first peroxo acids, and ultimately carboxylic acids. These autoxidation reactions are activated by light, catalyzed by salts of transition metals, and are autocatalytic (catalyzed by the products of the reaction). The addition of stabilizers (antioxidants) to shipments of aldehydes retards autoxidation. GLYOXAL HYDRATE TRIMER(4405-13-4) is incompatible with strong oxidizing agents.

Health Hazard

ACUTE/CHRONIC HAZARDS: GLYOXAL HYDRATE TRIMER may be harmful by inhalation, ingestion or skin absorption. It is irritating to the mucous membranes and upper respiratory tract. When heated to decomposition it emits toxic fumes of carbon monoxide and carbon dioxide.

Fire Hazard

Flash point data for GLYOXAL HYDRATE TRIMER are not available. GLYOXAL HYDRATE TRIMER is probably combustible.

Spectrum Detail

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