35138-22-8

Name Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
CAS 35138-22-8
EINECS(EC#) 460-220-1
Molecular Formula C16H24BF4Rh
MDL Number MFCD00075045
Molecular Weight 406.07
MOL File 35138-22-8.mol

Chemical Properties

Appearance dark red
Melting point  210 °C
density  0.42 g/cm3 (20℃)
storage temp.  Refrigerator (+4°C)
solubility  Chloroform (Slightly), Methanol (Slightly)
form  Powder
color  Red
PH 7 (5g/l, H2O, 20℃)
Water Solubility  insoluble
Sensitive  Slightly air & moisture sensitive
Exposure limits ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
InChI InChI=1S/2C8H12.BF4.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h2*1-2,7-8H,3-6H2;;/q;;-1;+1/b2*2-1-,8-7-;;
InChIKey IEMMJJILGGBYNZ-GSLAGHMSSA-M
SMILES [B-](F)(F)(F)F.C1CCC=CCCC=1.C1CCC=CCCC=1.[Rh+] |c:7,11,15,19|
CAS DataBase Reference 35138-22-8(CAS DataBase Reference)
Storage Precautions Air sensitive;Moisture sensitive;Heat sensitive;Store under nitrogen

Safety Data

Symbol(GHS)  Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
Signal word  Warning
Hazard statements  H228-H315-H317-H319-H335
Precautionary statements  P210-P240-P241-P280-P302+P352-P305+P351+P338
Hazard Codes  F,Xi
Risk Statements 
R11:Highly Flammable.
R34:Causes burns.
Safety Statements 
S16:Keep away from sources of ignition-No smoking .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
RIDADR  UN 2921
WGK Germany  2
Hazard Note  Irritant
TSCA  No
REACH Registrations Inactive
HazardClass  8
PackingGroup  III
HS Code  28439000
Storage Class 4.1B - Flammable solid hazardous materials
Hazard Classifications Acute Tox. 4 Oral
Eye Irrit. 2
Resp. Sens. 1
Skin Irrit. 2
Skin Sens. 1
STOT SE 3

Hazard Information

Questions And Answer

Supplier