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• Reaction

  1. Ring-Opening of epoxides and aziridines.
  2. Asymmetric conjugate addition of organozinc reagents to α,β-unsaturated ketones.
  3. Electrophilic addition of olefins.
  4. Asymmetric aziridination of olefins.
  5. Asymmetric cycloadditions and aldol condensations.
  6. Asymmetric Kharasch oxidation.
  7. Asymmetric Michael addition of enamides.
  8. Asymmetric O-H or O-R insertion reactions.
  9. Enantioselective intramolecular aminooxygenation of alkenes.
  10. Enantioselective addition of dialkylzinc reagents to N-acylpyridinium salts.
  11. Pd-catalyzed C-H functionalizations of oximes with arylboronic acids.
  12. Used as a Lewis acid in the Nazarov cyclization.
  13. Catalyst in the diacetoxylation olefins.
  14. Catalyst in the meta-selective direct arylation of α-aryl carbonyl compounds.
  15. Catalyst in the three-component coupling of amines, aldehydes, and alkynes.
  
  
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