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140-31-8
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Identification
Name
N-Aminoethylpiperazine
CAS
140-31-8
Synonyms
1-(2-AMINOETHYL)PIPERAZINE
1-piperazineethanamine
2-(1-PIPERAZINYL)ETHYLAMINE
2-PIPERAZIN-1-YL-ETHYLAMINE
2-PIPERAZINOETHYLAMINE
AEP
AKOS BBS-00004342
AMINOETHYLPIPERAZINE
LABOTEST-BB LTBB000498
N-(2-AMINOETHYL)PIPERAZIN
N-(2-AMINOETHYL)PIPERAZINE
N-AMINOETHYLPIPERAZINE
TIMTEC-BB SBB004229
1-(2-aminoethyl)-piperazin
1-Aminoethylpiperazine
1-Piperazineethylamine
2-(1-Piperazinyl)ethanamine
2-Piperazinoethylamione
2-Piperazinylethylamine
D.E.H. 39
EINECS(EC#)
205-411-0
Molecular Formula
C6H15N3
MDL Number
MFCD00005971
Molecular Weight
129.2
MOL File
140-31-8.mol
N-Aminoethylpiperazine
CAS
140-31-8
Synonyms
1-(2-AMINOETHYL)PIPERAZINE
1-piperazineethanamine
2-(1-PIPERAZINYL)ETHYLAMINE
2-PIPERAZIN-1-YL-ETHYLAMINE
2-PIPERAZINOETHYLAMINE
AEP
AKOS BBS-00004342
AMINOETHYLPIPERAZINE
LABOTEST-BB LTBB000498
N-(2-AMINOETHYL)PIPERAZIN
N-(2-AMINOETHYL)PIPERAZINE
N-AMINOETHYLPIPERAZINE
TIMTEC-BB SBB004229
1-(2-aminoethyl)-piperazin
1-Aminoethylpiperazine
1-Piperazineethylamine
2-(1-Piperazinyl)ethanamine
2-Piperazinoethylamione
2-Piperazinylethylamine
D.E.H. 39
EINECS(EC#)
205-411-0
Molecular Formula
C6H15N3
MDL Number
MFCD00005971
Molecular Weight
129.2
MOL File
140-31-8.mol
Chemical Properties
Definition
An amine combining a primary, secondary, and ter- tiary amine in one molecule.
Appearance
N-Aminoethypiperazine is a combustible and corrosive aliphatic amine It is a colorless to light yellow liquid
Appearance
viscous light yellow liquid
mp
-19 °C
bp
218-222 °C(lit.)
density
0.985 g/mL at 25 °C(lit.)
vapor density
4.4 (vs air)
vapor pressure
0.05 mm Hg ( 20 °C)
refractive index
n20/D 1.500
Fp
200 °F
Stability:
Stable. Flammable. Incompatible with acids, acid anhydrides, acid chlorides, strong oxidizing agents, chloroformates.
Water Solubility
soluble
Sensitive
Air Sensitive
BRN
104363
CAS DataBase Reference
140-31-8(CAS DataBase Reference)
NIST Chemistry Reference
N-(2-Aminoethyl)piperazine(140-31-8)
An amine combining a primary, secondary, and ter- tiary amine in one molecule.
Appearance
N-Aminoethypiperazine is a combustible and corrosive aliphatic amine It is a colorless to light yellow liquid
Appearance
viscous light yellow liquid
mp
-19 °C
bp
218-222 °C(lit.)
density
0.985 g/mL at 25 °C(lit.)
vapor density
4.4 (vs air)
vapor pressure
0.05 mm Hg ( 20 °C)
refractive index
n
Fp
200 °F
Stability:
Stable. Flammable. Incompatible with acids, acid anhydrides, acid chlorides, strong oxidizing agents, chloroformates.
Water Solubility
soluble
Sensitive
Air Sensitive
BRN
104363
CAS DataBase Reference
140-31-8(CAS DataBase Reference)
NIST Chemistry Reference
N-(2-Aminoethyl)piperazine(140-31-8)
Safety Data
Hazard Codes
C
Risk Statements
R21/22:Harmful in contact with skin and if swallowed .
R34:Causes burns.
R43:May cause sensitization by skin contact.
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
Safety Statements
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
RIDADR
UN 2815 8/PG 3
WGK Germany
2
RTECS
TK8050000
HazardClass
8
PackingGroup
III
HS Code
29335995
Safety Profile
Poison by intraperitoneal route. Moderately toxic by ingestion and skin contact. Experimental reproductive effects. A skin and eye irritant. Mutation data reported. See also AMINES. Moderately flammable when exposed to heat, flame, sparks, or powerful oxidlzers. To fight fire, use alcohol foam. When heated to decomposition it emits toxic fumes of NOx,.
Hazardous Substances Data
140-31-8(Hazardous Substances Data)
C
Risk Statements
R21/22:Harmful in contact with skin and if swallowed .
R34:Causes burns.
R43:May cause sensitization by skin contact.
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
Safety Statements
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
RIDADR
UN 2815 8/PG 3
WGK Germany
2
RTECS
TK8050000
HazardClass
8
PackingGroup
III
HS Code
29335995
Safety Profile
Poison by intraperitoneal route. Moderately toxic by ingestion and skin contact. Experimental reproductive effects. A skin and eye irritant. Mutation data reported. See also AMINES. Moderately flammable when exposed to heat, flame, sparks, or powerful oxidlzers. To fight fire, use alcohol foam. When heated to decomposition it emits toxic fumes of NOx,.
Hazardous Substances Data
140-31-8(Hazardous Substances Data)
Raw materials And Preparation Products
Raw materials
Potassium carbonate-->Ammonia-->1,4-Diazacyclohexane-->Dichloroethane-->2-Chloroethylamine hydrochloride
Preparation Products
Ethylenediamine-->3-[(Benzyloxycarbonyl)amino]propionaldehyde
Potassium carbonate-->Ammonia-->1,4-Diazacyclohexane-->Dichloroethane-->2-Chloroethylamine hydrochloride
Preparation Products
Ethylenediamine-->3-[(Benzyloxycarbonyl)amino]propionaldehyde
Hazard Information
General Description
A colorless liquid with a faint fishlike odor. Flash point 199°F. Corrosive to tissue. Toxic oxides of nitrogen are produced by combustion.
Reactivity Profile
N-AMINOETHYLPIPERAZINE(140-31-8) neutralizes acids to form salts plus water in exothermic reactions. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated in combination with strong reducing agents, such as hydrides.
Air & Water Reactions
Water soluble.
Hazard
Strong irritant to tissue.
Health Hazard
INHALATION: Burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. EYES AND SKIN: Extremely destructive to mucous membranes, upper respiratory tract, eyes and skin. Causes burns on short contact.
Potential Exposure
Used as an epoxy curing agent and making pharmaceuticals; synthetic fibers, and other chemicals.
Fire Hazard
Special Hazards of Combustion Products: Toxic fumes of NO x
First aid
If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. If victim is conscious, administer water or milk. Do not induce vomiting.
Shipping
UN2815 N-Aminoethylpiperazined, Hazard class: 8; Labels: 8-Corrosive material
Incompatibilities
Solution is a strong base. Reacts with nitrosating agents (e.g., nitrites, nitrous gases, nitrous acid); capable of releasing carcinogenic nitrosamines. Incompatible with nonoxidizing mineral acids; strong acids; organic acids, acid chlorides; acid anhydrides; organic anhydrides; isocyanates, chloroformates, vinyl acetate; acrylates, substituted allyls; alkylene oxides; epichlorohydrin, ketones, aldehydes, alcohols, glycols, phenols, cresols, caprolactum solution; strong oxidizers. Contact with copper alloys, zinc or galvanized steel may cause violent reaction.
A colorless liquid with a faint fishlike odor. Flash point 199°F. Corrosive to tissue. Toxic oxides of nitrogen are produced by combustion.
Reactivity Profile
N-AMINOETHYLPIPERAZINE(140-31-8) neutralizes acids to form salts plus water in exothermic reactions. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated in combination with strong reducing agents, such as hydrides.
Air & Water Reactions
Water soluble.
Hazard
Strong irritant to tissue.
Health Hazard
INHALATION: Burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. EYES AND SKIN: Extremely destructive to mucous membranes, upper respiratory tract, eyes and skin. Causes burns on short contact.
Potential Exposure
Used as an epoxy curing agent and making pharmaceuticals; synthetic fibers, and other chemicals.
Fire Hazard
Special Hazards of Combustion Products: Toxic fumes of NO x
First aid
If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. If victim is conscious, administer water or milk. Do not induce vomiting.
Shipping
UN2815 N-Aminoethylpiperazined, Hazard class: 8; Labels: 8-Corrosive material
Incompatibilities
Solution is a strong base. Reacts with nitrosating agents (e.g., nitrites, nitrous gases, nitrous acid); capable of releasing carcinogenic nitrosamines. Incompatible with nonoxidizing mineral acids; strong acids; organic acids, acid chlorides; acid anhydrides; organic anhydrides; isocyanates, chloroformates, vinyl acetate; acrylates, substituted allyls; alkylene oxides; epichlorohydrin, ketones, aldehydes, alcohols, glycols, phenols, cresols, caprolactum solution; strong oxidizers. Contact with copper alloys, zinc or galvanized steel may cause violent reaction.
Material Safety Data Sheet(MSDS)
Spectrum Detail
Spectrum Detail
N-Aminoethylpiperazine(140-31-8) IR1
N-Aminoethylpiperazine(140-31-8) 13C NMR
N-Aminoethylpiperazine(140-31-8) 1H NMR
N-Aminoethylpiperazine(140-31-8) Raman
N-Aminoethylpiperazine(140-31-8) IR1
N-Aminoethylpiperazine(140-31-8) 13C NMR
N-Aminoethylpiperazine(140-31-8) 1H NMR
N-Aminoethylpiperazine(140-31-8) Raman
Well-known Reagent Company Product Information
Acros Organics
1-(2-Aminoethyl)piperazine, 97%(140-31-8)
Alfa Aesar
1-(2-Aminoethyl)piperazine, 98%(140-31-8)
Sigma Aldrich
140-31-8(sigmaaldrich)
TCI AMERICA
N-(2-Aminoethyl)piperazine,>99.0%(GC)(140-31-8)
1-(2-Aminoethyl)piperazine, 97%(140-31-8)
Alfa Aesar
1-(2-Aminoethyl)piperazine, 98%(140-31-8)
Sigma Aldrich
140-31-8(sigmaaldrich)
TCI AMERICA
N-(2-Aminoethyl)piperazine,>99.0%(GC)(140-31-8)
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