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12138-09-9

Name TUNGSTEN SULFIDE
CAS 12138-09-9
EINECS(EC#) 235-243-3
Molecular Formula S2W
MDL Number MFCD00011467
Molecular Weight 247.97
MOL File 12138-09-9.mol

Chemical Properties

Appearance Grayish-black solid. Mp above 1480C, can lubricate at temperatures above 2400F (1316C). Attacked by fluorine and hot sulfuric and hydrogen fluoride.
Melting point  1480 °C
density  7.5 g/mL at 25 °C(lit.)
RTECS  YO7716000
solubility  insoluble in H2O, HCl, alkaline solutions
form  powder
color  Dark gray
Specific Gravity 7.5
Water Solubility  Slightly soluble in water.
Crystal Structure MoS2 type
crystal system Six sides
Space group P63/mmc
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.315320.315321.232390901200.1061
Exposure limits ACGIH: TWA 3 mg/m3
NIOSH: TWA 5 mg/m3; STEL 10 mg/m3
CAS DataBase Reference 12138-09-9(CAS DataBase Reference)
EPA Substance Registry System Tungsten sulfide (WS2) (12138-09-9)
Application

Due to its distinctive electron configuration and high specific surface area, few-layer tungsten disulfide nanosheets have potential applications in electrodes and energy storage devices, supercapacitors, and photoelectrochemical cells as a catalyst for hydrogen evolution reactions (HERs). With?tunable electromagnetic absorption, it has practical applications?against electromagnetic pollution. WS2?is also a great potential candidate in photothermal therapy for the ablation of cancer cells, when NIR light is absorbed and converted into heat.

Bandgap 1.4 - 2.01 eV
Chemical Synthesis

High-quality tungsten disulfide monolayer?films?are grown directly on the substrates (sapphire) by? the chemical vapour deposition (CVD) method.

Electronic properties 2D semiconductor
Odor Transparent
Preparation Synthetic?- Chemical Vapour Transport (CVT)

Safety Data

Hazard Codes  Xi
Risk Statements 
R36/37/38:Irritating to eyes, respiratory system and skin .
Safety Statements 
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
WGK Germany  -
TSCA  Yes
HS Code  28291900

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