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12138-09-9

Name TUNGSTEN SULFIDE
CAS 12138-09-9
EINECS(EC#) 235-243-3
Molecular Formula S2W
MDL Number MFCD00011467
Molecular Weight 247.97
MOL File 12138-09-9.mol

Chemical Properties

Appearance Grayish-black solid. Mp above 1480C, can lubricate at temperatures above 2400F (1316C). Attacked by fluorine and hot sulfuric and hydrogen fluoride.
Melting point  1480 °C
density  7.5 g/mL at 25 °C(lit.)
RTECS  YO7716000
solubility  insoluble in H2O, HCl, alkaline solutions
form  powder
color  Dark gray
Specific Gravity 7.5
Water Solubility  Slightly soluble in water.
Exposure limits ACGIH: TWA 3 mg/m3
NIOSH: TWA 5 mg/m3; STEL 10 mg/m3
CAS DataBase Reference 12138-09-9(CAS DataBase Reference)
EPA Substance Registry System Tungsten sulfide (WS2) (12138-09-9)
Application

Due to its distinctive electron configuration and high specific surface area, few-layer tungsten disulfide nanosheets have potential applications in electrodes and energy storage devices, supercapacitors, and photoelectrochemical cells as a catalyst for hydrogen evolution reactions (HERs). With?tunable electromagnetic absorption, it has practical applications?against electromagnetic pollution. WS2?is also a great potential candidate in photothermal therapy for the ablation of cancer cells, when NIR light is absorbed and converted into heat.

Bandgap 1.4 - 2.01 eV
Chemical Synthesis

High-quality tungsten disulfide monolayer?films?are grown directly on the substrates (sapphire) by? the chemical vapour deposition (CVD) method.

Electronic properties 2D semiconductor
Odor Transparent
Preparation Synthetic?- Chemical Vapour Transport (CVT)

Safety Data

Hazard Codes  Xi
Risk Statements 
R36/37/38:Irritating to eyes, respiratory system and skin .
Safety Statements 
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
WGK Germany  -
TSCA  Yes
HS Code  28291900

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