100-59-4

Name PHENYLMAGNESIUM CHLORIDE
CAS 100-59-4
EINECS(EC#) 202-868-8
Molecular Formula C6H5ClMg
MDL Number MFCD00000464
Molecular Weight 136.86
MOL File 100-59-4.mol
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Chemical Properties

Appearance yellowish-brown to dark brown solution
Melting point  89-90℃
Boiling point  230℃ (8 Torr)
density  0.98 g/mL at 20 °C
Fp  1 °F
storage temp.  water-free area
form  solution
Water Solubility  It reacts violently with water.
Sensitive  Air & Moisture Sensitive
Merck  7298
BRN  3587900
InChI InChI=1S/C6H5.ClH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1
InChIKey GQONLASZRVFGHI-UHFFFAOYSA-M
SMILES C1([Mg]Cl)C=CC=CC=1
CAS DataBase Reference 100-59-4(CAS DataBase Reference)
EPA Substance Registry System Magnesium, chlorophenyl- (100-59-4)

Safety Data

Symbol(GHS)  Flame (GHS02)Corrosion (GHS05)Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS02,GHS05,GHS07,GHS08
Signal word  Danger
Hazard statements  H371-H372-H261-H312-H318-H333-H225-H302-H314-H335-H351
Precautionary statements  P223-P303+P361+P353-P501a-P210-P260-P280-P305+P351+P338-P370+P378-P403+P235-P233-P240-P241+P242+P243-P264-P270-P271-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P308+P311-P403+P233-P405-P501
Hazard Codes  F,C
Risk Statements 
R14:Reacts violently with water.
R19:May form explosive peroxides.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R34:Causes burns.
R67:Vapors may cause drowsiness and dizziness.
R65:Harmful: May cause lung damage if swallowed.
R63:Possible risk of harm to the unborn child.
R48/20:Harmful: danger of serious damage to health by prolonged exposure through inhalation .
R11:Highly Flammable.
Safety Statements 
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
S33:Take precautionary measures against static discharges .
S16:Keep away from sources of ignition-No smoking .
RIDADR  UN 2924 3/PG 2
WGK Germany  2
F  10
TSCA  Yes
REACH Registrations Active
HazardClass  8
PackingGroup  II
HS Code  29319090
Storage Class 3 - Flammable liquids
Hazard Classifications Carc. 2
Eye Dam. 1
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3
Hazardous Substances Data 100-59-4(Hazardous Substances Data)

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