14040-11-0

Name Tungsten hexacarbonyl
CAS 14040-11-0
EINECS(EC#) 237-880-2
Molecular Formula C6H12O6W
MDL Number MFCD00011462
Molecular Weight 364
MOL File 14040-11-0.mol

Chemical Properties

Appearance White, volatile, highly refractive, crystalline solid. Decomposes without melting at 150C. One of the more stable carbonyls. Insoluble in water; soluble in organic solvents.
Melting point  150 °C (lit.)
Boiling point  175 °C
density  2.65 g/mL at 25 °C(lit.)
vapor density  12.1 (vs air)
vapor pressure  1.2 mm Hg ( 67 °C)
RTECS  YO7705000
Fp  200°C
storage temp.  Store below +30°C.
solubility  insoluble in H2O; soluble in organic solvents
form  Fine Crystalline Powder
color  Light yellow to beige
Specific Gravity 2.671
Stability: Stable. Incompatible with oxidizing agents.
Water Solubility  insoluble
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
Exposure limits ACGIH: TWA 3 mg/m3
NIOSH: TWA 5 mg/m3; STEL 10 mg/m3
InChI 1S/6CO.W/c6*1-2;
InChIKey FQNHWXHRAUXLFU-UHFFFAOYSA-N
SMILES [W].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
Uses
Tungsten coatings on base metals by deposition and decomposition of the carbonyl.
CAS DataBase Reference 14040-11-0(CAS DataBase Reference)
NIST Chemistry Reference Tungsten hexacarbonyl(14040-11-0)
EPA Substance Registry System 14040-11-0(EPA Substance)

Safety Data

Symbol(GHS)  Skull and Crossbones (GHS06)
GHS06
Signal word  Danger
Hazard statements  H301+H311+H331
Precautionary statements  P261-P264-P280-P301+P310-P302+P352+P312-P304+P340+P311
Hazard Codes  T
Risk Statements 
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
Safety Statements 
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S38:In case of insufficient ventilation, wear suitable respiratory equipment .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
RIDADR  UN 3466 6.1/PG 3
WGK Germany  3
Hazard Note  Toxic
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  29310095
Storage Class 6.1D - Non-combustible acute toxic Cat.3
toxic hazardous materials or hazardous materials causing chronic effects
Hazard Classifications Acute Tox. 3 Dermal
Acute Tox. 3 Inhalation
Acute Tox. 3 Oral

Raw materials And Preparation Products

Hazard Information

Material Safety Data Sheet(MSDS)

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