Supplier Related Products Identification Chemical Properties Safety Data Raw materials And Preparation Products Hazard Information Spectrum Detail Well-known Reagent Company Product Information
WebSite >  CAS DataBase List  > 108-37-2

108-37-2

Supplier Related Products Identification Chemical Properties Safety Data Raw materials And Preparation Products Hazard Information Spectrum Detail Well-known Reagent Company Product Information

Product Image

Identification

Name
3-BROMOCHLOROBENZENE
CAS
108-37-2
Synonyms
1-BROMO-3-CHLOROBENZENE
3-BROMOCHLOROBENZENE
M-BROMOCHLOROBENZENE
M-CHLOROBROMOBENZENE
1-bromo-3-chloro-benzen
1-Chloro-3-bromobenzene
3-Bromo-1-chlorobenzene
3-Chlorobromobenzene
3-Chlorophenyl bromide
3-chlorophenylbromide
Benzene, 1-bromo-3-chloro-
benzene,1-bromo-3-chloro-
m-Bromophenyl chloride
m-bromophenylchloride
m-Chlorophenyl bromide
m-chlorophenylbromide
3-BROMOCHLOROBENZENE 99%
3-Bromochlorobenzene/1-Bromo-3-chlorobenzene
Bromochlorobenzene, m-
EINECS(EC#)
203-575-8
Molecular Formula
C6H4BrCl
MDL Number
MFCD00000568
Molecular Weight
191.45
MOL File
108-37-2.mol

Chemical Properties

Appearance
CLEAR COLOURLESS TO LIGHT YELLOW LIQUID
Melting point 
-21.5 °C
mp 
-21.5 °C
Boiling point 
196 °C(lit.)

bp 
196 °C(lit.)

density 
1.63 g/mL at 25 °C(lit.)

refractive index 
n20/D 1.576(lit.)

Fp 
177 °F

storage temp. 
Sealed in dry,Room Temperature
form 
Liquid
color 
Clear colorless to light yellow
Specific Gravity
1.630
Water Solubility 
Insoluble
BRN 
1446353
CAS DataBase Reference
108-37-2(CAS DataBase Reference)
NIST Chemistry Reference
3-Chlorobromobenzene(108-37-2)
EPA Substance Registry System
108-37-2(EPA Substance)

Safety Data

Hazard Codes 
Xi
Risk Statements 
R36/37/38:Irritating to eyes, respiratory system and skin .
Safety Statements 
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
WGK Germany 
3

RTECS 
CY9005000

Hazard Note 
Irritant
TSCA 
Yes
HS Code 
29039990

Raw materials And Preparation Products

Preparation Products
1-(3-Chlorophenyl)-1-ethanol

Hazard Information

Chemical Properties
CLEAR COLOURLESS TO LIGHT YELLOW LIQUID
Uses
1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source.
Synthesis Reference(s)
The Journal of Organic Chemistry, 52, p. 664, 1987 DOI: 10.1021/jo00380a031
General Description
1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source.

Spectrum Detail

Well-known Reagent Company Product Information

SupplierMore