14694-95-2
| Name | Chlorotris(triphenylphosphine)rhodium(I) |
| CAS | 14694-95-2 |
| EINECS(EC#) | 238-744-5 |
| Molecular Formula | C54H45ClP3Rh |
| MDL Number | MFCD00010016 |
| Molecular Weight | 925.21 |
| MOL File | 14694-95-2.mol |
Chemical Properties
| Appearance | magenta crystals |
| Melting point | 245-250 °C (dec.) |
| Boiling point | >170°C |
| density | 1.363; d 1.379 |
| vapor pressure | 0Pa at 25℃ |
| storage temp. | 2-8°C |
| solubility | Soluble in most solvents (e.g. benzene, ethanol, chloroform, dichloromethane) but with phosphine dissociation. Reacts with O{2} in solution |
| form | Crystalline Powder |
| color | Red-brown to maroon |
| Water Solubility | insoluble |
| Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
| Sensitive | air sensitive |
| Merck | 14,10047 |
| BRN | 4581440 |
| Exposure limits | ACGIH: TWA 1 mg/m3 NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 |
| InChI | 1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1 |
| InChIKey | QEYYHUJFSQCTAE-UHFFFAOYSA-M |
| SMILES | Cl[Rh].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9 |
| LogP | 5.69 at 20℃ |
Safety Data
| Symbol(GHS) |  GHS07 |
| Signal word | Warning |
| Hazard statements | H317-H413 |
| Precautionary statements | P261-P272-P273-P280-P302+P352-P333+P313 |
| Hazard Codes | C,Xi |
| Risk Statements | |
| Safety Statements | |
| RIDADR | 1759 |
| WGK Germany | 1 |
| F | 8-10-23 |
| TSCA | Yes |
| REACH Registrations | Active |
| HS Code | 28439090 |
| Storage Class | 11 - Combustible Solids |
| Hazard Classifications | Aquatic Chronic 4 Skin Sens. 1 |
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